Barium Hydroxide in Acid-Alkali Titration
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Questions and Answers

How can barium hydroxide solutions be kept free from carbonates?

  • Absorb carbon dioxide using soda-lime absorption tubes
  • Precipitate absorbed carbon dioxide as insoluble barium carbonate (correct)
  • Standardize against normal sodium hydroxide solution
  • Standardize titrimetrically against sodium carbonate

How should alkali solutions be prepared to ensure they are free from carbon dioxide?

  • Protect from carbon dioxide using soda-lime absorption tubes (correct)
  • Standardize against pure sodium carbonate
  • Standardize gravimetrically by precipitation of silver chloride
  • Standardize titrimetrically against normal hydrochloric acid solution

What is a suitable method for standardizing alkali solutions like sodium hydroxide or potassium hydroxide?

  • Titration against sodium carbonate with phenolphthalein as an indicator
  • Using a standard solution of hydrochloric or sulphuric acid as a primary standard (correct)
  • Precipitating an equivalent amount of silver chloride
  • Standardizing against pure sodium carbonate

How is the standardization of sulfuric acid solution typically done?

<p>By titration against sodium carbonate or normal sodium hydroxide solution (D)</p> Signup and view all the answers

What is a primary standard that can be used to standardize alkali solutions?

<p>Potassium biphthalate (D)</p> Signup and view all the answers

Why should all alkali solutions be re-standardized frequently?

<p>To ensure their accuracy over time (A)</p> Signup and view all the answers

What is the purpose of using an indicator in a titration process?

<p>To indicate when equivalent quantities of analyte and titrant have reacted (B)</p> Signup and view all the answers

Why is it crucial to use carbon dioxide-free water in the preparation of 1N NaOH?

<p>To prevent the formation of carbonates in sodium hydroxide caused by carbon dioxide (C)</p> Signup and view all the answers

What does a primary standard refer to in the context of this text?

<p>Complex organic compounds used for standardization (C)</p> Signup and view all the answers

How is phenolphthalein used as an indicator in titrations?

<p>It turns pink at a slightly basic pH (C)</p> Signup and view all the answers

What is the endpoint observed when phenolphthalein is used as an indicator in neutralization reactions?

<p>Faint pink (A)</p> Signup and view all the answers

Why should sodium hydroxide pellets be dissolved in carbon dioxide-free water?

<p>To avoid forming carbonates in sodium hydroxide due to carbon dioxide (B)</p> Signup and view all the answers

What is the formula used for calculating the weight percentage of a substance?

<p>V x NF x Titer x 100 (A)</p> Signup and view all the answers

Which standard alkali solutions are commonly used in acidimetry and alkalimetry?

<p>Sodium hydroxide, potassium hydroxide, and barium hydroxide (A)</p> Signup and view all the answers

In which type of titration is hydrochloric acid preferable over sulfuric acid?

<p>In titrations where a precipitate is formed (D)</p> Signup and view all the answers

What happens to standard alkali solutions like sodium hydroxide and potassium hydroxide over time?

<p>They absorb carbon dioxide and may be contaminated with carbonates (B)</p> Signup and view all the answers

Why is sulfuric acid preferable over hydrochloric acid in hot titrations?

<p>There is no danger of loss due to volatilization (D)</p> Signup and view all the answers

What may impair the usefulness of standard alkali solutions?

<p>Absorption of carbon dioxide and contamination with carbonates (C)</p> Signup and view all the answers

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