Atomic Structure and Periodic Properties Quiz
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Questions and Answers

What are the basic building blocks of the following substances?

 a. water
 b. chalk
 c. sugar
 d. table salt

Are the basic building blocks of these substances the same or different?

The basic building blocks of the substances are atoms.

 a. Water is composed of hydrogen (H) and oxygen (O) atoms.
 b. Chalk is primarily composed of calcium (Ca), carbon (C) and oxygen (O) atoms.
 c. Sugar is composed of carbon (C), hydrogen (H) and oxygen (O) atoms.
 d.  Table salt is composed of sodium (Na) and chlorine (Cl) atoms.

The basic building blocks of these substances are different. Each substance is made up of unique combinations of atoms.

Why do different materials show different properties? For example, materials such as woods can burn, an iron nail can rust, table salt dissolves in water, etc.

The different properties of materials arise from differences in their atomic composition and how their atoms are arranged.

How do the beliefs about the structure of matter evolve?

Our understanding of the structure of matter has evolved over time through a combination of observation, experimentation, and theoretical development.

Describe the early developments leading to the modern concept of the atom.

<p>Early developments leading to the modern concept of the atom include the ideas of the Greek philosopher Democritus who proposed the existence of indivisible particles called atoms. These ideas paved the way for further exploration and understanding of the atom's composition.</p> Signup and view all the answers

Can we see atoms with our naked eyes?

<p>False</p> Signup and view all the answers

Describe the five postulates of Dalton’s atomic theory.

<p>Dalton's atomic theory proposes five key postulates:</p> <ol> <li>All matter is composed of atoms, which are indivisible and indestructible particles.</li> <li>All atoms of a given element are identical in mass and properties.</li> <li>Atoms of different elements have different masses and properties.</li> <li>Compounds are formed by the combination of two or more different kinds of atoms in a definite ratio by mass.</li> <li>Chemical reactions involve the rearrangement of atoms. Atoms are neither created nor destroyed in chemical reactions.</li> </ol> Signup and view all the answers

How do scientific ideas develop based on previous scientific findings?

<p>Scientific ideas develop through a process of building upon prior knowledge and observations. Previous scientific findings provide a foundation for further inquiry and exploration, leading to refinements and new discoveries.</p> Signup and view all the answers

What is the law that Dalton formulated based on the law of conservation of mass and the law of definite proportions? Write its statement in your notebook.

<p>The law that Dalton formulated based on the law of conservation of mass and the law of definite proportions is the Law of Multiple Proportions. The law states that when two elements form more than one compound, the masses of one element that combine with a fixed mass of the other element are in ratios of small whole numbers.</p> Signup and view all the answers

The mass of a piece of wood before and after it is burnt to ashes is not the same. Does this show that mass is created or destroyed?

<p>This does not indicate that mass is created or destroyed. When wood burns, it reacts with oxygen in the air. The resulting products, including ash, carbon dioxide, and water vapor, have a combined mass equal to the initial mass of the wood and oxygen. The mass simply changes form, not disappears.</p> Signup and view all the answers

What would be the mass of products if the burning of wood was carried out in a closed container?

<p>The total mass of the products in a closed container would be equal to the initial combined mass of the wood and oxygen. Since the container prevents any escape of gases, the entire mass of reactants would be transformed into products.</p> Signup and view all the answers

Sugar consists of C, H, and O Atoms. When a certain amount of sugar is burned in a crucible, it changes from white sugar to black carbon. Where has the hydrogen and oxygen gone?

