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Questions and Answers
What are the basic building blocks of the following substances?
a. water
b. chalk
c. sugar
d. table salt
Are the basic building blocks of these substances the same or different?
What are the basic building blocks of the following substances?
a. water
b. chalk
c. sugar
d. table salt
Are the basic building blocks of these substances the same or different?
The basic building blocks of the substances are atoms.
a. Water is composed of hydrogen (H) and oxygen (O) atoms.
b. Chalk is primarily composed of calcium (Ca), carbon (C) and oxygen (O) atoms.
c. Sugar is composed of carbon (C), hydrogen (H) and oxygen (O) atoms.
d. Table salt is composed of sodium (Na) and chlorine (Cl) atoms.
The basic building blocks of these substances are different. Each substance is made up of unique combinations of atoms.
Why do different materials show different properties? For example, materials such as woods can burn, an iron nail can rust, table salt dissolves in water, etc.
Why do different materials show different properties? For example, materials such as woods can burn, an iron nail can rust, table salt dissolves in water, etc.
The different properties of materials arise from differences in their atomic composition and how their atoms are arranged.
How do the beliefs about the structure of matter evolve?
How do the beliefs about the structure of matter evolve?
Our understanding of the structure of matter has evolved over time through a combination of observation, experimentation, and theoretical development.
Describe the early developments leading to the modern concept of the atom.
Describe the early developments leading to the modern concept of the atom.
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Can we see atoms with our naked eyes?
Can we see atoms with our naked eyes?
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Describe the five postulates of Dalton’s atomic theory.
Describe the five postulates of Dalton’s atomic theory.
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How do scientific ideas develop based on previous scientific findings?
How do scientific ideas develop based on previous scientific findings?
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What is the law that Dalton formulated based on the law of conservation of mass and the law of definite proportions? Write its statement in your notebook.
What is the law that Dalton formulated based on the law of conservation of mass and the law of definite proportions? Write its statement in your notebook.
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The mass of a piece of wood before and after it is burnt to ashes is not the same. Does this show that mass is created or destroyed?
The mass of a piece of wood before and after it is burnt to ashes is not the same. Does this show that mass is created or destroyed?
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What would be the mass of products if the burning of wood was carried out in a closed container?
What would be the mass of products if the burning of wood was carried out in a closed container?
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Sugar consists of C, H, and O Atoms. When a certain amount of sugar is burned in a crucible, it changes from white sugar to black carbon. Where has the hydrogen and oxygen gone?
Sugar consists of C, H, and O Atoms. When a certain amount of sugar is burned in a crucible, it changes from white sugar to black carbon. Where has the hydrogen and oxygen gone?
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What mass of hydrogen and oxygen can be obtained from
a. 18.0 g of water
b. 1.00 g of water
What mass of hydrogen and oxygen can be obtained from a. 18.0 g of water b. 1.00 g of water
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Show how the following data illustrate the law of multiple proportions:
Compound A Compound B Compound C
Mass of nitrogen that
combines with 1 g of oxygen 1.750 g 0.8750 g 0.4375 g
Show how the following data illustrate the law of multiple proportions:
Compound A Compound B Compound C
Mass of nitrogen that combines with 1 g of oxygen 1.750 g 0.8750 g 0.4375 g
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List the postulates of Dalton's that continue to have significance (are retained in the modern atomic theory).
List the postulates of Dalton's that continue to have significance (are retained in the modern atomic theory).
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How does the atomic theory account for the fact that when 1.00 g of water is decomposed into its elements, 0.112 g of hydrogen and 0.888 g of oxygen are obtained regardless of the source of the water?
How does the atomic theory account for the fact that when 1.00 g of water is decomposed into its elements, 0.112 g of hydrogen and 0.888 g of oxygen are obtained regardless of the source of the water?
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Which of Dalton’s postulates about atoms are inconsistent with later observations? Do these inconsistencies mean that Dalton was wrong?
Which of Dalton’s postulates about atoms are inconsistent with later observations? Do these inconsistencies mean that Dalton was wrong?
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Is Dalton’s model still useful?
Is Dalton’s model still useful?
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Describe the limitations of Dalton’s atomic theory.
Describe the limitations of Dalton’s atomic theory.
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Explain the postulates of the modern atomic theory.
Explain the postulates of the modern atomic theory.
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List the three fundamental laws of chemistry.
List the three fundamental laws of chemistry.
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How does the modern atomic theory explain the three fundamental laws of chemistry?
How does the modern atomic theory explain the three fundamental laws of chemistry?
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Describe the properties of cathode rays.
Describe the properties of cathode rays.
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Which rays are used to see whether bones are broken or not?
Which rays are used to see whether bones are broken or not?
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Does radioactivity support Dalton’s idea of atoms?
Does radioactivity support Dalton’s idea of atoms?
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Describe the common types of radioactive emissions.
Describe the common types of radioactive emissions.
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Why did most of the α-particles pass through the foil undeflected?
