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Questions and Answers
What did Thomson's cathode ray tube experiment demonstrate about the particles within the beam?
What did Thomson's cathode ray tube experiment demonstrate about the particles within the beam?
- They are positively charged and have no mass.
- They are neutral particles with no charge.
- They do not exist.
- They have mass and a negative charge. (correct)
What fundamental characteristic of electrons was revealed through Millikan's oil drop experiment?
What fundamental characteristic of electrons was revealed through Millikan's oil drop experiment?
- They have mass and can accumulate static charge. (correct)
- They do not have mass.
- They have a variable charge based on their environment.
- They have a positive charge.
Which scientist is credited with discovering the proton through his gold foil experiment?
Which scientist is credited with discovering the proton through his gold foil experiment?
- J.J. Thomson
- Albert Einstein
- Robert Millikan
- Ernest Rutherford (correct)
What was a key observation in Thomson's experiment that indicated the presence of electrons?
What was a key observation in Thomson's experiment that indicated the presence of electrons?
What does the plum pudding model suggest about the structure of an atom?
What does the plum pudding model suggest about the structure of an atom?
What conclusion did Rutherford draw regarding the structure of the atom?
What conclusion did Rutherford draw regarding the structure of the atom?
What is the significance of the nucleus in an atom according to Rutherford?
What is the significance of the nucleus in an atom according to Rutherford?
Which of the following best describes the 'solar system' model of the atom?
Which of the following best describes the 'solar system' model of the atom?
What does the 'right-hand rule' help to determine?
What does the 'right-hand rule' help to determine?
Which of the following defines an isotope?
Which of the following defines an isotope?
What does the atomic number represent?
What does the atomic number represent?
How do you calculate the number of neutrons in an atom?
How do you calculate the number of neutrons in an atom?
What is true about ions?
What is true about ions?
What distinguishes average atomic mass from relative atomic mass?
What distinguishes average atomic mass from relative atomic mass?
Which isotope is the most abundant form of hydrogen?
Which isotope is the most abundant form of hydrogen?
What does mass number represent in an atom?
What does mass number represent in an atom?
How is the charge of an ion determined?
How is the charge of an ion determined?
What is a common misconception about the nucleus of an atom?
What is a common misconception about the nucleus of an atom?
What is the structure of the isotope gallium-70?
What is the structure of the isotope gallium-70?
What does Dalton's Atomic Theory state about atoms of a given element?
What does Dalton's Atomic Theory state about atoms of a given element?
According to the Law of Multiple Proportions, how do the weights of elements combine to form different compounds?
According to the Law of Multiple Proportions, how do the weights of elements combine to form different compounds?
What is a key assumption of Dalton's Atomic Theory regarding chemical reactions?
What is a key assumption of Dalton's Atomic Theory regarding chemical reactions?
What does the Law of Definite Proportions state about a given chemical compound?
What does the Law of Definite Proportions state about a given chemical compound?
Which of the following is NOT one of Dalton's Atomic Theory postulates?
Which of the following is NOT one of Dalton's Atomic Theory postulates?
How did J.J. Thomson contribute to the understanding of atomic structure?
How did J.J. Thomson contribute to the understanding of atomic structure?
What implication does Dalton's theory have regarding the indivisibility of atoms?
What implication does Dalton's theory have regarding the indivisibility of atoms?
Which example illustrates the Law of Multiple Proportions?
Which example illustrates the Law of Multiple Proportions?
What does the Law of Octaves state about the chemical properties of elements?
What does the Law of Octaves state about the chemical properties of elements?
Which of the following correctly describes valence electrons?
Which of the following correctly describes valence electrons?
How does nuclear charge affect electronegativity?
How does nuclear charge affect electronegativity?
Which bond type is formed typically between two nonmetals?
Which bond type is formed typically between two nonmetals?
What is the effect of increased shielding on ionization energy?
What is the effect of increased shielding on ionization energy?
Which description best fits metallic bonding?
Which description best fits metallic bonding?
What determines the shape of a molecule according to VSEPR theory?
What determines the shape of a molecule according to VSEPR theory?
What occurs when the shielding effect increases in an atom?
What occurs when the shielding effect increases in an atom?
In Lewis structures, what is the central atom typically based on?
In Lewis structures, what is the central atom typically based on?
What is a characteristic feature of noble gases regarding electronegativity?
What is a characteristic feature of noble gases regarding electronegativity?
When considering ionic radii, how does nuclear charge affect the size of ions?
When considering ionic radii, how does nuclear charge affect the size of ions?
What does formal charge help determine in a chemical compound?
What does formal charge help determine in a chemical compound?
What type of bond is formed when two atoms share electrons equally?
What type of bond is formed when two atoms share electrons equally?
