Assertion-Reason Questions for Chemistry Exam
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Assertion: In zinc, 3d orbitals are completely filled in its ground state as well as in its oxidized state. Reason: In zinc, 3d orbitals are completely filled in its ground state as well as in its oxidized state.

  • Assertion is false but Reason is true.
  • Assertion and Reason both are true but Reason is not the correct explanation for Assertion.
  • Assertion is true but Reason is false.
  • Assertion and Reason both are true and Reason is the correct explanation for Assertion. (correct)
  • Assertion: In a first-order reaction, when the concentration of the reactant is doubled, its half-life is also doubled. Reason: The half-life of a reaction does not depend upon the initial concentration of the reactant in a first-order reaction.

  • Assertion is true but Reason is false.
  • Assertion and Reason both are true but Reason is not the correct explanation for Assertion.
  • Assertion and Reason both are true and Reason is the correct explanation for Assertion.
  • Assertion is false but Reason is true. (correct)
  • Assertion: Acetylation of aniline results in a decrease of electron density on nitrogen. Reason: Acetylation of aniline results in a decrease of electron density on nitrogen.

  • Assertion and Reason both are true and Reason is the correct explanation for Assertion. (correct)
  • Assertion is false but Reason is true.
  • Assertion and Reason both are true but Reason is not the correct explanation for Assertion.
  • Assertion is true but Reason is false.
  • Assertion: Vitamins A, D, E and K are stored in liver and adipose tissue. Reason: Vitamins A, D, E and K are soluble in fats and oils.

    <p>Assertion and Reason both are true and Reason is the correct explanation for Assertion. (D)</p> Signup and view all the answers

    Assertion: The base thymine is present in RNA while base uracil is present in DNA. Reason: The base thymine is present in RNA while base uracil is present in DNA.

    <p>Assertion is true but Reason is false. (C)</p> Signup and view all the answers

    Assertion: Adenine forms hydrogen bonds with guanine and thymine forms hydrogen bonds with cytosine. Reason: Adenine forms hydrogen bonds with guanine and thymine forms hydrogen bonds with cytosine.

    <p>Assertion is true but Reason is false. (B)</p> Signup and view all the answers

    Assertion: Glucose is not so reactive to form the product with. Reason: Glucose is not so reactive to form the product with.

    <p>Assertion is false but Reason is true. (C)</p> Signup and view all the answers

    Assertion: The human system contains cellulose enzyme which hydrolyze cellulose into glucose. Reason: The human system contains cellulose enzyme which hydrolyze cellulose into glucose.

    <p>Assertion is true but Reason is false. (B)</p> Signup and view all the answers

    Assertion: The carbonyl group is present in the open chain structure of glucose. Reason: The carbonyl group is present in the open chain structure of glucose.

    <p>Assertion and Reason both are true and Reason is the correct explanation for Assertion. (C)</p> Signup and view all the answers

    Assertion: Reason:

    <p>Assertion and Reason both are true but Reason is not the correct explanation for Assertion. (D)</p> Signup and view all the answers

    Which statement is true regarding the discharge of a lead storage battery?

    <p>Both Pb and PbO are produced. (B)</p> Signup and view all the answers

    What correctly describes the bond arrangement in tetrahedral complexes?

    <p>Ligands have the same relative position to the metal atom. (B)</p> Signup and view all the answers

    What happens to the molarity of a liquid state solution with temperature changes?

    <p>It changes due to volume variation. (C)</p> Signup and view all the answers

    Which statement compares the coloration of [Ti(H2O)6]3+ and [Sc(H2O)6]3+?

    <p>[Ti(H2O)6]3+ is colored and [Sc(H2O)6]3+ is colorless. (D)</p> Signup and view all the answers

    Which complex involves d2sp3 hybridization?

    <p>[Mn(CN)6]3− (B)</p> Signup and view all the answers

    What is true regarding weak electrolytes upon dilution?

    <p>Degree of dissociation increases. (B)</p> Signup and view all the answers

    Which condition applies to the diffusion of solvent molecules through a semipermeable membrane?

