Atomic Structure Concepts
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Questions and Answers

If an atom has an atomic number of 16, and a mass number of 32, what is the number of neutrons in its nucleus?

  • 16 (correct)
  • 32
  • 48
  • 8

An ion has a charge of +2. Which of the following statements is correct regarding the number of protons and electrons it contains?

  • It has two more protons than electrons. (correct)
  • It has two more electrons than protons.
  • It has an equal number of protons and electrons.
  • It has two more protons than neutrons.

Which subatomic particle primarily determines the identity of an element?

  • Positron
  • Proton (correct)
  • Electron
  • Neutron

How does the number of electrons relate to the number of protons in a neutral atom?

<p>The number of electrons is equal to the number of protons. (B)</p> Signup and view all the answers

If an atom loses an electron, what type of ion does it form?

<p>A cation with a positive charge (A)</p> Signup and view all the answers

Which of the following statements accurately describes the relative masses of subatomic particles?

<p>Protons and neutrons have approximately the same mass, while electrons are much lighter. (D)</p> Signup and view all the answers

What is the mass number of an atom that contains 17 protons, 18 neutrons, and 17 electrons?

<p>35 (A)</p> Signup and view all the answers

Which of the following describes the location of electrons within an atom?

<p>Moving rapidly around the nucleus (D)</p> Signup and view all the answers

How does the concept of isotopes explain why the atomic weight listed on the periodic table is a decimal number?

<p>The listed atomic weight is a weighted average of the mass numbers of all naturally occurring isotopes of an element. (A)</p> Signup and view all the answers

Which of these subatomic particle arrangements would result in a cation with a +2 charge?

<p>12 protons and 10 electrons (A)</p> Signup and view all the answers

Which of the following electron configurations violates Hund's rule?

<p>$1s^2 2s^2 2p_x^2 2p_y^0 2p_z^0$ (D)</p> Signup and view all the answers

Consider an element with an atomic number of 8. How many electrons would be present in the corresponding ion with a -2 charge?

<p>10 (B)</p> Signup and view all the answers

An element has the electron configuration $[Ar] 4s^2 3d^6$. In which block of the periodic table does it belong?

<p>d-block (A)</p> Signup and view all the answers

Which of the following elements has 6 valence electrons?

<p>Oxygen (O) (A)</p> Signup and view all the answers

What change occurs at the electron level when an atom emits light, such as in the aurora borealis?

<p>Electrons move from a higher energy level to a lower energy level, releasing energy as light. (C)</p> Signup and view all the answers

How does the quantum mechanical model describe the location of electrons in an atom?

<p>Electrons are located in specific, well-defined regions called orbitals, which represent probability zones. (C)</p> Signup and view all the answers

What is the valence shell of an element with the electronic configuration $1s^2 2s^2 2p^6 3s^2 3p^4$?

<p>3 (A)</p> Signup and view all the answers

How many valence electrons does Strontium (Sr) have?

<p>2 (B)</p> Signup and view all the answers

If an atom of an element has a mass number of 37 and contains 17 protons, how many neutrons does it have?

<p>20 (B)</p> Signup and view all the answers

An element has the valence electron configuration of $ns^2 np^3$. Which group does it belong to in the periodic table?

<p>Group 5A (15) (C)</p> Signup and view all the answers

Element X has two isotopes: X-20 and X-22. If the atomic weight of element X is 20.8, which isotope is more abundant in nature?

<p>X-20 (B)</p> Signup and view all the answers

Which statement accurately describes the relationship between atomic number, mass number, and the number of electrons in a neutral atom?

<p>The atomic number equals the number of protons and electrons, while the mass number is the sum of protons and neutrons. (D)</p> Signup and view all the answers

Which element is most likely to have similar chemical properties to Sulfur (S)?

<p>Oxygen (O) (A)</p> Signup and view all the answers

An element is located in the 5th period of the periodic table. According to the energy levels/shells principle, how many energy levels are occupied by its electrons?

<p>5 (A)</p> Signup and view all the answers

Tin (Sn) has the electron configuration ending in $5s^2 5p^2$. In which period and block of the periodic table is it located?

<p>Period 5, p-block (A)</p> Signup and view all the answers

Which of the following statements accurately describes the relationship between energy levels and sublevels within an atom?

