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Questions and Answers
What does the term 'atom' signify in Greek?
What does the term 'atom' signify in Greek?
In John Dalton's atomic theory, what is stated about atoms of the same element?
In John Dalton's atomic theory, what is stated about atoms of the same element?
Which scientist discovered the electron and what was the method used?
Which scientist discovered the electron and what was the method used?
How do atoms of sodium (Na) and chlorine (Cl) achieve stability during the formation of sodium chloride?
How do atoms of sodium (Na) and chlorine (Cl) achieve stability during the formation of sodium chloride?
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According to modern atomic theory, what distinguishes isotopes of the same element?
According to modern atomic theory, what distinguishes isotopes of the same element?
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Which experiment involved electric discharge through a gas at low pressure to observe blue rays?
Which experiment involved electric discharge through a gas at low pressure to observe blue rays?
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What particles are considered the fundamental components of an atom in modern atomic theory?
What particles are considered the fundamental components of an atom in modern atomic theory?
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What distinguishes cathode rays as discovered by J.J. Thomson in his experiment?
What distinguishes cathode rays as discovered by J.J. Thomson in his experiment?
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What determines the maximum number of electrons in each shell or orbit?
What determines the maximum number of electrons in each shell or orbit?
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Which of the following statements about protons is true?
Which of the following statements about protons is true?
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What is the primary characteristic of isotopes?
What is the primary characteristic of isotopes?
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Which shell can hold a maximum of 8 electrons?
Which shell can hold a maximum of 8 electrons?
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What happens to an atom with an unstable electronic configuration?
What happens to an atom with an unstable electronic configuration?
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Which of the following accurately describes the nucleus of an atom?
Which of the following accurately describes the nucleus of an atom?
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What rule governs the stability of an atom's outermost shell when it has multiple shells?
What rule governs the stability of an atom's outermost shell when it has multiple shells?
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Who discovered the atomic nucleus through their experiments?
Who discovered the atomic nucleus through their experiments?
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What is the atomic number of an element equal to?
What is the atomic number of an element equal to?
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What does the term 'valency' refer to in chemistry?
What does the term 'valency' refer to in chemistry?
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Which of the following statements correctly compares the views of Kanada and Dalton regarding atoms?
Which of the following statements correctly compares the views of Kanada and Dalton regarding atoms?
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What was the primary observation made by Goldstein that led to the discovery of protons?
What was the primary observation made by Goldstein that led to the discovery of protons?
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In the context of the formation of sodium chloride, which statement accurately describes the role of electron transfer?
In the context of the formation of sodium chloride, which statement accurately describes the role of electron transfer?
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What aspect of cathode rays was notably characterized by J.J. Thomson in his experiments?
What aspect of cathode rays was notably characterized by J.J. Thomson in his experiments?
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Which of the following best describes the modern understanding of atomic structure compared to Dalton's atomic theory?
Which of the following best describes the modern understanding of atomic structure compared to Dalton's atomic theory?
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What outcome does an atom achieve by obtaining a stable electronic configuration?
What outcome does an atom achieve by obtaining a stable electronic configuration?
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Which feature of isotopes is correctly described?
Which feature of isotopes is correctly described?
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What conclusion can be drawn about electrons based on J.J. Thomson's experiments?
What conclusion can be drawn about electrons based on J.J. Thomson's experiments?
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What is the primary governing rule for the filling of electron shells in an atom?
What is the primary governing rule for the filling of electron shells in an atom?
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Which of the following accurately represents the mass number of an element?
Which of the following accurately represents the mass number of an element?
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Which rule must an atom follow for its outermost shell to achieve stability when it has multiple shells?
Which rule must an atom follow for its outermost shell to achieve stability when it has multiple shells?
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What does the term 'isotope' refer to in the context of atomic structure?
What does the term 'isotope' refer to in the context of atomic structure?
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Which type of particle is specifically defined as having a positive charge and a unit mass?
Which type of particle is specifically defined as having a positive charge and a unit mass?
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What happens to elements with an unstable electronic configuration in terms of electron interaction?
What happens to elements with an unstable electronic configuration in terms of electron interaction?
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Which of the following statements about the distribution of electrons in atomic shells is true?
Which of the following statements about the distribution of electrons in atomic shells is true?
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What did Rutherford's experiment with alpha particles reveal about atomic structure?
What did Rutherford's experiment with alpha particles reveal about atomic structure?
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Which statement best describes the concept of valency in chemical bonding?
Which statement best describes the concept of valency in chemical bonding?
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What is the electronic configuration for the K shell and how many electrons does it hold?
What is the electronic configuration for the K shell and how many electrons does it hold?
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The term 'atom' comes from a Greek word meaning '____________'.
The term 'atom' comes from a Greek word meaning '____________'.
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In modern atomic theory, atoms are considered ___________ and divisible.
In modern atomic theory, atoms are considered ___________ and divisible.
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J.J. Thomson is known for the discovery of ___________ through his experiments with cathode rays.
J.J. Thomson is known for the discovery of ___________ through his experiments with cathode rays.