<p>When sugar is burned, the hydrogen and oxygen atoms combine with oxygen from the air to form water vapor (H2O) and carbon dioxide (CO2). These gases are released into the atmosphere, leaving behind the black carbon residue.</p> Signup and view all the answers

What mass of hydrogen and oxygen can be obtained from a. 18.0 g of water b. 1.00 g of water

<p>a. Mass of hydrogen in 18.0 g water = 0.112 × 18.0 g = 2.02 g Mass of oxygen in 18.0 g water = 0.888 × 18.0 g = 15.98 g</p> <p>b. Mass of hydrogen in 1.00 g water = 0.112 × 1.00 g = 0.112 g Mass of oxygen in 1.0 g water = 0.888 × 1.0 g = 0.888 g</p> Signup and view all the answers

Show how the following data illustrate the law of multiple proportions:

                             Compound A  Compound B  Compound C

Mass of nitrogen that combines with 1 g of oxygen 1.750 g 0.8750 g 0.4375 g

<p>The ratios of nitrogen masses combining with 1 gram of oxygen in each pair of compounds should be small whole numbers to support the law of multiple proportions. The ratios are:</p> <p>A/C = 1.750 / 0.4375 = 4 B/C = 0.8750 / 0.4375 = 2</p> <p>These results demonstrate small whole number ratios, supporting the Law of Multiple Proportions.</p> Signup and view all the answers

List the postulates of Dalton's that continue to have significance (are retained in the modern atomic theory).

<p>The postulates of Dalton's atomic theory that are still significant include:</p> <ol> <li>All matter is composed of atoms.</li> <li>Atoms of different elements have different masses and properties.</li> <li>Compounds are formed by the combination of two or more different kinds of atoms.</li> </ol> Signup and view all the answers

How does the atomic theory account for the fact that when 1.00 g of water is decomposed into its elements, 0.112 g of hydrogen and 0.888 g of oxygen are obtained regardless of the source of the water?

<p>The atomic theory explains this consistency because water is always composed of the same elements in the same proportions (two hydrogen atoms and one oxygen atom). Regardless of the origin of the water, the ratio of hydrogen to oxygen will remain constant, as dictated by the atomic theory.</p> Signup and view all the answers

Which of Dalton’s postulates about atoms are inconsistent with later observations? Do these inconsistencies mean that Dalton was wrong?

<p>One of Dalton's postulates, that atoms are indivisible and indestructible, was later found to be inconsistent with the discovery of subatomic particles like electrons, protons, and neutrons. While these inconsistencies show that Dalton's theory was not perfect, his work was revolutionary, laying the foundation for our modern understanding of the atom.</p> Signup and view all the answers

Is Dalton’s model still useful?

<p>True</p> Signup and view all the answers

Describe the limitations of Dalton’s atomic theory.

<p>Dalton's atomic theory had several limitations, primarily:</p> <ol> <li>Atoms are not indivisible and indestructible. They are composed of subatomic particles like electrons, protons, and neutrons.</li> <li>Atoms of the same element are not necessarily identical in mass. The existence of isotopes, atoms of the same element with different numbers of neutrons, challenges this postulate.</li> <li>Dalton's theory does not account for the behavior of atoms in the formation of molecules and the role of electrons in chemical bonding.</li> </ol> Signup and view all the answers

Explain the postulates of the modern atomic theory.

<p>The modern atomic theory is based on the following postulates:</p> <ol> <li>All matter is composed of tiny, indivisible particles called atoms.</li> <li>Atoms of a given element are chemically identical but differ from atoms of other elements in mass and properties.</li> <li>Atoms of different elements can combine in simple, whole-number ratios to form chemical compounds.</li> <li>Chemical reactions involve the rearrangement, combination, or separation of atoms but do not involve the creation or destruction of atoms.</li> <li>Atoms are composed of subatomic particles: electrons (negatively charged), protons (positively charged), and neutrons (no charge).</li> </ol> Signup and view all the answers

List the three fundamental laws of chemistry.

<p>The three fundamental laws of chemistry are:</p> <ol> <li>The law of Conservation of Mass: Mass is neither created nor destroyed in ordinary chemical reactions.</li> <li>The law of Definite Proportions: A given compound always contains the same elements in the same proportion by mass.</li> <li>The law of Multiple Proportions: When two elements combine to form more than one compound, the masses of one element that combine with a fixed mass of the other element are in ratios of small whole numbers.</li> </ol> Signup and view all the answers

How does the modern atomic theory explain the three fundamental laws of chemistry?