<p>Each energy level contains one or more sublevels (s, p, d, f), with the number of sublevels increasing with the energy level. (C)</p> Signup and view all the answers

Consider an atom with electrons in the d sublevel. What is the maximum number of electrons that can occupy this sublevel?

<p>10 (D)</p> Signup and view all the answers

What does the Aufbau principle state regarding the filling of electron orbitals?

<p>Electrons first occupy the lowest energy orbitals available. (D)</p> Signup and view all the answers

According to the Pauli Exclusion Principle, what is the maximum number of electrons that can occupy a single atomic orbital, and what must be true of their spins?

<p>Two electrons, with opposite spins. (D)</p> Signup and view all the answers

How does Hund's Rule of Maximum Multiplicity influence the arrangement of electrons within a sublevel containing multiple orbitals of equal energy (degenerate orbitals)?

<p>Electrons distribute themselves among the orbitals with parallel spins, maximizing the total spin. (A)</p> Signup and view all the answers

Which principle explains why electrons in the same orbital must have opposite spins?

<p>Pauli's exclusion principle (D)</p> Signup and view all the answers

Consider the element Oxygen (O), which has 8 electrons. Based on the provided principles, how would its electrons be arranged in the 2p orbitals?

<p>Two orbitals with a single electron, and one orbital with paired electrons. (C)</p> Signup and view all the answers

Which of the following elements has a valence shell with 6 electrons?

<p>Sulfur (S) (C)</p> Signup and view all the answers

Which element's electron configuration ends with the last electron occupying a d orbital?

<p>Iron (Fe) (A)</p> Signup and view all the answers

Which of the following represents the correct abbreviated electron configuration for Strontium (Sr)?

<p>[Kr] 5s² (A)</p> Signup and view all the answers

Which noble gas would be used to abbreviate the electron configuration of an element in the 4th period?

<p>Argon (Ar) (B)</p> Signup and view all the answers

Considering the filling order of orbitals, which of the following subshells would be filled immediately after the 4_p_ subshell?

<p>5s (D)</p> Signup and view all the answers

Which element is expected to have the same number of valence electrons as Gallium (Ga)?

<p>Indium (In) (A)</p> Signup and view all the answers

Which of the following statements accurately describes the noble gas configuration?

<p>Noble gases have completely filled <em>s</em> and <em>p</em> subshells in their outermost shell, except for Helium. (C)</p> Signup and view all the answers

An element has an abbreviated electron configuration of [Kr] 5s² 4d². In which period of the periodic table is this element located?

<p>Period 5 (A)</p> Signup and view all the answers

An element in Group 5A of the periodic table gains electrons to achieve a stable octet. What ionic charge will it typically have?

<p>3- (B)</p> Signup and view all the answers

Chlorine (Cl) gains one electron to form a chloride ion (Cl-). Which statement accurately describes the change in its electronic configuration?

<p>It gains an electron in its 3p orbital, achieving the same electron configuration as Argon (Ar). (A)</p> Signup and view all the answers

Sulfur (S) is in Group 6A. Which of the following options correctly identifies the number of valence electrons and the ionic charge of its ion?

<p><code>6</code> valence electrons, S^2- (A)</p> Signup and view all the answers

Consider an element 'X' that forms a stable ion with a 2+ charge. Which group in the periodic table is element 'X' MOST likely to belong to?

<p>Group 2A (B)</p> Signup and view all the answers

An unknown element 'Z' has an electronic configuration of 1s²2s²2p³. What ionic charge would 'Z' most likely adopt to achieve a noble gas configuration?

<p>3- (A)</p> Signup and view all the answers

How does the number of protons and electrons change when a neutral atom of oxygen (O) forms an oxide ion (O²⁻)?

<p>The number of protons remains the same, and the number of electrons increases. (B)</p> Signup and view all the answers

Which of the following electron configurations represents a stable ion MOST likely formed by an element in Group 6A?

<p>1s²2s²2p⁶3s²3p⁶ (B)</p> Signup and view all the answers

Which statement correctly describes the relationship between the group number of a representative nonmetal and its ionic charge?

<p>The ionic charge is equal to eight minus the group number. (D)</p> Signup and view all the answers

Flashcards

Atom

The smallest part of an element, retains properties.

Subatomic particles

Protons, neutrons, and electrons that make up an atom.

