Atomic Structure and Subatomic Particles

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Questions and Answers

How many electrons can each orbital hold?

  • One electron
  • Two electrons of opposite spin (correct)
  • Three electrons of the same spin
  • Four electrons

The Pauli exclusion principle states that no two electrons in an atom can have the same set of four quantum numbers.

True (A)

What is the Aufbau principle?

Electrons occupy the lowest energy orbitals first.

The electron configuration for an atom of Neon is _____

<p>[Ne]</p> Signup and view all the answers

What is the shape of a p orbital?

<p>Dumbbell-shaped (D)</p> Signup and view all the answers

What does the emission spectrum of hydrogen provide evidence for?

<p>The existence of electrons in discrete energy levels (A)</p> Signup and view all the answers

The maximum number of electrons that can occupy a main energy level is given by the formula 2n.

<p>False (B)</p> Signup and view all the answers

How does the emission spectrum of hydrogen help determine energy transitions?

<p>It shows distinct lines that correspond to specific energy transitions between levels.</p> Signup and view all the answers

Match the following electron configuration with the correct atom:

<p>1s²2s²2p⁶3s²3p¹ = Aluminum 1s²2s²2p⁶3s²3p⁴ = Sulfur 1s²2s²2p⁶ = Neon 1s²2s²2p⁶3s²3p² = Silicon</p> Signup and view all the answers

What is the electron configuration notation for an atom of oxygen, which has 8 electrons?

<p>1s² 2s² 2p⁴</p> Signup and view all the answers

A noble gas electron configuration ends with the nearest noble gas, represented by [___].

<p>Ar</p> Signup and view all the answers

The number of unpaired electrons in oxygen (element O) is _____

<p>2</p> Signup and view all the answers

Valence electrons play a crucial role in determining an atom's chemical properties.

<p>True (A)</p> Signup and view all the answers

The elements in group 18 of the periodic table are known as _____ gases.

<p>noble</p> Signup and view all the answers

Match the atom with its corresponding electron configuration:

<p>Carbon = 1s² 2s² 2p² Neon = 1s² 2s² 2p⁶ Sodium = 1s² 2s² 2p⁶ 3s¹ Chlorine = 1s² 2s² 2p⁶ 3s² 3p⁵</p> Signup and view all the answers

What does the atomic number represent?

<p>The number of protons in the nucleus (A)</p> Signup and view all the answers

The atomic number is equal to the total number of electrons in a neutral atom.

<p>True (A)</p> Signup and view all the answers

In terms of electron configuration, what are valence electrons?

<p>The outermost electrons of an atom that are involved in chemical bonding.</p> Signup and view all the answers

The element with atomic number 2 is represented by the symbol ______.

<p>He</p> Signup and view all the answers

Match the electron configuration notation with the element:

<p>1s2 = Helium 1s2 2s2 2p6 = Neon 1s2 2s2 2p6 3s2 = Magnesium 1s2 2s2 2p6 3s2 3p5 = Chlorine</p> Signup and view all the answers

How do unpaired electrons relate to an element's chemical properties?

<p>They influence the bonding behavior and reactivity of the element. (B)</p> Signup and view all the answers

Noble gas notation simplifies the representation of electron configurations.

<p>True (A)</p> Signup and view all the answers

What is the significance of the absence of a neutron in a hydrogen atom?

<p>It makes hydrogen the simplest atom with only one proton and no neutrons.</p> Signup and view all the answers

Flashcards

Atomic Number

The number of protons in an atom's nucleus.

Protons

Positively charged subatomic particles found in the atom's nucleus.

Neutrons

Neutral subatomic particles found in the atom's nucleus.

Electrons

Negatively charged subatomic particles orbiting the nucleus.

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Atomic Structure

The arrangement of protons, neutrons, and electrons within an atom.

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Periodic Table

An arrangement of chemical elements, ordered by their atomic number.

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Number of Electrons

Equal to the number of protons in a neutral atom.

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Electron Orbital

A region in space where there's a high probability of finding an electron.

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Orbital Energy

A specified energy level for an orbital based on electronic configuration and chemical surroundings.

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Pauli Exclusion Principle

No two electrons in an atom can have the same set of four quantum numbers.

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Aufbau Principle

Electrons fill the lowest energy levels first, following a specific order.

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Hund's Rule

Each orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied, and all electrons in singly occupied orbitals have the same spin.

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Electron Configuration

A representation of how electrons are arranged in atomic orbitals.

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Electromagnetic Spectrum

A range of all types of electromagnetic radiation, which include light.

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Emission Spectrum

The spectrum of light given off by an atom in an excited state.

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Line Spectrum

A spectrum containing only specific lines of color at specific wavelengths/frequencies.

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Continuous Spectrum

A complete range of all possible wavelengths, e.g., a rainbow.

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Emission Spectra of Hydrogen

Wavelengths of light emitted when a hydrogen atom transitions between energy levels.

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s, p, d, f orbitals

Different shapes of electron orbitals in an atom

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Isotopic analysis

Analysis of the different isotopes of an element.

