Air Pollution

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Questions and Answers

How does a thermal inversion primarily contribute to air pollution?

  • By increasing the density of the air, which dilutes pollutants.
  • By creating strong winds that carry pollutants away from urban areas.
  • By trapping cooler air beneath warmer air, preventing the dispersion of pollutants. (correct)
  • By facilitating rapid mixing and convection of air masses.

Which of the following best describes the role of nitrogen oxides (NOx) in air pollution?

  • They include nitric oxide and nitrogen dioxide and contribute to tropospheric ozone formation. (correct)
  • They only contribute to the greenhouse effect.
  • They solely deplete stratospheric ozone.
  • They are inert gases with no significant impact on air quality.

What is the primary difference between a primary and secondary air pollutant?

  • Primary pollutants are directly emitted from a source, while secondary pollutants form from reactions involving primary pollutants. (correct)
  • Primary pollutants are easier to control than secondary pollutants.
  • Primary pollutants are more harmful to human health than secondary pollutants.
  • Primary pollutants are only created indoors, while secondary pollutants are only created outdoors.

Which of the following pollutants is most directly associated with the formation of acid rain?

<p>Sulfur dioxide (SO₂). (B)</p> Signup and view all the answers

Why is ground-level ozone considered an air pollutant, while stratospheric ozone is not?

<p>Stratospheric ozone resides in the upper atmosphere and shields the Earth from harmful UV radiation, while ground-level ozone is an irritant and contributes to smog. (C)</p> Signup and view all the answers

Which of the following is a key reaction involved in the formation of tropospheric ozone and photochemical smog?

<p>$NO + O_2 \rightarrow NO_2$. (B)</p> Signup and view all the answers

What is the main purpose of a catalytic converter in a car's exhaust system?

<p>To convert harmful pollutants like carbon monoxide, hydrocarbons, and nitrogen oxides into less harmful substances. (A)</p> Signup and view all the answers

Which air pollutant is primarily associated with the risk of cardiovascular disease and lung cancer from cigarette smoke?

<p>Particulates. (B)</p> Signup and view all the answers

How does adopting clean coal technology help reduce air pollution?

<p>By minimizing the release of pollutants like sulfur dioxide, mercury, and particulate matter during coal combustion. (D)</p> Signup and view all the answers

What is the primary source of carbon monoxide (CO) as an indoor air pollutant?

<p>Burning without sufficient oxygen. (C)</p> Signup and view all the answers

Which of the following is a common strategy for mitigating photochemical smog caused by vehicles?

<p>Promoting the use of public transportation and hybrid/electric cars. (C)</p> Signup and view all the answers

What is a wet scrubber primarily designed to remove from industrial emissions?

<p>Sulfur dioxide. (B)</p> Signup and view all the answers

Why are volatile organic compounds (VOCs) considered indoor air pollutants?

<p>They can be emitted from furniture, building materials, and cleaning products and can have adverse health effects. (B)</p> Signup and view all the answers

Which primary pollutant is discharged from coal burning and exists in the form of $CH_3Hg$?

<p>Mercury. (B)</p> Signup and view all the answers

The Clean Air Act of 1973 established National Ambient Air Quality Standards (NAAQS) for six criteria air pollutants. Which of the following is NOT one of those pollutants?

<p>Methane (D)</p> Signup and view all the answers

What is the role of UV radiation in the formation of tropospheric ozone?

<p>UV radiation breaks down nitrogen dioxide ($NO_2$) into nitric oxide ($NO$) and atomic oxygen ($O$), which then combines with oxygen to form ozone. (C)</p> Signup and view all the answers

Which of the following best describes the function of an electrostatic precipitator?

<p>It uses an electrical charge to remove particulate matter from exhaust gases. (D)</p> Signup and view all the answers

Radon-222 is a decay product from which element?

<p>Uranium-238 (D)</p> Signup and view all the answers

Which strategy primarily focuses on reducing industrial smog caused by coal power plants?

<p>Adopting clean coal technology. (B)</p> Signup and view all the answers

Why is indoor air pollution often more severe in rural areas?

<p>Rural areas typically have older buildings with poor ventilation and rely on indoor burning for heating and cooking. (A)</p> Signup and view all the answers

Flashcards

What is a primary pollutant?

Pollutants discharged directly into the troposphere.

What is a secondary pollutant?

Pollutants formed from reactions between primary pollutants and other chemicals in the atmosphere.

What is thermal inversion?

Lack of mixing/convection due to a density difference where warm, lower density air is positioned above cooler air.

What are Nitrogen oxides (NOx)?

A group including nitric oxide (NO) and nitrogen dioxide (NO₂).

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What is Carbon Monoxide (CO)?

Colorless and odorless gas formed by incomplete combustion of fuels; highly toxic.

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What is Nitric Oxide (NO)?

A colorless and odorless gas, but a precursor to tropospheric ozone.

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What is Nitrogen Dioxide (NO₂)?

A brown-colored gas and a precursor to tropospheric ozone.

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What is Particulate Matter (PM)?

Small solid or liquid particles suspended in the air, classified as PM2.5 and PM10.

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What is Mercury (Hg)?

Chemicals discharged from coal burning, existing in the form of CH₃Hg⁺.