Proton

A positively charged particle located in the nucleus.

Neutron

A neutral particle found in the nucleus, with no charge.

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Electron

A negatively charged particle located outside the nucleus.

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Atomic number (Z)

The number of protons in an atom's nucleus.

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Mass number (A)

The total number of protons and neutrons in the nucleus.

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Neutral atom

An atom with equal numbers of protons and electrons.

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X

Chemical symbol representing an element.

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A

Mass number; total of protons and neutrons in an atom.

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Z

Atomic number; number of protons in an atom.

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Isotopes

Atoms of the same element with the same protons but different neutrons.

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Ion

An atom that has lost or gained electrons; has a charge.

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Cation

Positively charged ion formed by losing electrons.

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Anion

Negatively charged ion formed by gaining electrons.

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Quantum Mechanical Model

Model describing electrons in probability zones called orbitals.

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Energy levels

Regions around the nucleus where electrons can orbit; there are 7 energy levels (n=1 to n=7).

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Quantum number (n)

A number that identifies the energy level of an electron; ranges from 1 to 7.

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Energy sublevels

Smaller divisions within energy levels designated by S, P, D, F; each has different number of orbitals.

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Maximum electron capacity per sublevel

Each sublevel has a maximum number of electrons it can hold: s (2), p (6), d (10), f (14).

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Electron configuration

A distribution representation of electrons in atoms, following specific rules.

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Aufbau's principle

States electrons fill the lowest energy orbitals first before occupying higher ones.

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Pauli's exclusion principle

No more than two electrons can occupy the same orbital; they must have opposite spins.

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Hund's Rule of Maximum Multiplicity

Electrons must occupy degenerate orbitals singly before pairing up to minimize repulsion.

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Valence Shell

The outermost shell of an atom containing valence electrons.

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Valence Electrons

Electrons in the outermost shell responsible for chemical bonding.

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Noble Gas Configurations

Configurations where the outer s and p subshells are fully occupied.

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Abbreviated Configurations

A shorthand notation for electron configurations using noble gases.

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Kernel Electron Configuration

The part of the electron configuration that represents the noble gas core.

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Energy/Orbital Diagrams

Visual representations of electron arrangements within orbitals.

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Orbitals

Regions in an atom where there is a high probability of finding an electron.

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Periodic Table Groups

Elements with the same valence electrons belong to the same group, sharing similar properties.

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Tin Electronic Configuration

For Tin (Sn), the valence shell is 5 and valence electrons are 4, shown as 5s² 5p².

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Period in Periodic Table

The period of an element corresponds to its highest coefficient in the electronic configuration.

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Four Blocks of Elements

Elements are categorized into s, p, d, and f blocks based on the last orbital occupied.

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Representative Elements

Elements in groups 1A to 8A, identifiable by their last orbital being s or p.

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Valence electrons in Group 7A

Nonmetals in Group 7A have 7 valence electrons.

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Chlorine's ionic charge

Chlorine forms a negative ion with a charge of 1-.

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Octet rule

Atoms tend to gain, lose, or share electrons to achieve 8 valence electrons.

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Ionic charge of sulfur

Sulfur ion has a charge of 2-.

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Electron configuration of sulfur ion

The electronic configuration for sulfur ion is 1s22s22p63s23p6.

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Group 6A nonmetals' valence electrons

Nonmetals in Group 6A have 6 valence electrons.

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Ionic charge of chlorine

Chlorine forms ion Cl1- by gaining 1 electron.

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Ionic charge pattern by group

Metals form a charge equal to their group number; nonmetals charge is based on how many electrons needed to reach 8.

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Study Notes

Atomic Structure and Properties of Chemical Elements

  • Atoms are the smallest parts of an element, retaining its properties.
  • Atoms are composed of subatomic particles: protons, neutrons, and electrons.
  • Protons are positively charged, located in the nucleus and have a mass of 1 amu.
  • Neutrons have no charge, located in the nucleus, and have a mass of 1 amu.
  • Electrons are negatively charged, located outside the nucleus, and have negligible mass (approximately 1/1836 amu).
  • The atomic number (Z) is equal to the number of protons in an atom.
  • The mass number (A) is the sum of protons and neutrons in an atom.

