Aromatic L1

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Questions and Answers

What term best describes the structure of benzene?

  • Resonance hybrid (correct)
  • Aliphatic compound
  • Linear molecule
  • Aromatic isomer

Why is benzene often represented with alternating double bonds in structural formulas?

  • To indicate the presence of lone pairs
  • To emphasize its reactivity
  • To simplify electron counting (correct)
  • To show its linear structure

What is the enthalpy change for the reduction of benzene to cyclohexatriene?

  • -152 kJ/mol
  • -231 kJ/mol
  • -208 kJ/mol (correct)
  • -120 kJ/mol

Which type of reaction does benzene usually prefer over addition reactions?

<p>Substitution (B)</p> Signup and view all the answers

What is essential for aromaticity, according to the information provided?

<p>Cyclic conjugated systems (D)</p> Signup and view all the answers

In the context of benzene stability, what do unusual reactivity and preference for substitution suggest?

<p>High thermal stability (A)</p> Signup and view all the answers

What did Kekulé propose as the structure of benzene?

<p>Cyclohexatriene (C)</p> Signup and view all the answers

Why did Kekulé's earlier theory break when applied to benzene?

<p>Carbon lacked a 4th valence (C)</p> Signup and view all the answers

Why did Kekulé suggest that benzene was in rapid equilibrium between two isomers?

<p>To explain the missing isomer of dibromo benzene (D)</p> Signup and view all the answers

Which type of reaction does benzene undergo due to the stable nature of its resonance hybrid?

<p>Substitution reactions (B)</p> Signup and view all the answers

Why does benzene not react like a typical alkene despite having double bonds in its structure?

<p>Presence of resonance stabilization (D)</p> Signup and view all the answers

How does the presence of delocalized electrons in benzene contribute to its stability?

<p>Enhances its resonance energy (D)</p> Signup and view all the answers

Which technique showed that benzene has a symmetric hexagonal structure?

<p>X-ray diffraction (A)</p> Signup and view all the answers

What is the approximate C-C bond length in benzene?

<p>1.44 Ã… (C)</p> Signup and view all the answers

Why are chemical resonance hybrids only available for compounds with delocalized electrons?

<p>Delocalized electrons allow for free electron movement (D)</p> Signup and view all the answers

What effect does the freedom of electron movement have on the stability of a molecule?

<p>Increases stability (D)</p> Signup and view all the answers

In a resonance hybrid, which part of the molecule can participate in electron movement?

<p>$\pi$-bonds and lone pairs (B)</p> Signup and view all the answers

What must stay constant in a molecule's resonance hybrid?

<p>Number of electrons (C)</p> Signup and view all the answers

What is the main reason why aromatic compounds are so common in drugs and other applications?

<p>Their ability to form multiple resonance hybrids (D)</p> Signup and view all the answers

Which of the following drugs is NOT classified as an aromatic compound based on the information provided?

<p>Tamoxifen (D)</p> Signup and view all the answers

Based on the lecture, how many out of 100 drugs discussed are aromatic compounds?

<p>86 (D)</p> Signup and view all the answers

What role do delocalized electrons play in the stability of aromatic compounds?

<p>They contribute to resonance stabilization, increasing stability (B)</p> Signup and view all the answers

How do aromatic compounds differ from aliphatic compounds in terms of electron movement?

<p>Aromatic compounds demonstrate delocalized electron movement (C)</p> Signup and view all the answers

What aspect of aromatic compounds makes them suitable for applications like medicines and dyes?

<p>Their diverse electron delocalization that enhances stability (A)</p> Signup and view all the answers

What was the name given to the new compound isolated by Faraday from illuminating gas in 1825?

<p>Benzin (B)</p> Signup and view all the answers

How many degrees of unsaturation or ring systems does the molecular formula C6H6 indicate?

<p>4 (C)</p> Signup and view all the answers

Who established the molecular formula of benzene (C6H6) based on vapor density?

<p>Mitscherlich (C)</p> Signup and view all the answers

What describes benzene's properties in terms of Resonance Stabilization?

<p>Resonance of pi electrons over all six carbon atoms (C)</p> Signup and view all the answers

How does the chemistry of benzene compare to other 'unsaturated' compounds?

<p>Benzene shows unique stability due to resonance hybridization (D)</p> Signup and view all the answers

What term best describes the structure of benzene in relation to electron movement?

<p>Electron mobility across the ring (A)</p> Signup and view all the answers

Explain the reactivity of benzene towards bromine.

<p>Benzene can be brominated using FeBr3 as a catalyst, leading to substitution reactions.</p> Signup and view all the answers

What was Kekulé's proposal to explain the reactivity of benzene?

<p>Kekulé proposed that benzene exists as two isomers in rapid equilibrium.</p> Signup and view all the answers

Why did Kekulé's earlier theory break when applied to benzene?

<p>Kekulé's earlier theory broke because carbon in benzene needed a 4th valence, contradicting his own theory from 1859.</p> Signup and view all the answers

How does benzene's reactivity differ from that of alkenes?

<p>Benzene does not react like alkenes because it prefers substitution reactions over addition reactions.</p> Signup and view all the answers

What did Kekulé propose to explain the preference for substitution over addition in benzene?

<p>Kekulé suggested that benzene exists as two isomers in rapid equilibrium, accounting for the preference for substitution.</p> Signup and view all the answers

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