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What is Lead (Pb)?

Formerly a major pollutant from gasoline combustion.

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What is the formation of tropospheric ozone (O₃)?

NO + O₂ → NO₂; NO₂ + UV → NO + O; O + O₂ → O₃

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What is the formation of Sulfuric Acid (H₂SO₄)?

SO₂ + O₂ → SO₃; SO₃ + H₂O → H₂SO₄

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What is the formation of nitric acid (HNO₃)?

NO₂ + H₂O → HNO₃

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What is an electrostatic precipitator?

Uses electrostatic forces to remove particulate matter from exhaust gases.

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What is a wet scrubber?

Uses a liquid spray to remove pollutants from a gas stream.

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What is a three-way catalytic converter?

Converts harmful gases (HC, CO, NOx) into less harmful ones (N₂, H₂O, CO₂).

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What did the 1973 National Ambient Air Quality Standards (NAAQS) set?

Standards set for 6 criteria air pollutants: CO, NO₂, SO₂, particulates, Ozone, and Lead.

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What is Carbon Dioxide (CO₂)?

Colorless, odorless, usually from cooking.

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What can Cigarette smoke cause?

Causes lung cancer, cardiovascular disease, unpleasant smell.

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What are Volatile Organic Compounds (VOCs)?

Including methane, benzene, formaldehyde.

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Study Notes

  • The topic is air pollution

Air Pollution Key Facts

  • Indoor air pollution is more severe and deadly than outdoor pollution.
  • Indoor air pollution is more prevalent in rural areas due to indoor burning.
  • Modern buildings can also have indoor air pollution.

Primary vs. Secondary Pollutants

  • Primary pollutants are directly discharged into the troposphere, examples are CO2, NO, and SO2.
  • Secondary pollutants form from reactions between primary pollutants and other chemicals, for example, SO3 becomes H2SO4.

Thermal Inversion

  • Thermal inversion is a lack of mixing or convection caused by density differences.
  • Warm, lower density air is positioned on top.

Nitrogen Oxide (NOx)

  • Nitrogen oxide includes nitric oxide (NO) and nitrogen dioxide (NO2).

Ozone

  • Stratospheric ozone is beneficial and blocks harmful UVA and UVB rays from the sun.
  • Tropospheric ozone is harmful and considered an irritant.

Primary Outdoor Air Pollutants From Fossil Fuels

  • Carbon dioxide (CO2) is colorless and odorless.
  • Carbon monoxide (CO) is highly toxic, colorless, and odorless.
  • Nitric oxide (NO) is colorless, odorless and a precursor to tropospheric ozone.
  • Nitrogen dioxide (NO2) appears as a brown fume.
  • Sulfur dioxide (SO2) is a precursor to sulfuric acid and acid rain.
  • Particulate matter (PM) has two major classes: PM2.5 and PM10 which are fine particles.
  • Aerosols are chemically similar to PM in size and include ammonium nitrate (NH4NO3).
  • Mercury (Hg) is discharged from coal burning and exists in the form of CH3Hg.
  • Lead (Pb) was formerly a major pollutant from gasoline combustion.

Key Reactions

  • Formation of Tropospheric Ozone (O₃) & Photochemical Smog:
    • NO + O2 → NO2
    • NO2 + UV → NO + O
    • O + O2 → O3
  • Formation of Sulfuric Acid (H₂SO₄):
    • SO2 + O2 → SO3
    • SO3 + H2O → H2SO4
  • Formation of Nitric Acid (HNO3):
    • NO2 + H2O → HNO3

Primary Indoor Air Pollutants

  • Carbon dioxide (CO2) is colorless and odorless, typically from cooking.
  • Carbon monoxide (CO) is highly toxic and forms when burning without sufficient oxygen.
  • Formaldehyde has a "new" smell and comes from furniture.
  • Radon-222 is a decay product from uranium-238.
  • Asbestos was formerly used for insulation and fire prevention.
    • It consists of fine and abrasive particles.
  • Particulates include dust, pollens, and mites.
  • Cigarette smoke causes lung cancer, cardiovascular disease, and has an unpleasant smell.
  • Volatile Organic Compounds (VOCs) include methane, benzene, and formaldehyde.

Solutions for Photochemical Smog by Vehicles

  • Use public transportation.
  • Drive hybrid or electric cars.
  • Bike, walk, or carpool.
  • Drive more fuel-efficient cars.

Solutions for Industrial Smog by Coal Power Plants

  • Use renewable energy.
  • Adopt clean coal technology.
  • Use more efficient appliances.

Clean Coal Technology

  • Electrostatic precipitators and wet scrubbers are examples of clean coal technology.

Clean Air Acts

  • 1973: National Ambient Air Quality Standards (NAAQS) set standards for 6 criteria air pollutants: CO, NO2, SO2, particulates, ozone, and lead.
  • 1990: Established SO2 cap and trade program.

Hazardous Air Pollutants

  • HAP stands for hazardous air pollutant.
  • The EPA enlists 187 total HAPs.

Cleaner Car Exhaust: Catalytic Converter

  • Three-way catalysts help to clean car exhaust.
  • This removes CO and hydrocarbons.

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