History of Atomic Models

  • Solid Sphere Model (Dalton, 1803): Atoms are indivisible and identical for a given element.
  • Plum Pudding Model (Thomson, 1904): Atoms contain negatively charged electrons embedded in a positively charged sphere.
  • Nuclear Model (Rutherford, 1911): The atom is mostly empty space with a dense, positively charged nucleus at the center.
  • Planetary Model (Bohr, 1913): Electrons orbit the nucleus in specific energy levels (orbits) that are quantized.
  • Quantum Mechanical Model (Schrödinger, 1926): Electrons don't orbit in fixed paths but exist in probability clouds (orbitals) within energy levels.

Atomic Number, Mass Number, and Isotopes

  • The atomic number defines the element.
  • The mass number represents the total number of protons plus neutrons.
  • Atoms of the same element with different numbers of neutrons are isotopes.
  • Different isotopes have the same atomic number but different mass numbers.
  • The average atomic mass of an element is determined by the relative abundance of its different isotopes.

Atomic Structure and Ions

  • An ion is an atom or molecule that has a net electric charge due to a loss or gain of electrons.
  • A positively charged ion is called a cation.
  • A negatively charged ion is called an anion.
  • Representative elements tend to form ions based on the number of electrons in their outermost shell (valence shell).

Electronic Configuration

  • Electronic configuration describes the arrangement of electrons in different energy levels and sublevels within an atom.
  • Aufbau's principle states that electrons fill the lowest energy orbitals first.
  • Hund's rule states that electrons fill orbitals individually before pairing up.
  • Pauli's exclusion principle states that only two electrons can occupy any given orbital, and they must have opposite spins.
  • The periodic table organizes elements based on their electronic configurations.
  • Valence electrons are electrons in the outermost shell of an atom. The number of valence electrons is often related to the group number on the periodic table.

Energy Levels and Sublevels

  • Energy levels are designated by the principal quantum number (n).
  • Sublevels within each energy level are designated by letters (s, p, d, f).
  • Each sublevel has a specific number of orbitals, which specify the shape and spatial orientation of the electron cloud.

Orbital Diagrams

  • Orbital diagrams are used to visualize the electronic distribution within each orbital.
  • Pauli exclusion principle and Hund's rule guide the electron arrangement. Filling orbitals in order of energy and the direction of spin for each electron.

Noble Gas Configurations

  • Noble gases have completely filled outermost electron shells. Their electron configuration is used to represent the configurations of other elements in an abbreviated form.
  • The electronic configuration of a given element is abbreviated by preceding the noble gas symbol for the closest preceding element with a square bracket to express the electron configuration.

Types of Chemical Bonds

  • Ionic Bonds: Transfer of electrons from a metal to a nonmetal, forming ions (cations and anions). The attractive forces between oppositely charged ions are a form of ionic bonding.
  • Covalent Bonds: Sharing of valence electrons between two nonmetals or a nonmetal and a metalloid. This type of bonding does not result in ions.

Polar and Nonpolar Covalent Bonds

  • Polar Covalent Bonds: The unequal sharing of electrons between atoms because the electronegativity between the two atoms differs.
    • One atom has a greater attraction for the shared electrons, creating a partial positive charge on the one atom with the lesser attraction, and partial negative charge on the other atom receiving the electrons.
  • Nonpolar Covalent Bonds: Equal sharing of electrons because the two elements sharing the electrons have similar electronegativities, so they have similar attractions.

Periodic Properties

  • Elements in the same period show trends in properties (e.g., atomic radius, ionic radius, ionization energy, electronegativity.
  • Metallic character generally increases from right to left across a period and from top to bottom within a group.
  • Atomic radius generally increases from right to left across a period and from top to bottom within a group.
  • Ionization energy and electronegativity generally increase from left to right across a period and from bottom to top within a group.
  • Reactivity related to valence electrons often shows cyclical changes across the periodic table.

Octet Rule

  • Atoms tend to gain, lose, or share electrons to achieve a stable electron configuration similar to a noble gas (8 valence electrons, except He).

The Structure of a Periodic Table

  • Periods (horizontal rows) are numbered with integers (1 to 7) and indicate the number of electron shells.
  • Group (vertical columns) are labeled with numbers from 1 to 18, sometimes including a letter (A or B). This indicates the number of valence electrons an element is expected to have.

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