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Mass spectrum of Cl2

A graph showing the relative abundance of different isotopic masses of chlorine gas.

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Stable isotopes of Magnesium

Magnesium's naturally occurring isotopes, 24Mg, 25Mg, and 26Mg.

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Isotopic abundance

The percentage of a specific isotope in a natural element.

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Geiger-Marsden experiment

An experiment that showed the atom has a small, dense, positive nucleus surrounded by electrons.

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Atomic structure

The organization of protons, neutrons, and electrons in an atom.

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Atomic energy levels

Specific energy states that electrons can occupy in an atom.

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Electron configuration

The arrangement of electrons in energy levels and sublevels within an atom.

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Emission spectra

Light emitted by atoms when electrons return to lower energy levels.

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Line emission spectrum

Spectrum showing discrete lines of specific wavelengths emitted by an atom.

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Hydrogen line spectrum

Spectrum containing characteristic lines that provide evidence for discrete energy levels in hydrogen.

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Study Notes

Atomic Structure

  • Atoms are composed of a minute, positively charged nucleus and negatively charged electrons.
  • The mass of an atom is concentrated in its nucleus.
  • The electron configuration can be deduced from the atomic number.
  • Atoms are fundamental building blocks of everything.
  • Atoms have been theorized about for over 2500 years.
  • Experimental evidence for atoms emerged in the 19th century.
  • Atoms are too small to be seen directly.
  • All atoms of a given element have identical chemical properties.
  • Atoms of different elements have different properties.
  • Atoms consist of subatomic particles.
  • Atoms are largely empty space.
  • Atoms are made up of protons, neutrons, and electrons.

Subatomic Particles

  • Protons have a positive charge.
  • Neutrons have no charge.
  • Electrons have a negative charge.
  • Relative masses and charges are given in the IB data booklet.
  • The mass of the electron is negligible compared to protons and neutrons.
  • Protons and neutrons are collectively called nucleons.
  • The nucleus is a small, dense, positively charged core.
  • Electrons occupy the space outside the nucleus.
  • Isotopes are atoms of the same element with varying neutron numbers.

Atomic Number and Mass Number

  • Atomic number (Z) is the number of protons.
  • Mass number (A) is the sum of protons and neutrons.
  • Isotopes have the same atomic number (Z) but different mass numbers (A).

Atomic Number

  • The atomic number identifies the element.
  • The atomic number is equal to the number of protons.

Mass Number

  • The mass number is the sum of protons and neutrons in an atom.

Isotopes

  • Atoms of the same element with different mass numbers are called isotopes.
  • These atoms have the same number of protons but different numbers of neutrons.
  • Isotopes have different physical properties (e.g., boiling and melting points).

Nature of Science

  • Scientific knowledge is continually evolving.
  • New technologies facilitate scientific discoveries.
  • Scientific ideas are often initially speculative before gaining experimental support.
  • Scientists' work often involves collaborations and diverse perspectives.
  • Models can be used to explain processes that may not be observable directly.
  • Models are simplifications of reality, which may not be entirely accurate.
  • Modifications and expansions to models happen as more data is collected.
  • Models are adjusted or replaced when they are no longer aligned with observations.

Electron Configuration

  • Electrons occupy specific energy levels (shells).
  • Each energy level can hold a maximum number of electrons. (2n²).
  • Each main energy level is divided into sub-levels (s, p, d, f).
  • Sub-levels consist of orbitals.
  • Each orbital can hold a maximum of two electrons with opposite spins.
  • Hund’s rule describes the filling of orbitals within a sublevel.
  • The Pauli exclusion principle indicates that each orbital can hold only two electrons.

Atoms Contain Electrons

  • Electrons were discovered in the late 19th century.
  • Different metals produce streams of negatively charged particles (electrons) when a high voltage is applied.
  • Atoms contain electrons surrounding the nucleus.
  • The electron configuration provides information about the arrangement of electrons within the atom.

Electromagnetic Spectrum

  • Electromagnetic radiation is a form of energy that travels as waves.
  • Different types of electromagnetic radiation have different wavelengths.
  • The wavelength and frequency of radiation are related: c=νλ
  • Electromagnetic spectrum includes radio waves, microwaves, infrared, visible light, ultraviolet, X-rays, and gamma rays.
  • Different regions of the electromagnetic spectrum correspond to different energies.
  • Emission spectra are produced when excited electrons return to lower energy levels, giving off specific wavelengths of light..
  • Atoms have unique emission spectra that can be used for identification

Atomic Emission Spectra

  • Atoms emit light at specific wavelengths.
  • Each element has a unique pattern or spectrum of wavelengths.
  • This unique pattern is used to identify elements.

Bohr Model and Schrödinger Model

  • Bohr's model envisions electrons orbiting the nucleus in specific energy levels.
  • Schrödinger's model describes electron locations in orbitals, which are regions of space where an electron is likely to be found.
  • Schrödinger's model is based on wave-like properties of electrons.

Electromagnetic Radiation

  • Electromagnetic waves carry energy.
  • The energy of electromagnetic radiation is related to its frequency.
  • Different types of electromagnetic radiation have different energies.

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