<p>The modern atomic theory explains the fundamental laws of chemistry by emphasizing the conservation of atoms during chemical reactions. The law of conservation of mass is explained by the idea that atoms are not created or destroyed in chemical reactions, but are simply rearranged. The law of definite proportions is explained by the idea that compounds are formed from specific combinations of atoms in fixed ratios. The law of multiple proportions is explained by the concept that atoms of different elements can combine in different ratios to form different compounds, with those ratios being simple whole numbers.</p> Signup and view all the answers

Describe the properties of cathode rays.

<p>Cathode rays, discovered by J.J. Thomson, exhibit the following properties:</p> <ol> <li>They travel in straight lines from the cathode to the anode.</li> <li>They are deflected by magnetic fields and electric fields, indicating they carry a negative charge</li> <li>Their properties are independent of the material used for the cathode, which suggests that they are a fundamental constituent of all matter.</li> <li>They produce greenish light when they interact with glass.</li> </ol> Signup and view all the answers

Which rays are used to see whether bones are broken or not?

<p>X-rays are used to see whether bones are broken or not. X-rays have higher energies than visible light and can penetrate human tissues. When they interact with bones, they are partially absorbed, revealing structural information.</p> Signup and view all the answers

Does radioactivity support Dalton’s idea of atoms?

<p>Radioactivity contradicts Dalton's idea of atoms being indivisible. Radioactive decay demonstrates that atoms can break down into smaller particles, challenging the notion of atoms as fundamental, indivisible units.</p> Signup and view all the answers

Describe the common types of radioactive emissions.

<p>All of the above</p> Signup and view all the answers

Why did most of the α-particles pass through the foil undeflected?

<p>Most of the α-particles passed through the gold foil undeflected because atoms are mostly empty space. The α-particles were small and positively charged, and they interacted primarily with the electrons, which are much lighter, and the nucleus, which is very small.</p> Signup and view all the answers

Why did only a small fraction of the α-particles show a slight deflection?

<p>A small fraction of the α-particles showed slight deflection because they encountered the positive charge of the nucleus. As positively charged α-particles approached the positively charged nucleus, they experienced electrostatic repulsion, causing them to deviate from their original paths.</p> Signup and view all the answers

Why didn't all α-particles bounce at an angle of 180°?

<p>Not all α-particles bounced back at an angle of 180° because the nucleus is very small compared to the size of the atom. If the α-particles were to pass through the exact center, they would experience a direct head-on collision and bounce back. However, most particles passed close to the nucleus, experiencing only a partial deflection.</p> Signup and view all the answers

Based on the findings of Rutherford’s experiment, what is your conclusion about an atom?

<p>Based on the findings of Rutherford's experiment, we can conclude that</p> <ol> <li>Atoms are mostly empty space, as the majority of α-particles passed through the gold foil undeflected.</li> <li>Atoms contain a dense, positively charged nucleus, as a small fraction of α-particles experienced significant deflection.</li> <li>The nucleus occupies a very small fraction of the atom's total volume.</li> </ol> Signup and view all the answers

When Rutherford’s co-workers bombarded gold foil with α-particles, they obtained results that overturned the existing (Thomson) model of the atom. Explain.

<p>Rutherford's experiment overturned Thomson's plum-pudding model because it demonstrated that the positive charge of an atom is concentrated in a small, dense nucleus, rather than being uniformly distributed throughout the atom. This contradicted Thomson's model, which assumed a diffuse positive charge with electrons embedded within it, where electrons could easily scatter α-particles.</p> Signup and view all the answers

A sample of a radioactive element is found to be losing mass gradually. Explain what is happening to the sample.

<p>A radioactive element is undergoing radioactive decay, which involves the emission of particles and/or radiation from the nuclei of unstable atoms. This emission results in the transformation of the radioactive element into a different element, with a corresponding decrease in mass.</p> Signup and view all the answers

Describe the experimental basis for believing that the nucleus occupies a very small fraction of the volume of the atom.

