Air Pollution and Greenhouse Gases

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Questions and Answers

What is the result of the reaction between CaO and SO2?

  • Calcium sulfite (correct)
  • Calcium oxide
  • Calcium sulfide
  • Calcium sulfate

Which gas binds more strongly to hemoglobin than oxygen?

  • Nitrogen oxides
  • Carbon monoxide (correct)
  • Carbon dioxide
  • Methane

Which of the following is a primary source of nitrogen oxide emissions?

  • Industrial factories
  • Cars and buses (correct)
  • Agricultural activities
  • Natural gas plants

What phenomenon is caused by the interaction of sunlight, nitrogen oxides, and volatile organic compounds?

<p>Photochemical smog (A)</p> Signup and view all the answers

What is the average surface temperature of the Earth without atmospheric gases?

<p>254 K (D)</p> Signup and view all the answers

Which of the following gases is NOT considered a greenhouse gas?

<p>Nitrogen (D)</p> Signup and view all the answers

What is the role of greenhouse gases in the atmosphere?

<p>To trap infrared radiation (B)</p> Signup and view all the answers

What form of carbon monoxide exposure can lead to dangerous health effects?

<p>Significant amounts of CO exposure (A)</p> Signup and view all the answers

What is the primary contributor to the greenhouse effect mentioned in the content?

<p>Water vapor (D)</p> Signup and view all the answers

Which gas, when produced from the combustion of gasoline, contributes the most to carbon dioxide emissions?

<p>2 kg of CO2 (C)</p> Signup and view all the answers

Which of the following gases has a global warming potential more than 14,000 times that of CO2?

<p>HCF3 (C)</p> Signup and view all the answers

Where is methane primarily formed in the environment?

<p>In swamps and landfills (D)</p> Signup and view all the answers

What is the minimum dissolved oxygen requirement for cold-water fish?

<p>5 ppm (D)</p> Signup and view all the answers

What human activity is highlighted as detrimental to aquatic life?

<p>Waste disposal without treatment (C)</p> Signup and view all the answers

Which of the following statements accurately describes aerobic bacteria?

<p>They consume dissolved oxygen to oxidize organic materials. (D)</p> Signup and view all the answers

Which factor contributes to seasonal variations in CO2 concentration?

<p>Plant growth and decay cycles (C)</p> Signup and view all the answers

What are the primary components that make up fertile topsoil?

<p>Mineral particles, water, air, and organic matter (D)</p> Signup and view all the answers

What is ammonium nitrate classified as?

<p>Straight fertilizer (D)</p> Signup and view all the answers

Which category of fertilizer includes a mixture of nitrogen, phosphorus, and potassium?

<p>Complete fertilizer (D)</p> Signup and view all the answers

Which type of pesticide primarily targets insects?

<p>Insecticide (A)</p> Signup and view all the answers

What is a key characteristic of chlorinated hydrocarbons as insecticides?

<p>They have a long-lasting effect (B)</p> Signup and view all the answers

Organophosphorus compounds and carbamates break down more readily than chlorinated hydrocarbons due to their?

<p>High solubility in water (C)</p> Signup and view all the answers

Which pesticide is an example of a chlorinated hydrocarbon?

<p>DDT (C)</p> Signup and view all the answers

Farmers often amend soil with fertilizers to address the loss of what?

<p>Plant nutrients (D)</p> Signup and view all the answers

What is a significant safety concern related to the use of organophosphates and carbamates?

<p>They are toxic to honeybees. (C)</p> Signup and view all the answers

Which of the following is a selective herbicide that mimics plant growth hormones?

<p>2,4-D (B)</p> Signup and view all the answers

What is the primary method traditionally used to control weeds in crop fields?

<p>Plowing under soil (A)</p> Signup and view all the answers

Which herbicide is known to cause lung damage if residues enter illicit drug products?

<p>Paraquat (B)</p> Signup and view all the answers

What type of crops can rapidly detoxify atrazine through metabolism?

<p>Grass-like crops (D)</p> Signup and view all the answers

What is the role of fungi in agricultural settings?

<p>They can spoil stored food and harm crops. (B)</p> Signup and view all the answers

Which of the following herbicides is classified as nonselective?

<p>Glyphosate (B)</p> Signup and view all the answers

Which of the following best describes the function of thiram?

<p>Fungicide (D)</p> Signup and view all the answers

What is one of the main benefits of using toluene and methanol in the production of styrene?