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Kanada referred to these fundamental particles as ___________ in his atomic concept.
Kanada referred to these fundamental particles as ___________ in his atomic concept.
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Goldstein discovered ___________ rays, which were crucial for identifying protons.
Goldstein discovered ___________ rays, which were crucial for identifying protons.
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The electronic configuration of sodium (Na) is ___________.
The electronic configuration of sodium (Na) is ___________.
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To achieve stability, chlorine (Cl) gains one ___________ from sodium.
To achieve stability, chlorine (Cl) gains one ___________ from sodium.
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___________ contributed to the atomic theory by stating that atoms of the same element are alike in all respects.
___________ contributed to the atomic theory by stating that atoms of the same element are alike in all respects.
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The cathode rays consisted of negatively charged sub-atomic particles called ______.
The cathode rays consisted of negatively charged sub-atomic particles called ______.
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Goldstein concluded that anode rays or positive rays consist of positively charged particles called ______.
Goldstein concluded that anode rays or positive rays consist of positively charged particles called ______.
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Lord Rutherford discovered the atomic ______ through his experiments with alpha particles.
Lord Rutherford discovered the atomic ______ through his experiments with alpha particles.
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The maximum number of electrons in each shell or orbit is determined by the formula ______.
The maximum number of electrons in each shell or orbit is determined by the formula ______.
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Noble gases have stable electronic configuration with ______ electrons in their outer shell.
Noble gases have stable electronic configuration with ______ electrons in their outer shell.
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Atoms of other elements have unstable electronic configuration and tend to attain ______ electronic configuration.
Atoms of other elements have unstable electronic configuration and tend to attain ______ electronic configuration.
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The atomic number of an element is equal to the number of ______ in the atom.
The atomic number of an element is equal to the number of ______ in the atom.
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Isotopes are atoms of the same element having the same atomic number but different ______ numbers.
Isotopes are atoms of the same element having the same atomic number but different ______ numbers.
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Valency is the number of hydrogen atoms which can combine with one atom of the element or ______.
Valency is the number of hydrogen atoms which can combine with one atom of the element or ______.
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Mendeleeff classified elements in a table called the Modern ______ table.
Mendeleeff classified elements in a table called the Modern ______ table.
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An atom is a particle that is considered __________ in modern atomic theory.
An atom is a particle that is considered __________ in modern atomic theory.
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Kanada's concept of an atom involved particles known as __________.
Kanada's concept of an atom involved particles known as __________.
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Goldstein's experiments led to the discovery of __________ rays.
Goldstein's experiments led to the discovery of __________ rays.
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The electronic configuration of Sodium (Na) is __________.
The electronic configuration of Sodium (Na) is __________.
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In the formation of sodium chloride, Chlorine (Cl) gains one __________ from Sodium.
In the formation of sodium chloride, Chlorine (Cl) gains one __________ from Sodium.
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J.J. Thomson is credited with the discovery of __________ as a component of cathode rays.
J.J. Thomson is credited with the discovery of __________ as a component of cathode rays.
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Lord Rutherford discovered the atomic __________ through his alpha particle experiments.
Lord Rutherford discovered the atomic __________ through his alpha particle experiments.
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According to Dalton's atomic theory, atoms of the same element are __________ in all respects.
According to Dalton's atomic theory, atoms of the same element are __________ in all respects.
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The negatively charged sub-atomic particles are called ______.
The negatively charged sub-atomic particles are called ______.
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Goldstein observed anode rays, which consist of positively charged particles called ______.
Goldstein observed anode rays, which consist of positively charged particles called ______.
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The center of an atom, containing protons and neutrons, is known as the ______.
The center of an atom, containing protons and neutrons, is known as the ______.
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Rutherford's experiment revealed that the atomic nucleus contains a concentrated ______ mass.
Rutherford's experiment revealed that the atomic nucleus contains a concentrated ______ mass.
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The maximum number of electrons in each shell is determined by the formula ______.
The maximum number of electrons in each shell is determined by the formula ______.
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The outermost shell of an atom requires ______ electrons for stability if it has multiple shells.
The outermost shell of an atom requires ______ electrons for stability if it has multiple shells.
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Atoms with an unstable electronic configuration tend to gain or lose ______ to achieve stability.
Atoms with an unstable electronic configuration tend to gain or lose ______ to achieve stability.
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To form a compound with chlorine, one atom of hydrogen combines with one atom of ______.
To form a compound with chlorine, one atom of hydrogen combines with one atom of ______.
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The ______ gas elements have stable electronic configurations and do not readily react with other elements.
The ______ gas elements have stable electronic configurations and do not readily react with other elements.
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Isotopes are atoms of the same element that have the same atomic number but different ______ numbers.
Isotopes are atoms of the same element that have the same atomic number but different ______ numbers.
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The Greek word 'atom' means 'indivisible'.
The Greek word 'atom' means 'indivisible'.
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Dalton's atomic theory claims that atoms can be destroyed and are not the smallest particles of an element.
Dalton's atomic theory claims that atoms can be destroyed and are not the smallest particles of an element.
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Isotopes of the same element have identical atomic structures.
