CH 14: Activation energy
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Questions and Answers

What is the main difference between the potential energy diagrams of uncatalysed and catalysed endothermic reactions?

  • The uncatalysed reaction has a higher activation energy peak. (correct)
  • The uncatalysed reaction has a lower activation energy peak.
  • The catalysed reaction has a higher activation energy peak.
  • There is no difference in the activation energy peaks.

Which of the following statements about exothermic reactions is correct?

  • The energy level of the products is always higher than the energy level of the reactants in exothermic reactions.
  • Exothermic reactions release energy, so the energy level of the products is lower than the energy level of the reactants. (correct)
  • Catalysts do not affect the activation energy of exothermic reactions.
  • Exothermic reactions always have a higher activation energy peak than endothermic reactions.

What information can be determined from the difference in height between the reactants and products on the potential energy diagram?

  • The rate of the reaction.
  • The activation energy of the reaction.
  • The change in enthalpy (ΔH) of the reaction. (correct)
  • The presence of a catalyst.

What is the purpose of the peak point on the potential energy diagram?

<p>It represents the energy level of the activated complex. (B)</p> Signup and view all the answers

How does the presence of a catalyst affect the potential energy diagram of a reaction?

<p>The catalyst decreases the activation energy of the reaction. (B)</p> Signup and view all the answers

What does the area under the curve from reactants to the peak point on the potential energy diagram represent?

<p>The activation energy of the reaction. (D)</p> Signup and view all the answers

Which of the following statements about the potential energy diagrams of uncatalysed and catalysed reactions is correct?

<p>The uncatalysed and catalysed reactions have the same pathway on the diagram. (A)</p> Signup and view all the answers

What does the X-axis of the potential energy diagram represent?

<p>The progress of the reaction. (D)</p> Signup and view all the answers

Which of the following statements about the potential energy diagram of an endothermic reaction is incorrect?

<p>The area under the curve from reactants to the peak represents the change in enthalpy (ΔH). (D)</p> Signup and view all the answers

How does the presence of a catalyst affect the potential energy diagram of an exothermic reaction?

<p>The catalyst reduces the activation energy of the reaction. (B)</p> Signup and view all the answers

What type of reaction absorbs energy, with products having higher energy than reactants?

<p>Endothermic (D)</p> Signup and view all the answers

Which term defines the minimum energy required for reactants to form products during a chemical reaction?

<p>Activation energy (D)</p> Signup and view all the answers

What represents the unstable arrangement of atoms at the peak of the activation energy barrier?

<p>Activated complex (A)</p> Signup and view all the answers

In which reaction is energy released, with reactants having higher energy levels than the products?

<p>Exothermic (B)</p> Signup and view all the answers

What is the role of catalysts in chemical reactions?

<p>To decrease activation energy (C)</p> Signup and view all the answers

Which represents a specific momentary mixture of reactants and products during a reaction?

<p>Activated complex (D)</p> Signup and view all the answers

What is the significance of activation energy in determining the rate of a reaction?

<p>Lower activation energy leads to a faster reaction (C)</p> Signup and view all the answers

Which term describes the energy barrier that must be overcome for a chemical reaction to proceed?

<p>Activation energy (A)</p> Signup and view all the answers

In which type of reaction are reactants requiring external energy to convert into products?

<p>Endothermic (B)</p> Signup and view all the answers

What does the activated complex represent during a chemical reaction?

<p>An intermediate state at the peak of activation energy barrier (A)</p> Signup and view all the answers

What is the primary function of activation energy in a chemical reaction?

<p>To determine the rate of the reaction (D)</p> Signup and view all the answers

How does a higher activation energy affect the reaction rate under the same conditions?

<p>It decreases the reaction rate (C)</p> Signup and view all the answers

What does the activated complex represent in a chemical reaction?

<p>A midpoint where bonds are breaking and forming (B)</p> Signup and view all the answers

Which of the following statements about the activated complex is true?

<p>It has higher energy than the products (D)</p> Signup and view all the answers

What is the primary function of a positive catalyst in a chemical reaction?

<p>To lower the activation energy (C)</p> Signup and view all the answers

How do positive catalysts increase the rate of a chemical reaction?

<p>By allowing more reactant particles to reach the transition state (A)</p> Signup and view all the answers

What is the primary function of a negative catalyst (inhibitor) in a chemical reaction?

<p>To increase the activation energy (C)</p> Signup and view all the answers

Which of the following diagrams is used to represent activation energy in a chemical reaction?

<p>Potential energy diagrams (A)</p> Signup and view all the answers

What is the relationship between activation energy and the energy of the activated complex?

<p>The activation energy is higher than the energy of the activated complex (D)</p> Signup and view all the answers

Which of the following statements about catalysts is false?

<p>Catalysts are consumed during the reaction (A)</p> Signup and view all the answers

What does the area under the curve from reactants to the peak point on the potential energy diagram represent?

<p>The activation energy required for the reaction (C)</p> Signup and view all the answers

What is the primary function of activation energy in a chemical reaction?