    <p>Diffusion occurs from high concentration to low concentration. (D)</p> Signup and view all the answers

    What happens to the anion after the removal of α-hydrogen?

    <p>It is stabilized by inductive effect. (D)</p> Signup and view all the answers

    What is the significance of the large ionization energy of Cu?

    <p>It is compensated by hydration energy of Cu²⁺. (D)</p> Signup and view all the answers

    What accurately describes tertiary amines?

    <p>They have no hydrogen atoms attached. (D)</p> Signup and view all the answers

    Which statement about mercury cells is correct?

    <p>Mercury cells maintain a constant voltage during their operational life. (D)</p> Signup and view all the answers

    What is true regarding the equivalent conductance of acetic acid at infinite dilution?

    <p>It cannot be determined using the extrapolation method. (A)</p> Signup and view all the answers

    How does the presence of a nitro group affect haloarenes?

    <p>It decreases their reactivity towards nucleophilic substitution. (D)</p> Signup and view all the answers

    For zero order reactions, which statement is accurate?

    <p>Rate remains constant regardless of changes in concentration. (D)</p> Signup and view all the answers

    What occurs when NaCl is added to water?

    <p>There is a depression in freezing point observed. (A)</p> Signup and view all the answers

    What happens to the magnetic moment values of actinides compared to predicted values?

    <p>They are lesser than the predicted values. (D)</p> Signup and view all the answers

    Why can inert electrolytes like KCl not be used in certain salt bridges?

    <p>They react with silver ions. (D)</p> Signup and view all the answers

    What is the reason for using ethylene glycol in water as antifreeze?

    <p>It lowers the freezing point of water. (B)</p> Signup and view all the answers

    Which statement about crystal field splitting in ferrocyanide and ferricyanide ions is true?

    <p>Ferricyanide shows more splitting than ferrocyanide. (A)</p> Signup and view all the answers

    Which explanation is accurate regarding the use of Kohlrausch's Law?

    <p>It is used to find molar conductivity at infinite dilution. (D)</p> Signup and view all the answers

    Why does lowering vapor pressure cause depression in freezing point?

    <p>Lower vapor pressure affects molecular interaction. (B)</p> Signup and view all the answers

    What characterizes the intermediate carbocation in phenol?

    <p>It is stabilized by resonance effects. (A)</p> Signup and view all the answers

    What is the relationship between freezing point depression and solute concentration?

    <p>Increased solute concentration results in greater freezing point depression. (C)</p> Signup and view all the answers

    What correctly describes the efficiency of H2-O2 fuel cells?

    <p>Their efficiency ranges between 60-70%. (B)</p> Signup and view all the answers

    Which of the following is a requirement for accessing the Cognitive Conquest test mentioned in the text?

    <p>JavaScript must be enabled in the web browser (A)</p> Signup and view all the answers

    What is the suggested timeframe for taking the Cognitive Conquest test?

    <p>The test can be taken at any time before a specific date (D)</p> Signup and view all the answers

    What is the purpose of the Cognitive Conquest test?

    <p>To measure a person's knowledge of the subject matter for board exams (D)</p> Signup and view all the answers

    What is the significance of the Specimen Paper 2025 mentioned in the text?

    <p>It provides a sample paper for users to familiarize themselves with the question types available on the Cognitive Conquest test (B)</p> Signup and view all the answers

    What should a user do if the assertion is false, and the reason statement is true?

    <p>Select the option that indicates both the assertion and the reason are false (D)</p> Signup and view all the answers

    Which of the following is NOT mentioned as a feature of the Cognitive Conquest test in the given text?

    <p>Interactive question types like drag-and-drop or fill-in-the-blanks (B)</p> Signup and view all the answers

    What can be inferred from the phrase 'This test will be disabled on 8th February'?

    <p>The test will no longer be available after 8th February (C)</p> Signup and view all the answers

    What does the phrase "Refer to your Specimen Paper 2025" suggest?

    <p>The Specimen Paper 2025 gives users an idea of the question types and difficulty level of the actual test (C)</p> Signup and view all the answers

    What occurs to the degree of ionization of a weak electrolyte on increasing dilution?