Isotopes of the same element have identical atomic structures.
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J.J. Thomson discovered electrons through his experiments with cathode rays.
J.J. Thomson discovered electrons through his experiments with cathode rays.
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The electronic configuration of chlorine (Cl) is 2,8,7.
The electronic configuration of chlorine (Cl) is 2,8,7.
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Kanada conceptualized the idea of atoms being made up of particles called 'paramanus'.
Kanada conceptualized the idea of atoms being made up of particles called 'paramanus'.
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William Crookes is credited with the discovery of protons.
William Crookes is credited with the discovery of protons.
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Modern atomic theory maintains that atoms consist of protons, electrons, and neutrons.
Modern atomic theory maintains that atoms consist of protons, electrons, and neutrons.
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Electrons revolve around the nucleus in imaginary paths called orbits or skies.
Electrons revolve around the nucleus in imaginary paths called orbits or skies.
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Protons carry a negative charge and a unit mass.
Protons carry a negative charge and a unit mass.
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Anode rays consist of positively charged particles called protons.
Anode rays consist of positively charged particles called protons.
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Isotopes are atoms of the same element with different atomic numbers.
Isotopes are atoms of the same element with different atomic numbers.
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The maximum number of electrons in each shell is determined by the formula 2n^2.
The maximum number of electrons in each shell is determined by the formula 2n^2.
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The nucleus contains protons and electrons.
The nucleus contains protons and electrons.
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Stable electronic configuration for noble gases requires 2 or 8 electrons in their outer shell.
Stable electronic configuration for noble gases requires 2 or 8 electrons in their outer shell.
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The mass number is the total number of protons and electrons in the atom.
The mass number is the total number of protons and electrons in the atom.
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Electrons carry a positive charge and negligible mass.
Electrons carry a positive charge and negligible mass.
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Rutherford's experiment showed that atoms are mostly empty space with a concentrated positive mass in the center.
Rutherford's experiment showed that atoms are mostly empty space with a concentrated positive mass in the center.
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The term 'atom' originates from a Latin word meaning 'indivisible'.
The term 'atom' originates from a Latin word meaning 'indivisible'.
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John Dalton's atomic theory states that atoms of different elements are identical in all aspects.
John Dalton's atomic theory states that atoms of different elements are identical in all aspects.
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Goldstein discovered positively charged particles known as electrons.
Goldstein discovered positively charged particles known as electrons.
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In modern atomic theory, atoms are described as both destructible and indivisible.
In modern atomic theory, atoms are described as both destructible and indivisible.
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Isotopes are variants of the same element that have different numbers of protons.
Isotopes are variants of the same element that have different numbers of protons.
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To achieve stability, sodium (Na) loses one electron to chlorine (Cl).
To achieve stability, sodium (Na) loses one electron to chlorine (Cl).
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Kanada referred to the smallest particles of matter as atoms.
Kanada referred to the smallest particles of matter as atoms.
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Cathode rays were discovered by J.J. Thomson and consist of negatively charged particles.
Cathode rays were discovered by J.J. Thomson and consist of negatively charged particles.
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Protons are negatively charged particles found in the nucleus of an atom.
Protons are negatively charged particles found in the nucleus of an atom.
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The maximum number of electrons in the L shell is 8, as calculated using the formula 2n2.
The maximum number of electrons in the L shell is 8, as calculated using the formula 2n2.
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Neutrons carry a positive charge and contribute to the mass of the nucleus.
Neutrons carry a positive charge and contribute to the mass of the nucleus.
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Electrons occupy orbits or shells around the nucleus in a step-wise manner.
Electrons occupy orbits or shells around the nucleus in a step-wise manner.
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A stable electronic configuration is achieved when atoms have either 2 or 8 electrons in their outermost shell.
A stable electronic configuration is achieved when atoms have either 2 or 8 electrons in their outermost shell.
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Isotopes are atoms that have different atomic numbers but the same mass number.
Isotopes are atoms that have different atomic numbers but the same mass number.
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Lord Rutherford concluded that the atom is mostly solid with no empty space.
Lord Rutherford concluded that the atom is mostly solid with no empty space.
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Goldstein's experiment involved a perforated cathode that allowed the observation of anode rays.
Goldstein's experiment involved a perforated cathode that allowed the observation of anode rays.
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The atomic number of an element is determined by the total number of neutrons in its nucleus.
The atomic number of an element is determined by the total number of neutrons in its nucleus.
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The molecular weight of a substance is determined by how many times one molecule is heavier than an atom of hydrogen.
The molecular weight of a substance is determined by how many times one molecule is heavier than an atom of hydrogen.
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What are the three main sub-atomic particles that make up an atom?
What are the three main sub-atomic particles that make up an atom?
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What did Rutherford's experiment with gold foil reveal about atomic structure?
What did Rutherford's experiment with gold foil reveal about atomic structure?
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What are anode rays, and how did Goldstein contribute to their discovery?
What are anode rays, and how did Goldstein contribute to their discovery?
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According to the electron shell model, what is the maximum number of electrons that the L shell can hold?