In electron configurations, valence electrons are critical for understanding which concept?
In electron configurations, valence electrons are critical for understanding which concept?
Which color of light corresponds to the highest energy according to the electromagnetic spectrum?
Which color of light corresponds to the highest energy according to the electromagnetic spectrum?
What happens to energy levels as the orbits of electrons get higher?
What happens to energy levels as the orbits of electrons get higher?
What is the principle demonstrated by the double-slit experiment?
What is the principle demonstrated by the double-slit experiment?
In spectroscopy, what does a dark line in an absorption spectrum indicate?
In spectroscopy, what does a dark line in an absorption spectrum indicate?
According to the deBroglie hypothesis, what duality do electrons exhibit?
According to the deBroglie hypothesis, what duality do electrons exhibit?
Which principle states that electrons will fill the lowest energy orbitals first?
Which principle states that electrons will fill the lowest energy orbitals first?
The Uncertainty Principle, proposed by Heisenberg, highlights what challenge in measuring particles?
The Uncertainty Principle, proposed by Heisenberg, highlights what challenge in measuring particles?
Which of the following correctly describes the emission spectrum?
Which of the following correctly describes the emission spectrum?
What does the orbital notation show in electron configurations?
What does the orbital notation show in electron configurations?
In relation to electron configurations, how many electrons can the 'd' subshell hold?
In relation to electron configurations, how many electrons can the 'd' subshell hold?
How many electrons can the 'f' subshell hold?
How many electrons can the 'f' subshell hold?
What does the photoelectric effect demonstrate about light?
What does the photoelectric effect demonstrate about light?
Which of the following scientists contributed to the Quantum Mechanical Model of the atom?
Which of the following scientists contributed to the Quantum Mechanical Model of the atom?
What is the primary focus of the Quantum Mechanical Model?
What is the primary focus of the Quantum Mechanical Model?
Flashcards
Plum Pudding Model
Plum Pudding Model
Thomson's model of the atom, where negatively charged electrons are embedded in a positively charged sphere like plums in a pudding.
Thomson's Cathode Ray Tube Experiment
Thomson's Cathode Ray Tube Experiment
J.J. Thomson used a cathode ray tube to demonstrate the existence of electrons. He observed that a beam of particles, later identified as electrons, traveled from the cathode to the anode.
Millikan's Oil Drop Experiment
Millikan's Oil Drop Experiment
Robert Millikan's experiment involved observing the motion of tiny oil drops suspended between charged plates. By analyzing how the drops moved, he could determine the charge of a single electron.
Proton
Proton
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Rutherford's Gold Foil Experiment
Rutherford's Gold Foil Experiment
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Dalton's Atomic Theory - Postulate 1
Dalton's Atomic Theory - Postulate 1
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Dalton's Atomic Theory - Postulate 2
Dalton's Atomic Theory - Postulate 2
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Dalton's Atomic Theory - Postulate 3
Dalton's Atomic Theory - Postulate 3
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Dalton's Atomic Theory - Postulate 4
Dalton's Atomic Theory - Postulate 4
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Dalton's Atomic Theory - Postulate 5
Dalton's Atomic Theory - Postulate 5
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Law of Multiple Proportions
Law of Multiple Proportions
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Law of Definite Proportions
Law of Definite Proportions
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Dalton's Atomic Theory - Incorrect
Dalton's Atomic Theory - Incorrect
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Solar System Model of the Atom
Solar System Model of the Atom
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Gold Foil Experiment
Gold Foil Experiment
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Atomic Nucleus
Atomic Nucleus
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Location of Protons and Neutrons
Location of Protons and Neutrons
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Isotope
Isotope
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Ion
Ion
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Atomic Number
Atomic Number
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Mass Number
Mass Number
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Number of Neutrons
Number of Neutrons
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Relative Atomic Mass
Relative Atomic Mass
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Average Atomic Mass
Average Atomic Mass
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Most Abundant Isotope
Most Abundant Isotope
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Right-Hand Rule
Right-Hand Rule
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Scientific Method
Scientific Method
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Electron
Electron
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Light Color and Energy
Light Color and Energy
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Wavelength
Wavelength
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Wavelength and Energy
Wavelength and Energy
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Spectroscopy
Spectroscopy
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Emission Spectrum
Emission Spectrum
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Absorption Spectrum
Absorption Spectrum
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Interference Pattern
Interference Pattern
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Photoelectric Effect
Photoelectric Effect
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Bohr Model
Bohr Model
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deBroglie Hypothesis
deBroglie Hypothesis
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Quantum Mechanical Model
Quantum Mechanical Model
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Heisenberg's Uncertainty Principle
Heisenberg's Uncertainty Principle
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Subshell Notation
Subshell Notation
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Aufbau Principle
Aufbau Principle
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Hund's Rule
Hund's Rule
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Newlands' Law of Octaves
Newlands' Law of Octaves
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Valence Electrons
Valence Electrons
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Shielding
Shielding
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Nuclear Charge
Nuclear Charge
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Electron Repulsion
Electron Repulsion
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Electronegativity
Electronegativity
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Ionization Energy
Ionization Energy
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Atomic/Ionic Radii
Atomic/Ionic Radii
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Metallic Bonding
Metallic Bonding
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Ionic Bonding
Ionic Bonding
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Covalent Bonding
Covalent Bonding
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Lewis Structures
Lewis Structures
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VSEPR Theory
VSEPR Theory
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Hybridization
Hybridization
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Expanded Octets
Expanded Octets
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Study Notes
Atomic Structure of Matter
- Dalton's Atomic Theory postulates that elements are composed of indestructible atoms, atoms of the same element are identical, compounds form when combining different atoms in specific ratios, chemical reactions rearrange atoms, and atoms cannot be divided.
