Dienes ( buta-1,3-diene)
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Questions and Answers

What is buna rubber? Give its preparation with conditions .

Buna rubber also called polybutadiene. It is prepared from 1,3-butadiene in presence of peroxide (ROOR).

Name the catalysts used in addition of hydrogen in 1,3-butadiene.

Pt, Pd or Ni.

What is kinetically controlled product prepared from 1,3-butadiene when halogen acid is added to it? Give the temperature 🌡️ at which it is carried.

Product is called 3-bromo-1-butene. It is carried out at low temperature (-80°C).

How to prepare 1,3-butadiene from n-butane ?

<p>By catalytic dehydrogenation of butane in presence of Cr2O3-Al2O3 and 600°C.</p> Signup and view all the answers

To which of following if acidic condition (H+) provided, 1,3-butadiene if formed?

<p>1,4-Butandiol. (A)</p> Signup and view all the answers

Which of following is not required in preparation of 1,3-butadiene from 1-butene ?

<p>H+ (C)</p> Signup and view all the answers

Select the incorrect in accordance with Diels -Alder Reaction.

<p>At the expense of 3 original pi bonds , in a product 2 new pi bonds and 1new sigma bond is formed. (B)</p> Signup and view all the answers

Dienophiles with electron attracting groups give 100%yield and reaction carried out at 100°C.

<p>True (A)</p> Signup and view all the answers

Name the reactant reacting with 1,3-butadiene to form 3-cyclohexene-1-cabaldehyde.

<p>Prop-2-en-1-al</p> Signup and view all the answers

Flashcards

What is Buna Rubber?

Synthetic rubber made from 1,3-butadiene using a peroxide catalyst.

Catalysts for Hydrogenation of 1,3-Butadiene

Platinum (Pt), Palladium (Pd), or Nickel (Ni).

Kinetically Controlled Product of 1,3-Butadiene + HBr

3-bromo-1-butene, formed at -80°C.

1,3-Butadiene from n-Butane

Catalytic dehydrogenation using Cr2O3-Al2O3 at 600°C.

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Precursor to 1,3-Butadiene in Acidic Conditions

1,4-Butanediol.

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Not Required for 1,3-Butadiene from 1-Butene

H+

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Incorrect Statement about Diels-Alder

Incorrect: Diels-Alder forms 2 new sigma bonds and 1 new pi bond, consuming 3 pi bonds.

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Dienophiles with Electron Withdrawing Groups in Diels-Alder

True.

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Reactant to Form 3-Cyclohexene-1-Carbaldehyde with 1,3-Butadiene

Prop-2-en-1-al.

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