According to the electron shell model, what is the maximum number of electrons that the L shell can hold?
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What is the difference between stable and unstable electronic configurations?
What is the difference between stable and unstable electronic configurations?
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What determines the atomic number of an element?
What determines the atomic number of an element?
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Define isotopes and give an example.
Define isotopes and give an example.
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What is the significance of the octet rule in chemistry?
What is the significance of the octet rule in chemistry?
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What are the charges and mass characteristics of protons and neutrons?
What are the charges and mass characteristics of protons and neutrons?
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Explain what valency means in the context of chemical bonding.
Explain what valency means in the context of chemical bonding.
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What did Kanada propose about the structure of matter?
What did Kanada propose about the structure of matter?
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How did John Dalton describe the nature of atoms?
How did John Dalton describe the nature of atoms?
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What observation did J.J. Thomson make regarding cathode rays?
What observation did J.J. Thomson make regarding cathode rays?
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What was the main conclusion drawn from Goldstein's experiment with anode rays?
What was the main conclusion drawn from Goldstein's experiment with anode rays?
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How do sodium (Na) and chlorine (Cl) achieve a stable electronic configuration?
How do sodium (Na) and chlorine (Cl) achieve a stable electronic configuration?
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What significant difference exists between Dalton's atomic theory and modern atomic theory?
What significant difference exists between Dalton's atomic theory and modern atomic theory?
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What role did William Crookes play in the study of atomic structure?
What role did William Crookes play in the study of atomic structure?
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What does the term 'isotope' refer to in atomic terms?
What does the term 'isotope' refer to in atomic terms?
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Explain the significance of Kanada's concept of 'paramanus' in relation to atomic theory.
Explain the significance of Kanada's concept of 'paramanus' in relation to atomic theory.
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What conclusion can be drawn about the discovery of electrons from J.J. Thomson’s experiments?
What conclusion can be drawn about the discovery of electrons from J.J. Thomson’s experiments?
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How does Dalton's atomic theory differ from the modern atomic theory regarding atomic properties?
How does Dalton's atomic theory differ from the modern atomic theory regarding atomic properties?
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Describe the process by which sodium (Na) and chlorine (Cl) form sodium chloride (NaCl).
Describe the process by which sodium (Na) and chlorine (Cl) form sodium chloride (NaCl).
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What is the role of electron transfer in achieving stability for atoms during chemical reactions?
What is the role of electron transfer in achieving stability for atoms during chemical reactions?
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What observation did Goldstein make that led to the identification of protons?
What observation did Goldstein make that led to the identification of protons?
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In what way did Thomson's experiments challenge earlier notions about atomic structure?
In what way did Thomson's experiments challenge earlier notions about atomic structure?
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How does the electronic configuration of elements relate to their chemical properties?
How does the electronic configuration of elements relate to their chemical properties?
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What are the main three sub-atomic particles that make up an atom?
What are the main three sub-atomic particles that make up an atom?
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What experimental observation led to Rutherford's conclusion about the atomic nucleus?
What experimental observation led to Rutherford's conclusion about the atomic nucleus?
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How does the maximum number of electrons in a shell relate to the shell's principal quantum number, n?
How does the maximum number of electrons in a shell relate to the shell's principal quantum number, n?
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What is the significance of noble gases in terms of electronic configuration?
What is the significance of noble gases in terms of electronic configuration?
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What defines isotopes of an element?
What defines isotopes of an element?
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Describe how electrons are distributed within the atomic shells.
Describe how electrons are distributed within the atomic shells.
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What role do protons play in defining an element?
What role do protons play in defining an element?
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Why do atoms with unstable electronic configurations tend to gain or lose electrons?
Why do atoms with unstable electronic configurations tend to gain or lose electrons?
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What is the relationship between atomic number and the number of electrons in a neutral atom?
What is the relationship between atomic number and the number of electrons in a neutral atom?
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In terms of chemical bonding, what is valency?
In terms of chemical bonding, what is valency?
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Study Notes
Introduction
- The concept of atoms, the smallest indivisible particles of matter, was proposed by ancient Indian and Greek philosophers.
- John Dalton refined this concept with his Atomic Theory, proposing that atoms were indestructible and indivisible, forming the basis of modern chemistry.
- Later scientists like J.J. Thomson, Goldstein, Rutherford, and Chadwick further contributed to our understanding of atomic structure by discovering subatomic particles like electrons, protons, and neutrons.
Ancient Views of Atomic Structure
- Kanada, an Indian philosopher, proposed the concept of 'paramanus' (atoms) as the fundamental building blocks of matter.
- He believed that the combination of two atoms creates a 'dvyanuka' (molecule).
Dalton's Atomic Theory
- Atoms are the smallest particles of an element.
- Atoms of the same element are identical in all respects.
- Atoms are indestructible and indivisible.
Subatomic Particles
- Electrons: Discovered by J.J. Thomson, negatively charged particles found in the cathode rays of a discharge tube.
- Protons: Discovered by Goldstein, positively charged particles found in the anode rays of a modified discharge tube.