    <p>It increases and the mobility of ions increases. (B)</p> Signup and view all the answers

    Why is it more challenging to substitute chlorine with -OH in chlorobenzene compared to chloroethane?

    <p>Chlorobenzene's chlorine-carbon bond has partial double bond character due to resonance. (D)</p> Signup and view all the answers

    How does the boiling point of alcohols change with decreasing branching of the carbon chain?

    <p>It decreases due to decreased van der Waals forces. (A)</p> Signup and view all the answers

    What is the effect of the -OH group on the bromination of phenol?

    <p>It facilitates bromination even in the absence of a Lewis acid. (C)</p> Signup and view all the answers

    What is the relationship between order and molecularity in chemical reactions?

    <p>Order is determined experimentally, while molecularity is the sum of the reaction coefficients. (B)</p> Signup and view all the answers

    What happens to the number of ions per unit volume during dilution?

    <p>It decreases, leading to lower concentration. (B)</p> Signup and view all the answers

    How does the partial double bond character of the C—Cl bond in chlorobenzene affect its reactivity?

    <p>It makes the bond more rigid, hindering substitution. (B)</p> Signup and view all the answers

    What is a likely reason for the discrepancy between the bromination rates of phenol and other compounds?

    <p>Phenol's -OH group has a unique activating effect. (D)</p> Signup and view all the answers

    Which of the following describes the concept of ion mobility in diluted solutions?

    <p>Ion mobility increases with dilution. (D)</p> Signup and view all the answers

    Why would a weak electrolyte show increased ionization upon dilution?

    <p>The concentration of undissociated molecules is lower, promoting ionization. (A)</p> Signup and view all the answers

    What is the primary reason that branching in carbon chains affects alcohol boiling points?

    <p>Increased distances between molecules decrease intermolecular attractions. (D)</p> Signup and view all the answers

    What can be said about the chlorine-carbon bond in chlorobenzene compared to aliphatic chlorinated compounds?

    <p>It exhibits enhanced stability due to resonance. (D)</p> Signup and view all the answers

    How does the -OH group in phenol influence its nucleophilicity?

    <p>It enhances nucleophilicity by making the phenolic oxygen more reactive. (C)</p> Signup and view all the answers

    What is true regarding the assertion that molecularity is the sum of the molecular species in a reaction?

    <p>Molecularity is always a whole number in elementary reactions. (C)</p> Signup and view all the answers

    Flashcards

    Assertion

    A statement that is claimed to be true.

    Reason Statement

    An explanation or justification for an assertion.

    True Assertion

    An assertion that is correct or factual.

    False Assertion

    An assertion that is incorrect or not factual.

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    Assertion Reason Question Type

    A question format requiring evaluation of both assertion and reason.

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    Option (d) Selection

    Choose when both assertion and reason are false.

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    Correct Explanation

    When the reason accurately supports the assertion.

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    Specimen Paper

    Sample tests used for practice or evaluation.

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    Reason

    An explanation that supports or clarifies an assertion.

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    First-order reaction

    A chemical reaction where the rate depends only on the concentration of one reactant.

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    Half-life

    The time required for the concentration of a reactant to decrease by half.

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    Acetylation of aniline

    A chemical reaction that decreases the electron density on nitrogen.

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    Vitamins A, D, E, K

    Fat-soluble vitamins stored in liver and adipose tissue.

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    Thymine and Uracil

    Thymine is in DNA, Uracil is in RNA.

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    Hydrogen bonds in nucleic acids

    Interaction where Adenine bonds with Thymine and Guanine bonds with Cytosine.

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    Cellulose enzyme

    An enzyme in humans that breaks down cellulose into glucose.

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    Carbonyl group in glucose

    A functional group present in glucose's open chain structure.

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    Glucose reactivity

    Glucose is relatively unreactive in certain conditions.

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    Electrons and nitrogen

    Acetylation reduces electron density on nitrogen, affecting bonding.

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    Fat-solubility

    Refers to substances that dissolve in fats and oils.

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    Assertion-Reason relationship

    The connection between an assertion and its supporting reason can vary.

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    Oxidized state of zinc

    The state where zinc's 3d orbitals are filled.