- Law of Multiple Proportions states that when elements combine to form multiple compounds, the ratios of the weights of one element combining with a fixed weight of another are in whole numbers.
- Law of Definite Proportions asserts that a given compound always contains the same elements in the exact same proportions by mass.
Discovery of the Electron and the Nucleus
- J.J. Thomson used the cathode ray tube experiment to discover the electron and proposed the plum pudding model of the atom.
- Observations from the experiment included cathode ray beams traveling from cathode to anode, the beams being composed of particles (having mass), and the particles having a negative charge.
- The plum pudding model suggested that the atom is a sphere of positive charge with negatively charged electrons embedded within it.
Robert Millikan and the Oil Drop Experiment
- Robert Millikan's oil drop experiment determined the mass and charge of an electron.
- The experiment suspended tiny oil drops between two charged plates, and by observing their motion, Millikan determined the charge on each drop.
Ernest Rutherford and the Gold Foil Experiment
- Ernest Rutherford's gold foil experiment discovered the atomic nucleus.
- Alpha particles were aimed at a thin gold foil; most passed through, but some were significantly deflected, indicating a concentrated positive charge in a small, dense region (the nucleus) within the atom.
- This led to the development of the solar system model of the atom.
The Bohr Model and the de Broglie Hypothesis
- The Bohr model describes electrons orbiting the nucleus in specific energy levels.
- The deBroglie Hypothesis suggested that electrons exhibit wave-like properties.
The Quantum Mechanical Model
- The quantum mechanical model views electrons as waves within orbitals in atoms.
- Electrons reside in specific orbitals or regions of space within the atom.
Electron Configurations
- Subshell notation describes electron configuration using subshells (s, p, d, f) to indicate the electron arrangement within specific energy levels.
- The amount of electrons each sublevel can hold is s = 2, p = 6, d = 10, and f = 14.
- Orbital notation diagrams use boxes and arrows to represent electrons in orbitals, considering their spins (up or down).
- Aufbau Principle determines that orbitals with the lowest energy levels are filled first, following Hund's rule that all orbitals in a subshell are singly occupied before any pairing occurs. Pauli's exclusion principle dictates that no two electrons in an atom can have the same four quantum numbers.
- Exceptions to these are relevant to electron configuration within specific atoms.
Periodic Table
- Dimitri Mendeleev and Lothar Meyer developed the periodic table in 1869 based on the repeating pattern within elements' chemical and physical properties.
- Newlands' law of octaves demonstrated a repeating pattern every 8 elements, though not widely recognised at the time.
Periodic Properties and Trends
- Shielding occurs when inner electron shells repel outer electrons, lessening the attractive force between the nucleus and outer electrons.
- Nuclear charge corresponds to the number of protons in the nucleus, increasing the pull on electrons.
- Electronegativity measures the ability of an atom to attract shared electrons, increasing with greater nuclear charge and less shielding.
- Ionization energies increase with greater nuclear charge and less shielding.
- Ionic radii grow larger with more shielding and smaller with increasing nuclear charge.
Chemical Bonding and Formulas
- Chemical bonds are formed when electrons are shared or transferred between atoms.
- Covalent bonds occur between nonmetals.
- Metallic bonds form when metals share electrons.
- Ionic bonds form when a metal transfers electrons to a nonmetal.
- Lewis structures represent atoms bonding; valence electrons are shown with dots, bonding electrons paired with lines.
- Formal Charge and Resonance analysis helps identify the most probable structure for a molecule.
VSEPR Theory
- VSEPR (Valence Shell Electron Pair Repulsion) theory predicts molecular shapes based on repulsion between electron pairs.
- Electron domains are regions around central atoms where electrons reside.
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