- Neutrons: Discovered by Chadwick, neutral particles found in the nucleus of an atom.
Formation of Compounds
- Atoms achieve stability by attaining a complete outer shell like noble gases (2 electrons for the first shell, 8 electrons for the other shells).
- Sodium (Na) loses one electron to achieve stability and becomes positively charged, while chlorine (Cl) gains one electron to achieve stability and becomes negatively charged.
- This transfer of electrons leads to the formation of ionic compounds like sodium chloride (NaCl).
Rutherford's Atomic Model
- Rutherford's gold foil experiment demonstrated the existence of a positively charged nucleus at the center of an atom.
- Electrons revolve around the nucleus in specific orbits or shells.
Electronic Configuration
- Each shell or orbit can hold a maximum number of electrons determined by the formula 2n², where n is the shell number.
- The outer shell of an atom aims to achieve stability by following the duet rule (2 electrons) for the first shell or the octet rule (8 electrons) for subsequent shells.
Nuclear Structure
- The nucleus of an atom is positively charged and contains protons and neutrons.
Modern Periodic Table
- Dmitri Mendeleev organized elements in a table based on their increasing atomic numbers, creating the modern periodic table.
Atomic Terms Definitions
- Atomic Number (Z): The number of protons in an atom, which also equals the number of electrons.
- Mass Number (A): The total number of protons and neutrons in an atom.
- Atomic Weight or Relative Atomic Mass: The mass of an atom relative to the mass of a hydrogen atom.
- Molecular Weight or Relative Molecular Mass: The mass of a molecule relative to the mass of a hydrogen atom.
Isotopes
- Isotopes are atoms of the same element with the same atomic number (Z) but different mass numbers (A). This difference arises from the varying number of neutrons in the atom.
Valency
- Valency describes an atom's ability to combine with other atoms, specifically, the number of hydrogen atoms an atom can combine with or displace.
Stable Electronic Configuration
- Noble gases have a stable electronic configuration because their outer (valence) shell is already complete, with either 2 or 8 electrons.
Unstable Electronic Configuration
- Most other elements have unstable electronic configurations, with incomplete valence shells.
- To achieve stability, they gain, lose, or share electrons to attain the stable configuration of the nearest noble gas.
Ancient Views of Atomic Structure
- The idea that matter is made up of incredibly small particles was first proposed by ancient Indian and Greek philosophers.
- Kanada, an Indian philosopher, believed matter is made up of particles called “paramanus” (atoms).
- When two atoms combine, they form a “dvyanuka,” and three atoms form a “tryanuka”.
Dalton’s Atomic Theory
- John Dalton's theory explained chemical observations, including the Laws of Constant Proportions and Multiple Proportions.
- Atoms are the smallest particles of an element and are indestructible and indivisible.
- Atoms of the same element are alike in all respects.
Subatomic Particles
- Atoms are divisible and consist of protons, electrons, and neutrons.
- Discovery of electrons: J.J. Thomson observed that cathode rays were deflected by a positively charged plate in a discharge tube. This led him to believe that cathode rays were made up of negatively charged particles, which he called electrons.
- Discovery of protons: Goldstein observed anode rays passing through a perforated cathode in a modified discharge tube. These rays were deflected by electric and magnetic fields in a direction opposite to that of cathode rays. This led to the discovery of positively charged particles called protons.
- Discovery of the atomic nucleus: Rutherford conducted an experiment where he bombarded a thin gold foil with alpha particles. Most particles passed through the foil, but some were deflected by small and large angles. This led to the conclusion that the atom is mostly empty, and a small, dense, positively charged nucleus is in the center.
Electronic Configuration
- Stable Electronic Configuration: Noble gases have a stable electronic configuration because their outer shells are complete, containing two (He) or eight (Ne, Ar, Kr, Xe, Rn) electrons. They do not gain, lose, or share electrons.
- Unstable Electronic Configuration: Other elements have unstable electronic configurations with incomplete outer shells. To achieve stability, they tend to gain or lose electrons to achieve the electronic configuration of the nearest noble gas.
Atom Structure Key Points
- Nucleus: Located at the center of the atom and contains protons (positively charged) and neutrons (no charge).
- Orbits (Shells): Imaginary paths around the nucleus where electrons revolve.
- Protons: Positively charged with a unit mass.
- Neutrons: No charge with a unit mass.
- Electrons: Negatively charged with a negligible mass.
Atomic Number (Z)
- The atomic number is equal to the number of protons in an atom of an element.
- Since atoms are neutral, the atomic number also equals the number of electrons.
Mass Number (A)
- The mass number of an element is equal to the total number of protons and neutrons in the atom.
Atomic Weight (Relative Atomic Mass)
- Atomic weight or relative atomic mass is the number of times an atom of an element is heavier than the mass of one atom of hydrogen.
Molecular Weight (Relative Molecular Mass)
- Molecular weight or relative molecular mass is the number of times one molecule of the substance is heavier than one atom of hydrogen.
Isotopes
- Isotopes are atoms of the same element that have the same atomic number (Z) but different mass numbers (A). For example, hydrogen has three isotopes: protium, deuterium, and tritium.