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    H2-O2 fuel cell

    A type of fuel cell with 60-70% efficiency that does not cause pollution.

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    Mercury cells

    Batteries that maintain constant voltage during their lifespan.

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    Resonance stabilization

    A situation where the stability of a carbocation is increased due to electron delocalization.

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    Crystal field splitting

    The energy difference between d-orbitals in coordination compounds.

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    Kohlrausch's Law

    A principle used to calculate molar conductivity of weak electrolytes at infinite dilution.

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    Equivalent conductance of acetic acid

    Cannot be determined experimentally due to its weakness as an acid.

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    Inert electrolytes in salt bridges

    Substances like KCl or KNO3 used to maintain electrical neutrality in electrochemical cells.

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    Zero order reaction

    A reaction where the rate does not depend on the concentration of reactants.

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    Nitro group effect on haloarenes

    Presence of a nitro group increases haloarenes' reactivity in nucleophilic substitution.

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    Freezing point depression

    A decrease in the freezing point of a solution when solutes like NaCl are added to water.

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    Half-life of first order reaction

    The time required for the concentration of a reactant to reduce to half, independent of the initial concentration.

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    Ethylene glycol as antifreeze

    A substance added to water to lower its freezing point due to its ability to form hydrogen bonds.

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    Magnetic moment of actinides

    Actual magnetic moment values are less than the predicted values due to electron interactions.

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    Sulphonyl group

    An electron withdrawing group that influences the properties of attached compounds.

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    Assertion and Reason

    Both can either be true, indicating that one explains the other or not.

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    Degree of ionization

    The extent to which a weak electrolyte dissociates into ions.

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    Weak electrolyte behavior

    Weak electrolytes improve ion mobility upon dilution.

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    Chlorobenzene bond character

    Has partial double bond character due to resonance.

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    Bromination of phenol

    Can occur without Lewis acid due to -OH group's influence.

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    Boiling point of alcohols

    Decreases with increased branching of the carbon chain.

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    Van der Waals forces

    Weak attractions between molecules affecting boiling points.

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    Order of reaction

    Determined experimentally by the rate of reaction.

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    Molecularity

    The number of reactant particles involved in an elementary reaction.

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    Electrophilic attack

    A reaction where an electron-rich species forms a bond with an electron-poor species.

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    Ion mobility

    The ability of ions to move freely in a solution.

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    Chemical substitution difficulty

    Reacts differently based on the nature of substituted groups.

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    Partial double bond character

    A single bond exhibiting some properties of a double bond due to resonance.

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    Hydroxyl group's effect

    Alters reactivity of adjacent aromatic compounds.

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    Discharge of Lead Storage Battery

    During the discharge, both Pb and PbO are involved.

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    Temperature Effect on Molarity

    Molarity changes with temperature due to volume change.

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    Mohr's Salt in Solution

    Mohr's salt dissociates into NH4+, Fe2+, and SO42- ions in water.

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    Color in Metal Complexes

    [Ti(H2O)6]3+ is colored; [Sc(H2O)6]3+ is not due to d-d transition absence.

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    Inner vs Outer Orbital Complex

    [Mn(CN)6]3− has d2sp3 hybridization; [MnCl6]3− has sp3d2 hybridization.

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    Dilution of Weak Electrolytes

    Λm increases sharply for weak electrolytes when diluted as dissociation increases.

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    Solvent Movement in Semipermeable Membrane

    Solvent moves from pure solvent side to solution side due to diffusion.

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    Inductive Effect Stabilization

    Anions left after α-hydrogen removal are stabilized by inductive effects.

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    Ionization Energy and Hydration Energy

    High ionization energy of Cu is balanced by negative hydration energy of Cu²⁺.

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    Protonation in Aniline

    In aniline, the nitrogen's lone pair can be protonated in presence of AlCl3.

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    Study Notes

    Assertion-Reason Questions for Board Exam

    • Assertion-Reason Question Format: Each question presents an Assertion (statement) and a Reason (explanation). Determine if both are true, and if the Reason correctly explains the Assertion.

    • Incorrect Answer Selection (d): If the Assertion is false, even if the Reason is true, select (d) Both Assertion and Reason are False.