Why did most of the α-particles pass through the foil undeflected?
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Why did only a small fraction of the α-particles show a slight deflection?
Why did only a small fraction of the α-particles show a slight deflection?
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Why didn't all α-particles bounce at an angle of 180°?
Why didn't all α-particles bounce at an angle of 180°?
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Based on the findings of Rutherford’s experiment, what is your conclusion about an atom?
Based on the findings of Rutherford’s experiment, what is your conclusion about an atom?
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When Rutherford’s co-workers bombarded gold foil with α-particles, they obtained results that overturned the existing (Thomson) model of the atom. Explain.
When Rutherford’s co-workers bombarded gold foil with α-particles, they obtained results that overturned the existing (Thomson) model of the atom. Explain.
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A sample of a radioactive element is found to be losing mass gradually. Explain what is happening to the sample.
A sample of a radioactive element is found to be losing mass gradually. Explain what is happening to the sample.
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Describe the experimental basis for believing that the nucleus occupies a very small fraction of the volume of the atom.
Describe the experimental basis for believing that the nucleus occupies a very small fraction of the volume of the atom.
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Study Notes
Atomic Structure and Periodic Properties
- This unit covers the historical development of atomic structure, experimental observations, subatomic particles, atomic mass, isotopes, electromagnetic radiation, atomic spectra, Bohr models, quantum mechanical models, periodic law, and related electronic configurations.
- It also discusses scientific enquiry skills relevant to the unit.
Early Atomic Concepts
- Ancient Greek philosophers debated whether matter was infinitely divisible or composed of indivisible particles.
- Democritus proposed the concept of atoms (atomos), meaning indivisible.
Dalton's Atomic Theory
- Dalton's atomic theory, formulated in 1808, gained wide acceptance.
- Five postulates of Dalton's atomic theory are presented.
Modern Atomic Theory and Laws of Chemistry
- The modern atomic theory incorporates modifications and additions to Dalton's theory based on experimental evidence.
- Laws of conservation of mass, definite proportions, and multiple proportions are fundamental laws that underpin Dalton's theory.
Early Experiments to Characterize the Atom
- Discovery of the electron: J.J. Thomson's experiments with cathode rays demonstrated the existence of negatively charged particles (electrons) in all matter.
- Thomson's "plum-pudding" model: This model depicted electrons scattered throughout a positively charged atom.
- Radioactivity: Radioactive decay is the spontaneous emission of particles and radiation from unstable atomic nuclei.
- Rutherford's gold foil experiment: This experiment disproved Thomson's model, revealing a dense, positively charged nucleus at the atom's center.
Subatomic Particles
- Proton: Positively charged particle in the atom's nucleus.
- Neutron: Neutral particle in the atom's nucleus, similar in mass to a proton.
- Electron: Negatively charged particle orbiting the nucleus.
- These subatomic particles have different masses and charges.
Atomic Mass and Isotopes
- Atomic number (Z) is the number of protons in an atom.
- Mass number (A) is the total number of protons and neutrons in an atom.
- Isotopes are atoms of the same element with different numbers of neutrons, and therefore different mass numbers.
- Relative atomic mass (atomic mass) is the weighted average of the masses of all isotopes of an element.
Electromagnetic Radiation and Atomic Spectra
- Electromagnetic radiation (EMR) consists of electric and magnetic fields vibrating perpendicularly.
- EMR has a wavelength (λ), frequency (ν), and speed (c = νλ).
- The electromagnetic spectrum encompasses a broad range of frequencies and wavelengths.
- Emission spectra of atoms show a series of discrete lines due to transitions between quantized energy levels.
- A photon is a particle of light energy (E = hν = hc/λ).
Bohr's Model of the Atom
- Bohr's model describes the atom as having quantized energy levels for electrons.
- Electrons orbit in specific, fixed energy levels around the nucleus.
- Electrons absorb or emit energy when they change orbits, resulting in characteristic spectral lines.
Quantum Mechanical Model
- The quantum mechanical model of the atom incorporates wave-particle duality and the Heisenberg uncertainty principle.
- Electrons are described by probability distributions (orbitals) instead of fixed orbits.
- Four quantum numbers (n, ℓ, ml, ms) describe the properties of each electron.
Electronic Configurations and Orbital Diagrams
- Aufbau principle, Hund's rule, and Pauli exclusion principle govern the filling of atomic orbitals.
- Electronic configurations and orbital diagrams show the arrangement of electrons in orbitals.
- Valence electrons are the electrons in the outermost energy level, affecting bonding.
Limitations of Bohr's Model
- Bohr's model doesn’t explain the spectra of complex atoms.
- It doesn't account for the splitting of spectral lines in magnetic fields, and contradicts the uncertainty principle.
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Description
Test your knowledge on atomic structure and the periodic properties of elements. This quiz covers historical developments, Dalton's atomic theory, modern atomic theory, and key concepts such as isotopes and atomic spectra. Dive into the foundational aspects of chemistry and enhance your understanding of atomic models.