Valency
- Valency is the number of hydrogen atoms that one atom of an element or radical can combine with or displace when forming a compound.
Modern Periodic Table
- Mendeleev arranged the elements systematically in a table, the Modern Periodic Table.
- Elements are arranged in increasing order of atomic number.
Ancient Views of Atomic Structure
- The concept that all matter is composed of extremely small particles was proposed by ancient Indian and Greek philosophers.
- Kanada, an Indian philosopher, theorized that matter is made up of particles called paramanus (atoms).
- Dalton's atomic theory explained that all matter is made up of atoms, which are indivisible and indestructible.
- Dalton's theory also stated that all atoms of the same element are identical in mass and properties.
Discovery of Sub-Atomic Particles
- J.J. Thomson discovered electrons. Using a cathode ray tube, he observed that negatively charged particles, which he called electrons, were emitted from the cathode.
- Goldstein discovered protons. In a modified cathode ray tube with a perforated cathode, he observed positively charged particles called anode rays or protons.
- Rutherford discovered the nucleus. He bombarded a thin gold foil with alpha particles and observed that most passed straight through, while some were deflected at various angles. He concluded that atoms have a dense, positively charged center called the nucleus. The nucleus is surrounded by electrons that occupy specific orbits or shells.
Atomic Structure
- Atoms are composed of three sub-atomic particles: protons, neutrons, and electrons.
- The nucleus is located at the center of the atom and contains protons and neutrons.
- Electrons revolve around the nucleus in specific paths called orbits or shells.
- Protons have a positive charge (+1) and a mass of one atomic mass unit (amu).
- Neutrons have no charge (neutral) and a mass of one atomic mass unit (amu).
- Electrons have a negative charge (-1) and a negligible mass.
Electronic Configuration and Chemical Bonding
- Electronic configuration describes the arrangement of electrons in an atom's shells.
- Noble gases, like Helium (He) and Neon (Ne), have completely filled outermost shells, making them stable.
- Atoms tend to gain, lose, or share electrons to achieve a stable electronic configuration like the nearest noble gas.
- Electron transfer leads to the formation of ionic compounds. For example, Sodium (Na), with one electron in its outermost shell, loses it to Chlorine Cl (with seven electrons in its outermost shell) to achieve a stable configuration. This results in the formation of sodium chloride (NaCl).
Atomic and Mass Numbers
- Atomic number (Z) represents the number of protons in an atom. It is also equal to the number of electrons in a neutral atom.
- Mass number (A) represents the total number of protons and neutrons in an atom.
- Atomic weight (relative atomic mass) is the average mass of an atom of an element relative to the mass of an atom of carbon-12.
- Molecular weight (relative molecular mass) is the sum of the atomic weights of all the atoms in a molecule.
Isotopes
- Isotopes are atoms of the same element that have the same atomic number but different mass numbers.
- Isotopes have the same number of protons but different numbers of neutrons.
Valency
- Valency is the number of electrons an atom can gain, lose, or share to form chemical bonds.
- It determines the combining capacity of an element.
Stable Electronic Configuration
- Atoms with a full outermost shell (2 or 8 electrons) are considered stable, like noble gases.
Unstable Electronic Configuration
- Atoms with an incomplete outermost shell are considered unstable. They tend to gain, lose, or share electrons to achieve a stable configuration like the nearest noble gas.
Atomic Structure: Introduction
- Idea of indivisible particles (atoms) originated with ancient Indian and Greek philosophers.
- John Dalton's atomic theory formulated the basis for modern chemistry.
Dalton's Atomic Theory
- Postulated that atoms are the smallest indivisible particles of an element.
- Atoms of the same element are identical in all respects.
Modern Atomic Theory
- Atoms are divisible, made up of subatomic particles: protons, neutrons, and electrons.
- Atoms of the same element may not be identical (isotopes).
Subatomic Particles: Discovery and Properties
-
Electrons: Discovered by J.J. Thomson through cathode ray experiments.
- Cathode rays deflected by a positively charged plate, indicating the presence of negatively charged particles.
-
Protons: Discovered by Goldstein using modified cathode ray tubes.
- Anode rays (positive rays) deflected in the opposite direction to cathode rays, composed of positively charged particles.
-
Neutrons: Discovered by Chadwick.
- Uncharged particles found in the nucleus.
Atomic Structure
-
Nucleus:
- Located at the center of the atom.
- Contains protons and neutrons.
-
Electrons:
- Revolve around the nucleus in specific paths called orbits or shells.
Electronic Configuration
-
Electrons in Shells:
- The number of electrons in each shell is determined by the formula 2n², where n is the shell number.
- K shell (n=1): 2 electrons.
- L shell (n=2): 8 electrons.
- M shell (n=3): 18 electrons.
- The number of electrons in each shell is determined by the formula 2n², where n is the shell number.
-
Stability:
- Atoms strive for stability by achieving a full outer shell (octet rule) or duplet rule (for atoms with one shell).
- This involves gaining, losing, or sharing electrons.