    • Important Note: The Reason cannot be true if the Assertion is false.

    • Exam Deadline: The exam will close on February 8th. Take the test before this date.

    • Specimen Paper Reference: Consult the 2025 Specimen Paper.

    • Scoring and Solutions: After submission, view scores and solutions to all questions.

    Chemical Reactions and Properties

    • Zinc's Electronic Configuration: In zinc, 3d orbitals are completely filled in its ground state and oxidized state (Assertion and Reason correct, Reason explains Assertion).

    • First-Order Reaction Half-Life: The half-life of a first-order reaction is independent of the initial reactant concentration (Assertion and Reason correct, Reason explains Assertion).

    • Acetylation of Aniline: Acetylation of aniline decreases electron density on the nitrogen atom (Assertion and Reason correct, Reason explains Assertion).

    • Fat-Soluble Vitamin Storage: Vitamins A, D, E, and K are stored in the liver and adipose tissue because they are fat-soluble (Assertion and Reason correct, Reason explains Assertion).

    • Thymine and Uracil in Nucleic Acids: Thymine is found in DNA, and uracil is found in RNA (Assertion and Reason correct, Reason does not explain Assertion - they are in different molecules).

    • Adenine and Guanine Base Pairing: Adenine bonds with thymine (or uracil in RNA) and Guanine bonds with Cytosine (Assertion and Reason correct, Reason does not explain Assertion).

    • Glucose Reactivity: The assertion and reason information is missing (Insufficient information provided).

    • Cellulose Hydrolysis: The human system does not contain cellulose hydrolyzing enzymes needed to break cellulose down into glucose (Assertion and Reason correct, Reason does not explain Assertion - untrue human system feature).

    • Glucose Open-Chain Structure: The carbonyl group is present in the open-chain structure of glucose (Assertion and Reason correct, Reason explains Assertion).

    Other Chemistry Concepts

    • Dilution of Weak Electrolytes: Increasing dilution increases the degree of ionization and ion mobility in weak electrolytes (Assertion and Reason correct, Reason explains Assertion).

    • Dilution and Ion Concentration: Dilution decreases the number of ions per unit volume (Assertion and Reason correct, Reason explains Assertion).

    • Chlorobenzene vs. Chloroethane Reactivity: It is harder to replace chlorine with -OH in chlorobenzene than in chloroethane due to partial double bond character of the C-Cl bond in chlorobenzene (Assertion and Reason correct, Reason explains Assertion).

    • Phenol Bromination: Phenol undergoes bromination without a Lewis acid catalyst due to the benzene ring deactivation (Assertion and Reason correct, Reason explains Assertion).

    • Alcohol Boiling Points: Branching a carbon chain in alcohols decreases the boiling point due to decreased van der Waals forces due to smaller surface area. (Assertion and Reason correct, Reason explains Assertion).

    • Reaction Order and Molecularity: The assertion and reason information is missing (Insufficient information provided).

    • H₂-O₂ Fuel Cell: The assertion and reason information is missing (Insufficient information provided).

    • Battery Voltage Stability: Mercury cells maintain a constant voltage throughout their lifespan (Assertion and Reason correct, Requires further background, but Reason may, or may not, explain Assertion).

    • Phenol Carbocation Stabilization: In phenol, the intermediate carbocation is more resonance stabilized (Assertion and Reason correct, Reason explains Assertion).

    • Crystal Field Splitting: Crystal field splitting is greater in ferrocyanide than in ferricyanide (Assertion and Reason correct, Reason explains Assertion).

    • Weak Electrolyte Molar Conductivity: Experimental determination of the molar conductivity at infinite dilution of a weak electrolyte is not possible (Assertion and Reason are correct, Reason explains Assertion).

    • Equivalent Conductance of Acetic Acid: The equivalent conductance of acetic acid at infinite dilution can not be determined experimentally by extrapolation methods (Assertion is correct, Reason is correct, Reason explains Assertion).

    • Salt Bridge Electrolytes: Inert electrolytes like KCl, KNO₃, K₂SO₄ are used in salt bridges because they do not react (Assertion and Reason correct, Reason explains Assertion).

