Atomic Models and Principles Quiz

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Questions and Answers

Which principle states that each electron occupies the lowest energy orbital available?

  • Pauli exclusion principle
  • Hund’s rule
  • Heisenberg uncertainty principle
  • Aufbau principle (correct)

How many orbitals are present in the D sublevel?

  • 7
  • 1
  • 3
  • 5 (correct)

What does the quantum number 'n' represent in the quantum mechanical model of the atom?

  • Principal energy level (correct)
  • Orbital shape
  • Electron spin
  • Number of electrons

Which of the following correctly describes the Heisenberg uncertainty principle?

<p>The position and velocity of a particle can't be known simultaneously. (A)</p> Signup and view all the answers

What must occur when energy is added to an electron in an atom?

<p>The electron moves to a higher energy state. (B)</p> Signup and view all the answers

Which rule states that single electrons with the same spin must occupy each orbital before pairing?

<p>Hund’s rule (A)</p> Signup and view all the answers

What is the maximum number of electrons that can occupy the S sublevel?

<p>2 (A)</p> Signup and view all the answers

What is meant by the term 'ground state' in relation to an atom?

<p>An atom's lowest energy level (B)</p> Signup and view all the answers

Flashcards

Aufbau Principle

States that electrons occupy the lowest available energy levels first, filling orbitals in order of increasing energy.

Valence Electrons

Electrons in the outermost energy level of an atom, responsible for its chemical behavior.

Pauli Exclusion Principle

In a multi-electron atom, each orbital can hold a maximum of two electrons, but only if they have opposite spins.

Hund's Rule

For degenerate orbitals, single electrons with the same spin occupy each orbital before pairing up in any one orbital.

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Ground State

The lowest energy state of an atom, where all electrons occupy the lowest possible energy levels.

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Electron Cloud

A region around the nucleus where an electron is most likely to be found, often visualized as a probability cloud.

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Orbital Diagram

A representation of an atom's electron configuration using arrows to indicate the spin of each electron in its orbitals.

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Noble Gas Notation

A shorthand method of representing an atom's electron configuration using the previous noble gas element followed by the remaining electron configuration.

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Study Notes

Atomic Models: Principles and Structure

  • Bohr Model:

    • Electrons exist in specific energy levels (allowed energy states)
    • Electrons orbit the nucleus in circular paths
    • When electrons absorb energy, they jump to a higher energy level; releasing energy when returning to a lower level.
  • De Broglie Model:

    • Electrons exhibit wave-like properties
    • Electrons have specific wavelengths, frequencies, and energies
    • Electrons do not move in fixed circular orbits around the nucleus
  • Heisenberg's Uncertainty Principle:

    • Simultaneous precise determination of an electron's position and velocity is impossible
    • It's not possible to predict a fixed path for electrons
    • The probability of finding an electron in a region around the nucleus can be determined
  • Schrödinger's Quantum Mechanical Model:

    • Electrons do not have fixed paths around the nucleus
    • Electrons behave as waves
    • The electron cloud represents the greatest probability of finding an electron in a given region around the nucleus

Quantum Mechanical Model Details

  • Principal Energy Level (n):

    • Represents the energy level of an electron
    • n = 1, 2, 3 etc (increasing energy levels)
  • Sublevels per Level (n):

    • n = 1: 1 sublevel (s) holding 2 electrons
    • n = 2: 2 sublevels (s, p) holding 8 electrons
    • n = 3: 3 sublevels (s, p, d) holding 18 electrons
    • n = 4: 4 sublevels (s, p, d, f) holding 32 electrons
  • Orbitals per Sublevel:

    • s: 1 orbital
    • p: 3 orbitals
    • d: 5 orbitals
    • f: 7 orbitals
  • Electrons per Orbital/Sublevel:

    • Each orbital holds a maximum of 2 electrons
    • s: 2 electrons
    • p: 6 electrons
    • d: 10 electrons
    • f: 14 electrons
  • Orbital Size and Energy:

    • As n increases, orbitals become larger and have higher energy
  • Ground State:

    • The lowest energy level of an atom

Electron Arrangement Rules

  • Aufbau Principle:

    • Electrons fill the lowest energy orbitals first
  • Pauli Exclusion Principle:

    • A maximum of two electrons can occupy an orbital, with opposite spins
  • Hund's Rule:

    • Electrons fill orbitals of equal energy singly before doubling up

Electron Configuration Notation Examples

  • Electron Configuration Notation:

    • 1s2, 2s2, 2p6, 3s2, 3p5
  • Noble Gas Notation:

    • [Ne] 3s2, 3p5
  • Orbital Diagrams (Example):

    1s   2s        2p        3s        3p 
    [^v] [^v] [^v|^v|^v] [^v] [^v|^v|^v] 
    

Chemical Behavior

  • Valence Electrons:
    • Electrons in the outermost energy level
    • Determine the chemical behavior of an element

Electron-Dot Structures

  • Components:

    • Valence electrons
  • Example (Correct): Cl·

  • Example (Incorrect): …… Cl·

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