Arrangement of Electrons and Hydrogen Spectrum
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Questions and Answers

Barium salts produce a blue color in a flame test.

False (B)

Heisenberg’s Uncertainty principle states that the position and velocity of an electron can be known simultaneously.

False (B)

Millikan’s ‘oil drop’ experiments were aimed at measuring the charge on a proton.

False (B)

The atomic orbital of silicon has a total of 8 occupied orbitals in its ground state.

<p>True (A)</p> Signup and view all the answers

Neils Bohr is known for his work on energy levels in the hydrogen atom.

<p>True (A)</p> Signup and view all the answers

Niels Bohr discovered that the fixed paths for electrons in an atom are called orbits.

<p>True (A)</p> Signup and view all the answers

The emission spectrum of an element can be the same as the emission spectrum of another element.

<p>False (B)</p> Signup and view all the answers

Lithium salts produce a crimson flame when burned in a Bunsen burner.

<p>True (A)</p> Signup and view all the answers

A spectroscope can measure the wavelengths of light in a spectrum.

<p>False (B)</p> Signup and view all the answers

Electrons in their ground state have the highest possible energy.

<p>False (B)</p> Signup and view all the answers

Bohr theorized that energy levels in an atom are represented by the letter 'm'.

<p>False (B)</p> Signup and view all the answers

Copper salts produce a blue-green flame during a flame test.

<p>True (A)</p> Signup and view all the answers

Bohr's model allows an electron to have a continuous range of energy levels.

<p>False (B)</p> Signup and view all the answers

When an electron jumps to a higher energy level, it is said to be in an excited state.

<p>True (A)</p> Signup and view all the answers

The energy absorbed by an atom is always greater than the energy difference between its ground and excited states.

<p>False (B)</p> Signup and view all the answers

The Balmer Series of emissions lines is due to electrons falling to the n=3 energy level.

<p>False (B)</p> Signup and view all the answers

An Atomic Absorption Spectrometer can be used to analyze blood samples for heavy metals.

<p>True (A)</p> Signup and view all the answers

Electrons in the excited state are stable and remain in that state indefinitely.

<p>False (B)</p> Signup and view all the answers

The spectrum of light emitted from an atom can show specific energy values, indicating quantized energy levels.

<p>True (A)</p> Signup and view all the answers

In Atomic Absorption Spectrometry, atoms absorb light of wavelengths that are not characteristic of them.

<p>False (B)</p> Signup and view all the answers

Planck's constant is represented by the letter 'p' in the equation E2 – E1 = hf.

<p>False (B)</p> Signup and view all the answers

The amount of light absorbed is inversely proportional to the concentration of the element present in the sample.

<p>False (B)</p> Signup and view all the answers

Every energy level includes at least one sublevel.

<p>True (A)</p> Signup and view all the answers

The 'd' orbital has a maximum capacity of 8 electrons.

<p>False (B)</p> Signup and view all the answers

Wave-particle duality suggests that particles like electrons show both wave-like and particle-like properties.

<p>True (A)</p> Signup and view all the answers

Bohr's theory effectively explains the emission spectra of all elements in the periodic table.

<p>False (B)</p> Signup and view all the answers

An 's' orbital is said to have a dumbbell shape.

<p>False (B)</p> Signup and view all the answers

Heisenberg's Uncertainty Principle states that the speed and position of an electron can be measured simultaneously.

<p>False (B)</p> Signup and view all the answers

The number of sublevels in an energy level is equal to the value of n for that level.

<p>True (A)</p> Signup and view all the answers

Flashcards

Emission Spectrum

A spectrum consisting of specific, narrow colored lines of light, unique to each element.

Quantized Energy Levels

Electrons in an atom can only have specific, fixed amounts of energy.

Ground State

The lowest energy level an electron in an atom can occupy.

Energy Levels (Orbits)

Fixed paths that electrons travel around the nucleus in an atom.

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Quantum of Energy

The fixed amount of energy that an electron in an atom can possess.

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Bohr Model

A model of the atom that describes electrons orbiting the nucleus in fixed energy levels.

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Spectrometer

A device used to measure the wavelength of light in a spectrum.

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Flame Test

A method for identifying metals by observing the color of the flame they produce.

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Excited state of an atom

The state of an atom where electrons are in higher energy levels than in the ground state.

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Ground state of an atom

The state of an atom where electrons occupy the lowest available energy levels.

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Atomic Absorption Spectrum

Spectrum of light with certain wavelengths missing when light passes through a gaseous element.