    • Zero-Order Reaction Graph: For zero-order reactions, the rate vs. concentration graph is a straight line parallel to the concentration axis (Assertion and Reason correct, Reason explains Assertion).

    • Nitro Group Effect on Haloarenes: The presence of an ortho or para nitro group increases the reactivity of haloarenes to nucleophilic substitution (Assertion and Reason are correct, Reason explains Assertion incorrectly given the effect).

    • Freezing Point Depression by Solutes: Adding NaCl to water lowers its freezing point (Assertion and Correct, Reason explains Assertion).

    • First-order Reaction Half-life: The half-life of a first-order reaction is independent of the initial reactant concentration (Assertion and Reason correct, Reason explains Assertion).

    • Ethylene Glycol Antifreeze: Adding ethylene glycol lowers the freezing point of water and acts as an antifreeze (Assertion and Reason correct, Reason explains Assertion correctly).

    • Inert Electrolytes in Salt Bridge: KCl, NaCl, and NH₄Cl are unsuitable in a silver-containing salt bridge because they react with silver (Assertion and Reason are correct, Reason explains Assertion).

    • Actinide Magnetic Moment: Actinide magnetic moment values are lower than predicted due to shielding (Assertion and Reason correct, Reason explains Assertion).

    • Sulphonyl Group as Electron Withdrawing Group: A sulphonyl group attached to nitrogen is a strong electron-withdrawing group (Assertion and Reason correct, Reason explains Assertion).

    • Lead Storage Battery Discharge: During discharge, both Pb and PbO₂ are involved (Assertion and Reason correct, Reason explains Assertion incorrectly).

    • Tetrahedral Complex Ligand Position: The relative positions of ligands in tetrahedral complexes are the same regarding the central metal atom (Assertion and Reason correct, Reason explains Assertion).

    • Solution Molarity and Temperature: Solution molarity changes with temperature because solutions' volume depends on temperature (Assertion and Reason correct, Reason explains Assertion).

    • Mohr's Salt Ions: Mohr's salt produces NH₄⁺, Fe²⁺, and SO₄²⁻ in aqueous solution (Assertion and reason correct, Reason explains Assertion).

    • Color in Transition Metal Complexes: [Ti(H₂O)₆]³⁺ is colored, but [Sc(H₂O)₆]³⁺ is colorless due to absence of d-d transitions (Assertion and Reason correct, Reason explains Assertion).

    • Inner and Outer Orbital Complexes: [Mn(CN)₆]³⁻ is an inner-orbital complex whereas [MnCl₆]³⁻ is an outer-orbital complex (Assertion and Reason correct, Requires background for clarification on which is the correct reason).

    • Weak Electrolyte Molar Conductivity and Dilution: The molar conductivity of a weak electrolyte increases sharply with dilution because degree of dissociation increases (Assertion and Reason correct, Reason explains Assertion).

    • Solvent Diffusion Across Semipermeable Membrane: Solvent flows from the pure solvent side to the solution side across a semipermeable membrane (Assertion and Reason correct, Requires background to clarify).

    • Anion Stabilization: The absence of alpha-hydrogens stabilizes the remaining portion of the anion (Assertion and Reason are correct, Reason explains Assertion incorrectly - needs clarification).

    • Copper Ion Hydration: Copper's high ionization energy is offset by its strongly negative hydration energy (Assertion and Reason correct, Reason explains Assertion).

    • Tertiary Amines: Tertiary amines have three alkyl or aryl groups attached to nitrogen (Assertion and Reason correct, Reason explains Assertion).

    • Faraday's Constant: 1 Faraday equals the charge of 1 mole of electrons (Assertion and Reason correct, Reason explains Assertion).

    • Aniline Protonation: In aniline, the nitrogen lone pair does not get protonated in the presence of AlCl₃ (Assertion correct, Reason incorrect - requires additional clarification)

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    Prepare for your upcoming chemistry board exam with these Assertion-Reason questions. Each question will test your understanding of key concepts related to chemical reactions and properties, including zinc's electronic configuration and reaction kinetics. Make sure to complete the quiz before the February 8th deadline.

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