Atomic Terminology
-
Atomic Number (Z):
- Represents the number of protons in an atom of an element.
- Equal to the number of electrons in a neutral atom.
-
Mass Number (A):
- The total number of protons and neutrons in an atom.
-
Atomic Weight (Relative Atomic Mass):
- The relative mass of an atom of an element compared to the mass of a hydrogen atom.
-
Molecular Weight (Relative Molecular Mass):
- The relative mass of a molecule compared to the mass of a hydrogen atom.
Isotopes
- Atoms of the same element with the same atomic number but different mass numbers.
- Differing mass numbers are due to variations in the number of neutrons.
Valency
- Represents the combining capacity of an atom or radical with other atoms.
- Determined by the number of electrons an atom gains, loses, or shares to achieve stability.
Stable and Unstable Electronic Configurations
-
Noble Gases:
- Have stable electronic configurations with complete outer shells.
- Do not readily gain, lose, or share electrons.
-
Other Elements:
- Possess unstable electronic configurations with incomplete outer shells.
- Tend to gain, lose, or share electrons to achieve the stable electronic configuration of the nearest noble gas.
Modern Periodic Table
- Elements are arranged systematically in order of increasing atomic numbers, reflecting periodicity in their properties.
Ancient Views of Atomic Structure
- The concept of matter being made up of tiny particles was proposed by Indian and Greek philosophers.
- Kanada, an Indian philosopher, used the term "paramanu" to describe these particles, which are now known as atoms.
Dalton's Atomic Theory
- Dalton proposed that atoms are the smallest indivisible particles of an element.
- Atoms of the same element are identical in all respects.
Sub-Atomic Particles
- Electrons: Discovered by J.J.Thomson through experiments with cathode rays. Electrons are negatively charged particles found outside the nucleus.
- Protons: Discovered by Goldstein through experiments with anode rays. Protons are positively charged particles located in the nucleus.
- Neutrons: Discovered by Chadwick. Neutrons are neutral particles located in the nucleus.
Formation of Compounds
- Atoms of elements can combine to form compounds by gaining or losing electrons to achieve a stable electronic configuration mimicking the nearest noble gas.
- For example, sodium (Na) loses one electron to achieve a stable configuration like Neon (Ne), while chlorine (Cl) gains one electron to achieve a stable configuration like Argon (Ar). This transfer of electrons results in the formation of sodium chloride (NaCl).
Atomic Structure
- Nucleus: The dense, positively charged center of an atom containing protons and neutrons.
- Orbits/Shells: Imaginary paths around the nucleus where electrons revolve.
- Electron Distribution: The number of electrons in each shell can be determined using the formula 2n², where 'n' represents the shell number.
- Stability: Atoms achieve stability by attaining a complete outer shell, either with 2 electrons (duplet rule) or 8 electrons (octet rule).
Atomic Number and Mass Number
- Atomic Number (Z): Represents the number of protons in an atom, which also equals the number of electrons.
- Mass Number (A): Represents the total number of protons and neutrons in an atom.
Atomic Weight and Molecular Weight
- Atomic Weight (Relative Atomic Mass): Represents the mass of an atom compared to the mass of a hydrogen atom.
- Molecular Weight (Relative Molecular Mass): Represents the mass of a molecule compared to the mass of a hydrogen atom.
Isotopes
- Isotopes are atoms of the same element with the same atomic number but different mass numbers. This difference in mass number arises due to variations in the number of neutrons.
Valency
- Valency is the number of hydrogen atoms an element combines with or displaces to form a compound. This indicates the combining capacity of an element.
Electronic Configuration and Stability
- Noble gases have a stable electronic configuration with a fully filled outer shell (2 or 8 electrons).
- Atoms of other elements have unstable electronic configurations and tend to gain, lose, or share electrons to achieve the stable electronic configuration of the nearest noble gas.
Modern Periodic Table
- Mendeleev organized elements systematically in the Modern Periodic Table based on their increasing atomic numbers.
Ancient Views of the Atomic Structure
- Kanada's Concept of an Atom: An Indian philosopher who theorized that matter is made up of particles called "paramanus" (atoms).
-
Dalton's Atomic Theory:
- Proposed atoms are indestructible and indivisible.
- Atoms of the same element are identical.
The Atom and Sub-Atomic Particles
-
Modern Atomic Theory:
- Atoms are divisible and consist of protons, electrons, and neutrons.
- Atoms of the same element may differ due to isotopes.
-
Discovery of the Electron:
- J.J. Thomson observed cathode rays in a discharge tube.
- These rays were deflected by a positively charged plate, concluding that they were made up of negatively charged particles called electrons.
-
Discovery of the Proton:
- Goldstein used a modified cathode ray tube with a perforated cathode.
- He observed positively charged rays called anode rays, concluding that they were made up of positively charged particles called protons.
-
Rutherford's Experiment:
- Alpha particles were directed towards a thin gold foil.
- Most passed straight through, but some were deflected at various angles, revealing a dense, positively charged nucleus within the atom.
- This led to the discovery of the atomic nucleus and the concept of electrons revolving around it in orbits or shells.