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Atomic Absorption Spectrometry (AAS)

Technique that measures absorption of light by atoms in a sample.

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Energy level

Fixed energy value that an electron in an atom can have.

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Balmer series

Emissions of visible light due to electrons falling to the n=2 energy level

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Photon

A particle of light with a definite amount of energy.

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Barium Flame Test Color

The color observed in a flame test when barium salts are present is green.

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Thomson Plum Pudding Model

A model of the atom where a positively charged material with embedded negatively charged electrons is presented.

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Heisenberg Uncertainty Principle

It's impossible to simultaneously know the exact position and velocity of an electron.

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Millikan's Oil Drop Experiments

Experiments conducted to determine the magnitude of the electric charge carried by an electron.

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Electron Configuration of Iron

Electron distribution of an iron atom; 1s2 2s2 2p6 3s2 3p6 4s2 3d6

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Energy Sublevels

Subdivisions of a main energy level, consisting of one or more orbitals with the same energy.

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Atomic Orbital

A region in space within which there's a high probability of finding an electron.

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s orbital

A spherical-shaped orbital.

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p orbital

A dumbbell-shaped orbital.

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Wave-Particle Duality

The concept that electrons behave like both waves and particles.

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Bohr's model limitations

Bohr's model works well for hydrogen but fails to explain emission spectra of atoms with more than one electron, doesn't consider wave motion and sublevels.

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Light absorption & concentration

The amount of light absorbed is directly proportional to the concentration of the substance in the sample.

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Study Notes

Arrangement of Electrons in the Atom

  • Bohr, a Danish scientist, explained electron arrangement in atoms.
  • White light, passed through a prism, separates into a continuous spectrum (rainbow).
  • Bohr used a hydrogen gas discharge tube and a prism to create an emission spectrum, consisting of narrow coloured lines.

Hydrogen Spectrum

  • Emission spectra are crucial in identifying elements.
  • Each element has a unique emission spectrum.
  • A spectrometer measures the wavelength of spectral lines.
  • A spectroscope displays but does not measure wavelengths.

Mandatory Experiment

  • Flame tests identify metals.
  • Using a damp wooden splint and a Bunsen burner, salts are used in flame tests.
  • The colour of the flame indicates the metal present.
  • Metals and their corresponding flame colours are: lithium - crimson, potassium - lilac, barium - green, strontium - red, copper - blue-green, and sodium - yellow.

The Bohr Theory

  • Electrons orbit the nucleus in fixed energy levels (orbits).
  • Energy levels are represented by 'n' (lowest is n=1).
  • Electrons do not gain or lose energy while in a fixed energy level.
  • The ground state is the lowest energy level occupied by electrons.
  • Excited state occurs when electrons absorb energy and jump to higher levels.
  • Energy absorbed matches the difference between the ground and excited state energy.
  • Electrons return to lower levels, emitting light of specific frequencies.
  • Frequency differences correlate with specific coloured lines in the spectrum.

Atomic Absorption Spectrometry (AAS)

  • Atoms absorb light at specific wavelengths.
  • The absorbed wavelengths match emission wavelengths.
  • AAS measures the absorption spectrum, identifying elements.
  • Used in various applications like water or blood sample analysis.
  • The amount of absorbed light directly correlates with element concentration.

Energy Sublevels

  • Each energy level (except n=1) divides into sublevels.
  • Sublevels contain orbitals of similar energy.
  • Each level has the same number of sublevels denoted by n.
  • The number of sublevels increases with increasing energy levels (n = 1 has one sublevel, n = 2 has two, and so on).

Wave Nature of the Electron

  • Electrons exhibit wave-particle duality, meaning they have wave-like properties.
  • Louis de Broglie suggested that particles move as waves.
  • Heisenberg's uncertainty principle states that simultaneous precise measurement of electron velocity and position is impossible.
  • Bohr's theory doesn't fully account for the behaviour of complex atoms with more than one electron.
  • Bohr's theory does not explain wave motion of electrons, splitting of lines, lack of specificity .

Atomic Orbitals

  • Orbitals are regions in space where an electron is likely to be found.
  • s orbitals are spherical, p orbitals have dumbbell shapes.
  • Different sublevels (s, p, d, f) hold different numbers of electrons.
  • Atomic orbitals relate to the arrangement of electrons.

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Description

Explore the fascinating world of electron arrangements in atoms with this quiz. Delve into the Bohr model, emission spectra, and the methods used to identify elements through flame tests. Test your understanding of the unique properties of elements as showcased by their emission spectra.

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