Advantages of Nanoporous Materials Quiz

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Questions and Answers

What is the main limitation of creating nanoporous materials using the bottom-up approach?

  • Dependent on the use of autoclaves
  • Require high temperatures above 200 °C
  • Limited to pores/channels open at both ends
  • Restricted to pores/channels open at one end (correct)

In nanoporous materials synthesis, what does SDA stand for?

  • Silane Dissolution Agent
  • Surface Deposition Agent
  • Silica Directing Agent
  • Structural Directing Agent (correct)

What is the pore size range typically achieved through molecular templating in nanoporous materials?

  • 1-10 Ã…ngstroms (correct)
  • 10-20 Ã…ngstroms
  • 30-40 Ã…ngstroms
  • 20-30 Ã…ngstroms

Which method can be used to measure the pore size and volume of nanoporous materials?

<p>Gas adsorption using BET isotherm (B)</p> Signup and view all the answers

What is specific surface area (SSA) a measure of in nanoporous materials?

<p>The total surface area of a material per unit mass (A)</p> Signup and view all the answers

How can the pore size distribution and pore structure of nanoporous materials be observed?

<p>By gas adsorption using BET isotherm (D)</p> Signup and view all the answers

Which type of adsorption is characterized by the formation of a monolayer?

<p>Type I (C)</p> Signup and view all the answers

At what temperature is the N2 saturation pressure approximately 757.30 mmHg?

<p>77.3 K (A)</p> Signup and view all the answers

Based on the BET equation, what does the slope of the plot of P/W versus P represent?

<p>Weight of monolayer nitrogen adsorbed (C)</p> Signup and view all the answers

In which type of isotherm is the limiting uptake governed by the accessible micropore volume?

<p>Type III (C)</p> Signup and view all the answers

In the BET equation, what does 'C' represent?

<p>Cross-section area (B)</p> Signup and view all the answers

What is the appropriate linear range of P/P0 in the BET equation dependent on?

<p>Materials being tested (B)</p> Signup and view all the answers

What does the inflection point in Type I isotherm indicate?

<p>Both a and b (C)</p> Signup and view all the answers

In Type II isotherm, what occurs when adsorption is approaching a limit quantity?

<p>Multilayer adsorption begins (A)</p> Signup and view all the answers

What is the formula for the sample surface area (St) according to the text?

<p>$2MRT$ (D)</p> Signup and view all the answers

What does Type III isotherm form before completing the monolayer?

<p>&lt; adsorbate-surface (D)</p> Signup and view all the answers

What is the intercept in the plot of P/W versus P indicative of in the BET equation?

<p>Condensation coefficient (B)</p> Signup and view all the answers

In a standard BET test, what does 'W' represent?

<p>Weight of nitrogen adsorbed at a given relative pressure (D)</p> Signup and view all the answers

What type of adsorption is represented by Type IV isotherms?

<p>Reversible adsorption/desorption (C)</p> Signup and view all the answers

What characterizes the intermediate flat region in Type IV isotherms?

<p>Monolayer formation (B)</p> Signup and view all the answers

Which type of isotherm exhibits a combination of characteristics from Type III and Type IV?

<p>Type V (B)</p> Signup and view all the answers

What did Langmuir assume in his description of the Type I isotherm?

<p>Adsorption limited to monolayer (A)</p> Signup and view all the answers

What does the Langmuir equation for Type I isotherms relate to?

<p>Weight of adsorbate in a completed monolayer (C)</p> Signup and view all the answers

What is the main result of Capillary condensation?

<p>Vapor condenses due to increased interactions inside capillaries (C)</p> Signup and view all the answers

What is a key advantage of nanoporous materials in terms of adsorption capacity?

<p>Large surface area (D)</p> Signup and view all the answers

Why do interconnected pore structures in nanoporous materials enable fast diffusion of guest species?

<p>Due to interconnected pore structures (D)</p> Signup and view all the answers

What makes nanoporous materials suitable for mixture separation or confined chemical reactions?

<p>High selectivity (D)</p> Signup and view all the answers

What is the main function of a metal organic framework (MOF) structure?

<p>Catalysis (A)</p> Signup and view all the answers

In a metal organic framework (MOF), what role does Metal Organic Frameworks (microporous structure) play?

<p>Secondary building unit (SBU) (C)</p> Signup and view all the answers

What allows MOF structures to be chemically tailored for different applications?

<p>Metal ion clusters (C)</p> Signup and view all the answers

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