<p>The experimental basis for believing that the nucleus occupies a very small fraction of the volume of the atom comes from Rutherford's alpha-scattering experiment. In this experiment, the majority of α-particles passed straight through the gold foil, indicating that the atoms were largely empty space. Only a small fraction of particles were deflected, suggesting that the positive charge of the atom was concentrated in a small, dense nucleus.</p> Signup and view all the answers

Study Notes

Atomic Structure and Periodic Properties

  • This unit covers the historical development of atomic structure, experimental observations, subatomic particles, atomic mass, isotopes, electromagnetic radiation, atomic spectra, Bohr models, quantum mechanical models, periodic law, and related electronic configurations.
  • It also discusses scientific enquiry skills relevant to the unit.

Early Atomic Concepts

  • Ancient Greek philosophers debated whether matter was infinitely divisible or composed of indivisible particles.
  • Democritus proposed the concept of atoms (atomos), meaning indivisible.

Dalton's Atomic Theory

  • Dalton's atomic theory, formulated in 1808, gained wide acceptance.
  • Five postulates of Dalton's atomic theory are presented.

Modern Atomic Theory and Laws of Chemistry

  • The modern atomic theory incorporates modifications and additions to Dalton's theory based on experimental evidence.
  • Laws of conservation of mass, definite proportions, and multiple proportions are fundamental laws that underpin Dalton's theory.

Early Experiments to Characterize the Atom

  • Discovery of the electron: J.J. Thomson's experiments with cathode rays demonstrated the existence of negatively charged particles (electrons) in all matter.
  • Thomson's "plum-pudding" model: This model depicted electrons scattered throughout a positively charged atom.
  • Radioactivity: Radioactive decay is the spontaneous emission of particles and radiation from unstable atomic nuclei.
  • Rutherford's gold foil experiment: This experiment disproved Thomson's model, revealing a dense, positively charged nucleus at the atom's center.

Subatomic Particles

  • Proton: Positively charged particle in the atom's nucleus.
  • Neutron: Neutral particle in the atom's nucleus, similar in mass to a proton.
  • Electron: Negatively charged particle orbiting the nucleus.
  • These subatomic particles have different masses and charges.

Atomic Mass and Isotopes

  • Atomic number (Z) is the number of protons in an atom.
  • Mass number (A) is the total number of protons and neutrons in an atom.
  • Isotopes are atoms of the same element with different numbers of neutrons, and therefore different mass numbers.
  • Relative atomic mass (atomic mass) is the weighted average of the masses of all isotopes of an element.

Electromagnetic Radiation and Atomic Spectra

  • Electromagnetic radiation (EMR) consists of electric and magnetic fields vibrating perpendicularly.
  • EMR has a wavelength (λ), frequency (ν), and speed (c = νλ).
  • The electromagnetic spectrum encompasses a broad range of frequencies and wavelengths.
  • Emission spectra of atoms show a series of discrete lines due to transitions between quantized energy levels.
  • A photon is a particle of light energy (E = hν = hc/λ).

Bohr's Model of the Atom

  • Bohr's model describes the atom as having quantized energy levels for electrons.
  • Electrons orbit in specific, fixed energy levels around the nucleus.
  • Electrons absorb or emit energy when they change orbits, resulting in characteristic spectral lines.

Quantum Mechanical Model

  • The quantum mechanical model of the atom incorporates wave-particle duality and the Heisenberg uncertainty principle.
  • Electrons are described by probability distributions (orbitals) instead of fixed orbits.
  • Four quantum numbers (n, ℓ, ml, ms) describe the properties of each electron.

Electronic Configurations and Orbital Diagrams

  • Aufbau principle, Hund's rule, and Pauli exclusion principle govern the filling of atomic orbitals.
  • Electronic configurations and orbital diagrams show the arrangement of electrons in orbitals.
  • Valence electrons are the electrons in the outermost energy level, affecting bonding.

Limitations of Bohr's Model

  • Bohr's model doesn’t explain the spectra of complex atoms.
  • It doesn't account for the splitting of spectral lines in magnetic fields, and contradicts the uncertainty principle.

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Test your knowledge on atomic structure and the periodic properties of elements. This quiz covers historical developments, Dalton's atomic theory, modern atomic theory, and key concepts such as isotopes and atomic spectra. Dive into the foundational aspects of chemistry and enhance your understanding of atomic models.

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