<p>They have a lower energy requirement in the reaction. (C)</p> Signup and view all the answers

Which of the following is a characteristic of supercritical fluids?

<p>They possess properties of both gas and liquid. (C)</p> Signup and view all the answers

Why are volatile organic compounds a concern in chemical processes?

<p>They can decompose and create toxic waste products. (D)</p> Signup and view all the answers

What are the two most popular choices for supercritical fluid solvents?

<p>Water and carbon dioxide. (D)</p> Signup and view all the answers

What hazardous characteristic is associated with benzene?

<p>It is a known carcinogen. (D)</p> Signup and view all the answers

In the production of terephthalic acid, what role does acetic acid serve?

<p>It is the solvent in the oxidation reaction. (C)</p> Signup and view all the answers

What is a significant advantage of the one-step process for producing styrene compared to the traditional two-step process?

<p>It reduces the overall number of chemical reactions. (A)</p> Signup and view all the answers

What reaction does para-xylene undergo to produce terephthalic acid?

<p>Oxidation. (C)</p> Signup and view all the answers

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Study Notes

Air Pollution and Greenhouse Gases

  • CaO reacts with SO2 to form calcium sulfite which can be used to remove SO2 from combusted fuel.
  • Carbon monoxide is produced by incomplete combustion of carbon-containing materials.
  • CO binds to hemoglobin 200x stronger than O2, leading to reduced oxygen levels in blood.
  • Nitrogen oxides are a primary component of smog, mostly emitted by vehicles.
  • Photochemical smog is formed by the reaction of sunlight, nitrogen oxides, and volatile organic compounds, producing particulate matter and ground-level ozone.
  • Greenhouse gases trap infrared radiation.
  • Without greenhouse gases, the Earth's surface temperature would be 254K.
  • Water vapor and carbon dioxide are major greenhouse gases.
  • Increased CO2 levels in the atmosphere can lead to an unnatural increase in global temperatures.
  • Other greenhouse gases include: methane, hydrofluorocarbons (HFCs), and chlorofluorocarbons (CFCs).
  • Methane forms in low-oxygen environments and is produced by anaerobic bacteria.

Water Quality and Human Activities

  • All life on Earth depends on access to suitable water.
  • Untreated waste disposal into natural waters can contaminate water and harm aquatic life.
  • Dissolved oxygen levels are an important indicator of water quality.
  • Cold-water fish require at least 5 ppm oxygen.
  • Aerobic bacteria consume dissolved oxygen to oxidize organic materials.

Soil and Agriculture

  • Fertile topsoil is composed of mineral particles, water, air, and organic matter.
  • Fertilizers replace lost nutrients in soil.
  • Straight fertilizers contain only one nutrient, for example, ammonium nitrate (NH4NO3) contains nitrogen.
  • Complete fertilizers contain a mix of nitrogen, phosphorus, and potassium.
  • High-yield crops require adequate nutrition and protection from pests.

Pesticides

  • Pesticides are used to control pests, including insects, weeds, and fungi.
  • Insecticides include chlorinated hydrocarbons, organophosphorus compounds, and carbamates.
  • Chlorinated hydrocarbons are persistent and nonbiodegradable.
  • Organophosphorus compounds and carbamates readily decompose into water-soluble components.
  • Malathion is an organophosphorus compound, and carbaryl is a carbamate.
  • Herbicides control weeds.
  • 2,4-D and 2,4,5-T are selective herbicides that kill broad-leafed plants.
  • Atrazine is toxic to weeds but not to many grass-like crops.
  • Paraquat kills weeds in their sprouting phase.
  • Glyphosate is a nonselective herbicide.
  • Fungicides control fungi.
  • Thiram is a fungicide widely used on fruits and vegetables.

Safer Chemistry Practices

  • Reagents and solvents in chemical processes should be chosen to minimize potential accidents.
  • Styrene is a building block for polymers and is produced in a two-step process currently, but a one-step process using toluene and methanol is more cost-effective and environmentally friendly.
  • Supercritical fluids can replace conventional solvents.
  • Supercritical CO2 is used in the production of Teflon and is replacing chlorofluorocarbons.
  • Para-xylene is oxidized to produce terephthalic acid, used in PET plastic and polyester fibers.
  • The oxidation process uses oxygen as an oxidizing agent and acetic acid as a solvent.

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