Binary Phase Diagrams in Engineering Materials
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Questions and Answers

What is the meaning of 'isomorphous' in the context of binary phase diagrams?

  • It indicates complete solubility of the 2 substances together. (correct)
  • It indicates the absence of any solubility between the 2 substances.
  • It indicates partial solubility of the 2 substances together.
  • It indicates the presence of three distinct phases.
  • What is the name given to the lines separating the liquid and solid phases in an isomorphous system?

  • Equilibrium lines
  • Liquidus and Solidus (correct)
  • Isomorphous lines
  • Isobar
  • At point A in the Ni-Cu phase diagram, with T = 1100°C and C0 = 60 wt% Ni, how many phases are present?

  • 2 phases: Liquid (L) and FCC solid solution (𝛼)
  • 1 phase: Liquid (L)
  • No phase
  • 1 phase: FCC solid solution (𝛼) (correct)
  • At point B in the Ni-Cu phase diagram, with T = 1250°C and C0 = 65 wt% Cu, how many phases are present?

    <p>2 phases: Liquid (L) and FCC solid solution (𝛼)</p> Signup and view all the answers

    What do we determine by knowing both the temperature (T) and initial composition (C0) in a phase diagram?

    <p>The phases present and their compositions</p> Signup and view all the answers

    What microstructural changes accompany the cooling of a C0 = 35 wt% Ni alloy under non-equilibrium (cored) cooling?

    <p>The solidus line on the phase diagram has been shifted to higher Ni contents</p> Signup and view all the answers

    What is the main mechanism that accomplishes the readjustments during the cooling of a C0 = 35 wt% Ni alloy under equilibrium cooling?

    <p>Diffusion in both solid and liquid phases</p> Signup and view all the answers

    What type of microstructure is revealed in the photomicrograph of an as-cast bronze alloy found in Syria, dated to the 19th century BC?

    <p>Cored structure</p> Signup and view all the answers

    In an isomorphous alloy, what effect does slow rate of cooling have on the resulting microstructure?

    <p>Formation of equilibrium structure</p> Signup and view all the answers

    What is the role of diffusion in both solid and liquid phases during the cooling of a C0 = 35 wt% Ni alloy under equilibrium cooling?

    <p>Accomplishing readjustments in microstructure</p> Signup and view all the answers

    Study Notes

    Isomorphous Systems

    • Isomorphous refers to binary phase diagrams where the components are completely soluble in each other in both solid and liquid states.

    Phase Boundaries

    • The lines separating the liquid and solid phases in an isomorphous system are called liquidus and solidus lines.

    Phase Diagram Analysis

    • Given a point on the phase diagram, knowing both the temperature (T) and initial composition (C0) allows us to determine the number of phases present.
    • At point A in the Ni-Cu phase diagram, with T = 1100°C and C0 = 60 wt% Ni, two phases are present.
    • At point B in the Ni-Cu phase diagram, with T = 1250°C and C0 = 65 wt% Cu, one phase is present.

    Cooling and Microstructure

    • During non-equilibrium (cored) cooling of a C0 = 35 wt% Ni alloy, microstructural changes occur due to incomplete diffusion, resulting in coring.
    • During equilibrium cooling of a C0 = 35 wt% Ni alloy, the main mechanism that accomplishes the readjustments is diffusion.

    Microstructure Analysis

    • The photomicrograph of an as-cast bronze alloy found in Syria, dated to the 19th century BC, reveals a dendritic microstructure.

    Cooling Rates and Microstructure

    • In an isomorphous alloy, a slow rate of cooling results in a more homogeneous microstructure.

    Role of Diffusion

    • During equilibrium cooling of a C0 = 35 wt% Ni alloy, diffusion plays a crucial role in both solid and liquid phases, allowing for the readjustments of the microstructure.

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    Description

    Learn about binary phase diagrams in engineering materials, considering phase diagrams at a specified pressure (1 atm) with 2 independent variables: T and C and discussing isomorphous and eutectic binary systems.

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