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Questions and Answers
What percentage of monosaccharides exist in the open-chain form?
What percentage of monosaccharides exist in the open-chain form?
Which component is formed when a monosaccharide cyclizes?
Which component is formed when a monosaccharide cyclizes?
What is the structure of sucrose?
What is the structure of sucrose?
Which type of bond forms between monosaccharides to create disaccharides?
Which type of bond forms between monosaccharides to create disaccharides?
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What configuration does the anomeric hydroxyl take in an α-bond?
What configuration does the anomeric hydroxyl take in an α-bond?
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Which of the following is categorized as a reducing sugar?
Which of the following is categorized as a reducing sugar?
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Which compound is involved in forming a glycosidic bond during polymerization of sugars?
Which compound is involved in forming a glycosidic bond during polymerization of sugars?
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What is a key characteristic of reducing sugars in terms of their functional groups?
What is a key characteristic of reducing sugars in terms of their functional groups?
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What is the empirical formula for many simpler carbohydrates?
What is the empirical formula for many simpler carbohydrates?
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Which of the following statements correctly describes epimers?
Which of the following statements correctly describes epimers?
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Which of the following is NOT a classification of monosaccharides based on the number of carbon atoms?
Which of the following is NOT a classification of monosaccharides based on the number of carbon atoms?
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How are monosaccharides numbered?
How are monosaccharides numbered?
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Which sugar is NOT considered a D-sugar?
Which sugar is NOT considered a D-sugar?
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Which functional group determines if a monosaccharide is an aldose or ketose?
Which functional group determines if a monosaccharide is an aldose or ketose?
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Which of the following sugars are isomers?
Which of the following sugars are isomers?
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Which characteristic is true of carbohydrates?
Which characteristic is true of carbohydrates?
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What is the primary storage form of glucose in animals?
What is the primary storage form of glucose in animals?
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Which type of glycosidic bond primarily connects glucose units in cellulose?
Which type of glycosidic bond primarily connects glucose units in cellulose?
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What are the key structural features of starch?
What are the key structural features of starch?
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Which of these best describes the bonding in glycogen?
Which of these best describes the bonding in glycogen?
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What is the role of ribose in biological systems?
What is the role of ribose in biological systems?
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How does cellulose differ structurally from starch?
How does cellulose differ structurally from starch?
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What is the significance of glycoproteins in biological systems?
What is the significance of glycoproteins in biological systems?
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What type of bond is formed when a sugar is attached to a purine base?
What type of bond is formed when a sugar is attached to a purine base?
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What is a key feature of glycogen regarding its structure?
What is a key feature of glycogen regarding its structure?
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What role does glucose play in the human body?
What role does glucose play in the human body?
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Study Notes
Carbohydrates
- Carbohydrates are the most abundant organic molecules in nature
- They are classified based on the number of carbon atoms, sugar subunits, or functional groups
- Carbohydrates exist as isomers, which have the same chemical formula but different structures
- Carbohydrates' functions include short-term energy generation, intermediate-term energy storage, and structural components of cells
- Carbohydrates can be attached to non-carbohydrate molecules by glycosidic bonds
Biomolecules
- Biomolecules are organic molecules formed by living organisms
- They are primarily composed of carbon, hydrogen, oxygen, and nitrogen
- Four major classes of biomolecules include carbohydrates, proteins, lipids, and nucleic acids
Monosaccharides
- Monosaccharides are simple sugars that cannot be hydrolyzed into simpler carbohydrates
- They are classified based on the number of carbon atoms (e.g., trioses, tetroses, pentoses, hexoses)
- Monosaccharides can be aldoses (aldehyde functional group) or ketoses (ketone functional group)
- Common monosaccharides include glucose, fructose, and galactose
Isomers
- Isomers have the same chemical formula but different structures
- Examples include glucose, galactose, and fructose, all with the formula C6H12O6.
- Enantiomers are nonsuperimposable mirror images
Epimers
- Epimers are isomers that differ in the configuration around only one specific carbon atom (excluding the carbonyl carbon)
- Glucose and mannose are C-2 epimers
- Glucose and galactose are C-4 epimers
Cyclisation
- Monosaccharides often exist in ring formations
- Less than 1% of monosaccharides exist in their open-chain form
- Cyclization creates an anomeric carbon
Glycosidic bonds
- Glycosidic bonds are the bonds that link monosaccharides to form disaccharides, oligosaccharides, and polysaccharides
- They are formed through dehydration reactions (condensation)
- Glycosidic bonds are named based on the configuration of the anomeric hydroxyl group (α or β)
Common disaccharides
- Disaccharides are formed from two monosaccharides
- Examples include lactose (β-galactose + α-glucose), maltose (α-glucose + α-glucose), and sucrose (α-glucose + β-fructose)
Reducing sugars
- Reducing sugars can act as reducing agents because the anomeric carbon is not involved in a glycosidic bond
- All monosaccharides are reducing sugars
Glucose – biomedical importance
- Glucose is a crucial energy source in all cells
- It cannot be stored in this form because it would affect osmotic balance
- It is stored as glycogen in animals
- Ribose is present in nucleotides and nucleic acids.
Polymers of glucose
- Glycogen: Storage form of glucose in animals, highly branched
- Starch: Storage form of glucose in plants; composed of amylose (linear) and amylopectin (branched)
- Cellulose: Structural component of plant cell walls, composed of unbranched chains of β-glucose
Cellulose vs Starch
- The main difference between cellulose and starch is that cellulose uses β-glucose while starch uses α-glucose units in its structure
Complex carbohydrates
- Carbohydrates can be attached to non-carbohydrate molecules via glycosidic bonds
- Structures include glycoproteins, proteoglycans, and glycolipids
- The types of glycosidic bonds depend on the attached non-carbohydrate molecule (-NH2 group = N-glycoside, -OH group = O-glycoside)
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Description
Explore the fascinating world of carbohydrates and biomolecules in this quiz. Learn about the classification, functions, and structures of carbohydrates, as well as the four major classes of biomolecules. Test your knowledge of monosaccharides, isomers, and their roles in living organisms.