Analytical Chemistry Techniques Quiz
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Questions and Answers

What is the relationship between particle size of precipitates and relative supersaturation?

  • Particle size is directly proportional to relative supersaturation
  • Particle size remains constant regardless of relative supersaturation
  • Particle size is not affected by relative supersaturation
  • Particle size is inversely proportional to relative supersaturation (correct)

How can large crystals be obtained through precipitation?

  • Increase the rate of nucleation
  • Use a higher degree of supersaturation
  • Maximize contamination
  • Minimize the degree of supersaturation (correct)

What is the formula for relative supersaturation?

  • (Q + S)/S (Q = Concentration of mixed reagents before precipitation, S = solubility of the precipitate at equilibrium)
  • (S + Q)/S (Q = Concentration of mixed reagents before precipitation, S = solubility of the precipitate at equilibrium)
  • (S − Q)/S (Q = Concentration of mixed reagents before precipitation, S = solubility of the precipitate at equilibrium)
  • (Q − S)/S (Q = Concentration of mixed reagents before precipitation, S = solubility of the precipitate at equilibrium) (correct)

What should be done to obtain large crystals when precipitating from a dilute solution?

<p>Keep Q low and add precipitating reagent (B)</p> Signup and view all the answers

How does high relative supersaturation affect crystal formation?

<p>Results in many small crystals with high surface area (A)</p> Signup and view all the answers

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