Allotropy and Polymorphism

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Questions and Answers

Which of the following statements is true about allotropic substances?

  • They have the same melting point
  • They have different stabilities (correct)
  • They have the same crystalline form
  • They have the same solubility

What is the term used to describe the conversion of a metastable form to a stable form of a polymorph?

  • Allotropy
  • Spontaneous conversion (correct)
  • Crystallization
  • Supersaturation

Which of the following is NOT a characteristic of polymorphs?

  • Different solubilities
  • Different x-ray crystal and diffraction patterns
  • Different covalent bond geometries (correct)
  • Different melting points

Which of the following variables may affect the formation of polymorphs?

<p>Crystallization process (B)</p>
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What is the most common example of polymorphism?

<p>Diamond and graphite (C)</p>
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Which of the following is NOT a characteristic of polymorphs?

<p>Different melting points (D)</p>
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What is the term used to describe the existence of more than one crystalline form of an elemental substance?

<p>Allotropy (B)</p>
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Which of the following variables does NOT affect the formation of polymorphs?

<p>Geometry of the covalent bonds (A)</p>
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Which of the following statements is true about allotropic substances?

<p>They have the same stabilities (C)</p>
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What is the most common example of polymorphism mentioned in the text?

<p>Diamond and graphite (B)</p>
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Flashcards

What is allotropy?

The existence of more than one crystalline form of an elemental substance.

What are allotropic substances?

Substances of the same element with different structural forms; display different stabilities.

What is spontaneous conversion?

The changing of a metastable polymorph to a stable one without external influence.

What is polymorphism?

The ability of a solid material to exist in more than one crystal structure.

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What affects polymorph formation?

Crystallization processes, temperature, pressure, solvent effects and presence of impurities.

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Diamond and Graphite

Two common carbon polymorphs with strikingly different properties.

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