<p>To determine the rate of the reaction (A)</p> Signup and view all the answers

How does the presence of a catalyst affect the potential energy diagram of an exothermic reaction?

<p>It decreases the activation energy and lowers the energy of the products (A)</p> Signup and view all the answers

What term defines the minimum energy required for reactants to form products during a chemical reaction?

<p>Activation energy (B)</p> Signup and view all the answers

Which of the following statements about the potential energy diagram of an endothermic reaction is incorrect?

<p>The potential energy of the products is lower than the potential energy of the reactants (B)</p> Signup and view all the answers

What represents the unstable arrangement of atoms at the peak of the activation energy barrier?

<p>The activated complex (B)</p> Signup and view all the answers

How does a higher activation energy affect the reaction rate under the same conditions?

<p>It decreases the reaction rate (D)</p> Signup and view all the answers

What is the primary function of a negative catalyst (inhibitor) in a chemical reaction?

<p>To increase the activation energy and slow down the reaction (A)</p> Signup and view all the answers

Which type of reaction absorbs energy, with products having higher energy than reactants?

<p>Endothermic reaction (A)</p> Signup and view all the answers

What is the main difference between the potential energy diagrams of uncatalyzed and catalyzed endothermic reactions?

<p>The activation energy is lower in the catalyzed reaction (B)</p> Signup and view all the answers

What role do positive catalysts (catalysts) play in a chemical reaction?

<p>Provide an alternative reaction pathway with lower activation energy (C)</p> Signup and view all the answers

Which term best describes the activated complex in a chemical reaction?

<p>Midpoint between reactants and products (D)</p> Signup and view all the answers

How does a higher activation energy affect the rate of a reaction under the same conditions?

<p>Slows down the reaction (D)</p> Signup and view all the answers

What is the primary function of negative catalysts (inhibitors) in a chemical reaction?

<p>Increase the activation energy (B)</p> Signup and view all the answers

What information can be inferred from the difference in height between reactants and products on a potential energy diagram?

<p>Activation energy value (B)</p> Signup and view all the answers

What characteristic differentiates activated complexes from reactants and products in a chemical reaction?

<p>Higher energy level (C)</p> Signup and view all the answers

In a chemical reaction, what is the primary effect of a negative catalyst (inhibitor) on the rate of reaction?

<p>Slows down the reaction (C)</p> Signup and view all the answers

What do potential energy diagrams show in terms of chemical reactions?

<p>$\Delta E$ values (B)</p> Signup and view all the answers

'Isolating the activated complex is challenging due to its:' ...?

<p>$\text{High energy level and instability}$ (B)</p> Signup and view all the answers

What is represented by the area under the curve from reactants to the peak point on a potential energy diagram?

<p>The activation energy barrier for the reaction (B)</p> Signup and view all the answers

In a potential energy diagram, what does the difference in height between the reactants and products represent?

<p>The enthalpy change ($\Delta H$) of the reaction (B)</p> Signup and view all the answers

What does the area under the curve from reactants to the peak point on the potential energy diagram represent?

<p>The activation energy of the reaction (D)</p> Signup and view all the answers

How does the presence of a catalyst affect the potential energy diagram of a reaction?

<p>It lowers the activation energy peak, but the start and end points remain the same (C)</p> Signup and view all the answers

What does the peak point on the potential energy diagram represent?

<p>The activated complex (D)</p> Signup and view all the answers

What is the primary function of activation energy in a chemical reaction?

<p>To provide the energy required for the reaction to occur (B)</p> Signup and view all the answers

How do positive catalysts increase the rate of a chemical reaction?

<p>By lowering the activation energy barrier (A)</p> Signup and view all the answers

What represents the unstable arrangement of atoms at the peak of the activation energy barrier?

<p>The activated complex (C)</p> Signup and view all the answers

Which term defines the minimum energy required for reactants to form products during a chemical reaction?

<p>Activation energy (B)</p> Signup and view all the answers

What is the role of catalysts in chemical reactions?

<p>To lower the activation energy barrier (A)</p> Signup and view all the answers

Which of the following statements about the potential energy diagrams of uncatalysed and catalysed reactions is correct?

<p>The catalysed reaction has a lower activation energy peak than the uncatalysed reaction (D)</p> Signup and view all the answers

What information can be determined from the difference in height between the reactants and products on the potential energy diagram?

<p>The change in enthalpy (ΔH) of the reaction (B)</p> Signup and view all the answers

Which of the following statements about the potential energy diagrams of uncatalysed and catalysed reactions is correct?

<p>The catalysed reaction has a lower activation energy peak than the uncatalysed reaction. (A)</p> Signup and view all the answers

What does the peak point on the potential energy diagram represent?

<p>The activated complex (B)</p> Signup and view all the answers

What is the primary function of a positive catalyst in a chemical reaction?

<p>To decrease the activation energy of the reaction (B)</p> Signup and view all the answers

What does the area under the curve from reactants to the peak point on the potential energy diagram represent?

<p>The activation energy of the reaction (D)</p> Signup and view all the answers

Which of the following statements about catalysts is false?

