Bayes Decision Rule

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Questions and Answers

The silicon NRs grown on Au(110) are similar to those obtained on which surface?

  • Cu(100)
  • Ag(110) (correct)
  • Al(111)
  • Pt(111)

What is suggested by the STM images obtained routinely on Ag(110)?

  • Absence of protrusions
  • Formation of diamond structures
  • Formation of complex oxides
  • Similar behavior to Si NRs on Au(110) (correct)

The silicon NRs are composed of how many zig-zag chains of Si atoms?

  • Seven
  • Five (correct)
  • Three
  • Two

What is the approximate width of the silicon NRs grown on Au(110)?

<p>1.6 nm (B)</p> Signup and view all the answers

What kind of structure is seen in the high-resolution STM images of NRs on Ag(110)?

<p>Honeycomb structure (A)</p> Signup and view all the answers

Along the close packed [110] direction, how many Au atomic distances fit on 5 silicene unit cells?

<p>6 (B)</p> Signup and view all the answers

What is the lattice constant used in conjunction with 6 Au atomic distances fitting on 5 silicene unit cells?

<p>0.346 nm (D)</p> Signup and view all the answers

What is the approximate width of the ribbon along the [100] direction, corresponding to about 4 Au lattice constants?

<p>4 silicene rows (B)</p> Signup and view all the answers

What is the approximate Si-Si in-plane nearest neighbor lateral distance deduced from the model?

<p>0.2 nm (C)</p> Signup and view all the answers

What does the high-resolution photoemission spectroscopy data indicate about the silicon core levels?

<p>Si atoms are in two different environments. (C)</p> Signup and view all the answers

The Si NRs present how many zig-zag chains on each side?

<p>One zig-zag chain (D)</p> Signup and view all the answers

Based on the model, what is the fraction for the edge atoms in the unit cell for two zig-zag chain?

<p>0.4 (D)</p> Signup and view all the answers

The silicon NRs widths displayed, are they symmetric across the width?

<p>The widths are asymmetric (C)</p> Signup and view all the answers

What is NOT true about all Si atoms?

<p>Occupy different heights above the surface (D)</p> Signup and view all the answers

What is the primary technique used to observe the internal order of a Si NR with asymmetry across its width?

<p>Scanning Tunneling Microscopy (STM) (C)</p> Signup and view all the answers

What is the typical shape presented by the Si NR with zig-zag edges?

<p>Black honeycomb lattice (C)</p> Signup and view all the answers

In the model for Si NRs on Au(110), what material are the atoms that correspond to the corners of the lozenge made of?

<p>Gold (A)</p> Signup and view all the answers

In Figure 6, what do the light gray and dark gray atoms represent?

<p>The 1st and the 2nd Au layer (B)</p> Signup and view all the answers

The edges of the Au/Si nano-ribbon are composed of?

<p>1 Zig-Zag chains (D)</p> Signup and view all the answers

What does the SOLEIL Project support?

<p>Beam time allocation (C)</p> Signup and view all the answers

Flashcards

Si NRs width on Au(110)

Silicon nanoribbons grown on gold have a width of 1.6 nm.

Si atom environments

High-resolution photoemission spectroscopy reveals Si atoms exist in two distinct locations.

Si NRs height consistency

All silicon atoms reside at the same height over the gold surface.

Observed Characteristics

Metallic, suggesting silicene NRs have been formed on the gold surface.

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Si-Si Distance

The observed length of the Si-Si bonds here will underestimate its true length.

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NR Chain Structure

Silicon nanoribbons are composed of five zig-zag chains of silicon atoms running the length of the ribbon.

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Edge Composition

The edge of the NR have two zig-zag chains

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Si NRs on Au(110)

Nano-sized structures of silicon atoms arranged in a specific pattern on a gold surface.

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STM topographies and Quantum Interference

These images might be related to electron quantum interference at the NR edges as seen in graphene.

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Study Notes

  • Objective is to reduce error probability in classification.
  • Requires prior probabilities $P(ω_i)$ and conditional probability density functions $p(x|ω_i)$.

Bayes Formula

  • Describes the relationship between conditional and posterior probabilities:

    $P(ω_i|x) = \frac{p(x|ω_i)P(ω_i)}{p(x)}$

    • $p(x) = \sum_{i=1}^{c} p(x|ω_i)P(ω_i)$
  • A posteriori probability: $P(ω_i|x)$ is the probability of category $ω_i$ given observation $x$.

  • Bayes decision rule: Assign to $ω_1$ if $P(ω_1|x) > P(ω_2|x)$, otherwise assign to $ω_2$.

Minimum Error Rate

  • Classification error is $P(error|x) = min[P(ω_1|x), P(ω_2|x)]$.
  • To minimize error, select $ω_i$ if $P(ω_i|x) > P(ω_j|x)$ for all $j \neq i$.

Discriminant Functions

  • Decision boundaries can be defined using discriminant functions $g_i(x)$.
  • Assign to $ω_i$ if $g_i(x) > g_j(x)$ for all $j \neq i$.
  • Possible forms:
    • $g_i(x) = P(ω_i|x)$
    • $g_i(x) = p(x|ω_i)P(ω_i)$
    • $g_i(x) = ln p(x|ω_i) + ln P(ω_i)$

Two-Category Case

  • Can define a single discriminant function $g(x) = P(ω_1|x) - P(ω_2|x)$.
  • Assign to $ω_1$ if $g(x) > 0$, and $ω_2$ if $g(x) < 0$.
  • Likelihood ratio: $l(x) = \frac{p(x|ω_1)}{p(x|ω_2)}$.
  • Decide $ω_1$ if $l(x) > \frac{P(ω_2)}{P(ω_1)}$, otherwise decide $ω_2$.

Cost Functions

  • Let $\alpha_i$ represent the action of deciding the state of nature is $ω_i$

  • $\lambda_{ij} = \lambda(\alpha_i|ω_j)$ is the cost of action $\alpha_i$ when the true state is $ω_j$.

  • Expected cost of action $\alpha_i$:

    $R(\alpha_i|x) = \sum_{j=1}^{c} \lambda_{ij}P(ω_j|x)$

  • Bayes decision rule: Minimize expected cost $R(\alpha_i|x)$.

Minimum Error Rate

  • Cost function: $\lambda_{ij} = 0$ if $i = j$, and $\lambda_{ij} = 1$ if $i \neq j$.
  • Risk: $R(\alpha_i|x) = \sum_{j=1}^{c} \lambda_{ij}P(ω_j|x) = \sum_{j \neq i} P(ω_j|x) = 1 - P(ω_i|x)$.
  • Minimizing risk is equivalent to maximizing $P(ω_i|x)$.

Bayes Classifier

  • Uses Bayes decision rule to minimize expected cost.
  • Requires:
    • Prior probabilities $P(ω_i)$.
    • Conditional probability density functions $p(x|ω_i)$.
    • Cost functions $\lambda_{ij}$.

Curse of Dimensionality

  • The number of training samples needed to accurately estimate probability density functions increases exponentially with the dimensionality of the feature space.

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