Structure of the Atom
- Sub-Atomic Particles:: Atoms are composed of protons, neutrons, and electrons
- Nucleus: Located at the center of the atom, containing protons and neutrons.
- Orbits or Shells: Imaginary paths around the nucleus where electrons revolve.
- Protons: Positively charged sub-atomic particles found in the nucleus, carrying a unit mass and a +1 charge.
- Neutrons: Uncharged sub-atomic particles found in the nucleus, carrying a unit mass.
- Electrons: Negatively charged sub-atomic particles revolving around the nucleus in orbits, carrying a negligible mass and a -1 charge.
Electronic Configuration and Stability
-
Stable Electronic Configuration:
- Noble gases have complete valence shells, with either 2 or 8 electrons in their outermost shell.
- They are chemically unreactive as they do not gain, lose, or share electrons.
-
Unstable Electronic Configuration:
- Other elements have incomplete valence shells.
- They tend to gain, lose, or share electrons to achieve the stable electronic configuration of the nearest noble gas (He, Ne, Ar, Kr, Xe, Rn) by forming chemical bonds.
Atomic Structure & Terminology
- Modern Periodic Table: Elements are arranged in increasing order of their atomic numbers.
- Atomic Number (Z): Represents the number of protons in an atom, which is also equal to the number of electrons.
- Mass Number (A): Represents the total number of protons and neutrons in an atom.
- Atomic Weight or Relative Atomic Mass: Represents the mass of an atom of an element relative to the mass of an atom of hydrogen.
- Molecular Weight or Relative Molecular Mass: Represents the mass of a molecule of a substance relative to the mass of an atom of hydrogen.
- Isotopes: Atoms of the same element with the same atomic number (Z) but different mass numbers (A) due to variations in the number of neutrons.
- Valency: The number of hydrogen atoms that can combine with or displace one atom of an element or radical.
Ancient Views on Atomic Structure
-
Kanada's Concept of an Atom:
- An Indian philosopher who believed matter is made up of particles called "paramanus" (atoms)
- When two atoms combine, it's called "dvyanuka"
-
Dalton's Atomic Theory:
- Proposed by John Dalton
- Atoms are indestructible and indivisible
- Atoms of the same element are alike in all respects
Modern Atomic Theory - Sub-atomic Particles
-
Discovery of Electrons:
- Scientist: J.J. Thomson
- Observation: Cathode rays are deflected by a positively charged plate in a discharge tube.
- Conclusion: Cathode rays contain negatively charged particles called electrons.
-
Discovery of Protons:
- Scientist: Goldstein
- Observation: Anode rays, passing through a perforated cathode in a modified discharge tube, are deflected by electric & magnetic fields in the opposite direction to cathode rays.
- Conclusion: Anode rays consist of positively charged particles called protons.
-
Discovery of Atomic Nucleus:
- Scientist: Lord Rutherford
- Observation: Most alpha particles passed through a thin gold foil, but some were deflected by large angles.
- Conclusion: An atom is mostly empty but contains a concentrated positive mass called the nucleus in the center.
Atomic Structure: Key Components
-
Sub-atomic Particles:
- Atoms are made of three fundamental particles: protons, neutrons, and electrons.
-
Nucleus:
- The nucleus is located at the center of the atom.
- Contains protons and neutrons.
-
Orbits/Shells:
- Imaginary paths around the nucleus where electrons revolve.
-
Protons:
- Found in the nucleus.
- Carry a positive charge (+1) and a unit mass.
-
Neutrons:
- Found in the nucleus.
- Carry no charge and have a unit mass.
-
Electrons:
- Revolve around the nucleus in orbits or shells.
- Carry a negative charge (-1) and negligible mass.
Electronic Configuration and Stability
-
Stable Electronic Configuration:
- Noble gases have a stable electronic configuration with their outermost shell complete.
- They do not gain, lose, or share electrons.
-
Unstable Electronic Configuration:
- Atoms of other elements have incomplete outer shells.
- They tend to achieve a stable configuration like the nearest noble gas by gaining or losing electrons.
Key Concepts Related to Atoms
-
Modern Periodic Table:
- Elements are arranged systematically in increasing order of atomic numbers.
-
Atomic Number (Z):
- Represents the number of protons in an atom.
- Also equal to the number of electrons in an atom.
-
Mass Number (A):
- The total number of protons and neutrons in an atom.
-
Atomic Weight/Relative Atomic Mass:
- The number of times an atom of an element is heavier than an atom of hydrogen.
-
Molecular Weight/Relative Molecular Mass:
- The number of times a molecule of a substance is heavier than an atom of hydrogen.
-
Isotopes:
- Atoms of the same element with the same atomic number (Z) but different mass numbers (A).
-
Valency:
- The number of hydrogen atoms that can combine with or displace one atom of an element or radical to form a compound.
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Test your knowledge on the history and structure of atoms, from ancient philosophies to modern atomic theory. Explore concepts introduced by notable scientists such as Dalton and Thomson, and understand the significance of subatomic particles. This quiz will enhance your understanding of fundamental chemistry concepts.