<p>Catalysts are consumed during the reaction and must be replenished. (C)</p> Signup and view all the answers

What is the main difference between the potential energy diagrams of uncatalysed and catalysed endothermic reactions?

<p>The catalysed reaction has a lower activation energy peak. (C)</p> Signup and view all the answers

What is the primary function of activation energy in a chemical reaction?

<p>To determine the rate of the reaction (B)</p> Signup and view all the answers

Which term best describes the activated complex in a chemical reaction?

<p>The transition state (B)</p> Signup and view all the answers

What does the X-axis of the potential energy diagram represent?

<p>The course of the reaction, from reactants to products (B)</p> Signup and view all the answers

What effect does a higher activation energy have on the rate of a reaction under the same conditions?

<p>Decreases the rate of reaction (A)</p> Signup and view all the answers

Which of the following characteristics best differentiates activated complexes from reactants and products?

<p>Exists momentarily (A)</p> Signup and view all the answers

What is the primary function of a positive catalyst in a chemical reaction?

<p>Lowers the activation energy (B)</p> Signup and view all the answers

Which term best describes the activated complex in a chemical reaction?

<p>Midpoint between reactants and products (D)</p> Signup and view all the answers

How do negative catalysts (inhibitors) affect a chemical reaction?

<p>Increase the activation energy (C)</p> Signup and view all the answers

What defines a positive catalyst (catalyst) in a chemical reaction?

<p>Lowers the activation energy (D)</p> Signup and view all the answers

In terms of chemical reactions, what does a negative catalyst (inhibitor) primarily do?

<p>Stops or slows down the reaction (D)</p> Signup and view all the answers

What is represented by a higher activation energy in a chemical reaction?

<p>Slows down the reaction (A)</p> Signup and view all the answers

What happens to the rate of a reaction when a negative catalyst is introduced?

<p>Decreases (B)</p> Signup and view all the answers

What role does a positive catalyst play in relation to activation energy?

<p>Lowers activation energy (A)</p> Signup and view all the answers

What is the primary characteristic that distinguishes the activated complex from the reactants and products during a chemical reaction?

<p>It is a fleeting arrangement that quickly dissociates into products or reverts to reactants. (C)</p> Signup and view all the answers

In the context of potential energy diagrams, what does the area under the curve from reactants to the peak point represent?

<p>The activation energy required for the reaction to proceed. (C)</p> Signup and view all the answers

How do positive catalysts increase the rate of a chemical reaction?

<p>By lowering the activation energy of the reaction. (A)</p> Signup and view all the answers

Which statement about the role of negative catalysts (inhibitors) in a chemical reaction is correct?

<p>They increase the activation energy, thereby slowing down the reaction rate. (D)</p> Signup and view all the answers

Which statement best describes the potential energy diagrams of uncatalyzed and catalyzed reactions?

<p>The catalyzed reaction has a lower activation energy but the same enthalpy change. (C)</p> Signup and view all the answers

According to the law of conservation of energy in chemical reactions, what is the relationship between energy changes and enthalpy changes?

<p>Energy cannot be created or destroyed, and enthalpy changes account for energy transferred as heat or work. (B)</p> Signup and view all the answers

Which statement accurately describes the characteristic of the activated complex during a chemical reaction?

<p>It is a momentary arrangement that quickly dissociates into products or reverts to reactants. (B)</p> Signup and view all the answers

In the context of potential energy diagrams, what does the difference in height between the reactants and products represent?

<p>The enthalpy change $\Delta$H for the overall reaction. (C)</p> Signup and view all the answers

Which statement accurately describes the significance of activation energy in determining the rate of a chemical reaction?

<p>Lower activation energy results in a faster reaction rate under the same conditions. (A)</p> Signup and view all the answers

Which statement accurately describes the role of positive catalysts in chemical reactions?

<p>They lower the activation energy, thereby increasing the reaction rate. (C)</p> Signup and view all the answers

What feature on a potential energy diagram represents the highest point on the curve, symbolizing the activated complex?

<p>Peak point (B)</p> Signup and view all the answers

In a catalysed exothermic reaction, what is the primary effect on the activation energy peak?

<p>It decreases compared to the uncatalysed reaction (B)</p> Signup and view all the answers

What does the X-axis represent on a potential energy diagram?

<p>Course of the reaction (D)</p> Signup and view all the answers

How are activated complexes different from reactants and products in a chemical reaction?

<p>They have higher potential energy than reactants but lower than products (D)</p> Signup and view all the answers

What aspect of a potential energy diagram highlights the difference made by the presence of a catalyst in a reaction?

<p>Peak point (D)</p> Signup and view all the answers

In an exothermic reaction, what does it signify if the curve ends below the initial energy level of the reactants?

<p>The reaction is exothermic (C)</p> Signup and view all the answers

What does the difference in height between reactants and products represent on a potential energy diagram?

<p>Change in enthalpy of the reaction (D)</p> Signup and view all the answers

Which term best describes the activated complex in terms of its stability during a chemical reaction?

<p><strong>Metastable</strong> (B)</p> Signup and view all the answers

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