Acidic Properties of Solutions Chapter 2
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Questions and Answers

What is indicated by the glowing of a bulb in an acidic solution?

  • There is a flow of electric current through the solution. (correct)
  • The bulb is faulty.
  • The solution is not conducting electricity.
  • The solution is a base.
  • Which ion is common to all acids?

  • H+ (correct)
  • OH-
  • Cl-
  • Na+
  • In what type of solution will a bulb start to glow?

  • Glucose
  • Acid (correct)
  • Alcohol
  • Salt
  • What ions carry electric current through an acidic solution?

    <p>Ions (B)</p> Signup and view all the answers

    What is produced when acids are dissolved in solution that gives them their acidic properties?

    <p>Hydrogen ions (D)</p> Signup and view all the answers

    What is observed when dry HCl gas is tested with dry litmus paper?

    <p>There is no color change. (D)</p> Signup and view all the answers

    What is the name given to the H3O+ ion?

    <p>Hydronium ion (A)</p> Signup and view all the answers

    In what form do hydrogen ions exist in aqueous solutions?

    <p>H+(aq) (C)</p> Signup and view all the answers

    What is produced when a base such as NaOH is dissolved in water?

    <p>Na+(aq) and OH-(aq) (C)</p> Signup and view all the answers

    What is required for hydrogen ions to be produced from HCl molecules?

    <p>The presence of water (A)</p> Signup and view all the answers

    Why do glucose and alcohol solutions not conduct electricity, unlike acidic solutions?

    <p>They do not contain ions to carry the electric current. (A)</p> Signup and view all the answers

    What is the role of water in the production of ions from HCl?

    <p>Water facilitates the separation of $H^+$ ions from HCl molecules. (A)</p> Signup and view all the answers

    Which of the following is the correct representation of hydrogen ions in aqueous solution?

    <p>$H_3O^+$ (D)</p> Signup and view all the answers

    What does the experiment with solid NaCl and concentrated sulfuric acid demonstrate?

    <p>The need for water to produce hydrogen ions from HCl. (D)</p> Signup and view all the answers

    Why is it important to use a guard tube containing calcium chloride when preparing HCl gas in a humid climate?

    <p>To ensure the HCl gas is dry, as the presence of water affects the experiment. (B)</p> Signup and view all the answers

    Which of the following correctly describes what happens when NaOH is dissolved in water?

    <p>It produces sodium ions ($Na^+$) and hydroxide ions ($OH^-$). (D)</p> Signup and view all the answers

    Consider two test tubes, one containing dry HCl gas and the other containing an aqueous solution of HCl. Which one will turn blue litmus paper red?

    <p>Only the test tube containing the aqueous solution of HCl. (A)</p> Signup and view all the answers

    A student tests a solution with litmus paper and finds that it turns blue. Which of the following ions is most likely present in higher concentration in the solution?

    <p>$OH^-$ (C)</p> Signup and view all the answers

    Which of the following acids will produce $NO_3^-$ ions when dissolved in water?

    <p>$HNO_3$ (C)</p> Signup and view all the answers

    If a solution conducts electricity, what can you infer about its composition?

    <p>It contains ions that can move freely. (B)</p> Signup and view all the answers

    Consider a scenario where a student tests the conductivity of various solutions using a light bulb connected in a circuit. If the bulb glows brightly with solution A, dimly with solution B, and not at all with solution C, what can be inferred about the relative concentrations of ions in these solutions?

    <p>Solution A has the highest, solution B has a moderate, and solution C has the lowest concentration of ions. (D)</p> Signup and view all the answers

    A chemist prepares a solution of hydrochloric acid (HCl) in both distilled water and a non-polar solvent (like toluene). Which of the following statements accurately compares the ability of these two solutions to conduct electricity, and why?

    <p>The HCl solution in water conducts electricity, while the HCl solution in toluene does not because water facilitates the ionization of HCl into ions. (C)</p> Signup and view all the answers

    A researcher performs an experiment using dry hydrogen chloride (HCl) gas and methylbenzene (toluene). The researcher then bubbles the dry HCl gas into the methylbenzene. Upon testing this solution, it is found to be non-conducting. Which statement provides the best explanation for that result?

    <p>The absence of water prevents the ionisation of HCl. (B)</p> Signup and view all the answers

    A scientist introduces dry HCl gas into two separate beakers: one containing distilled water and the other containing anhydrous ethanol (absolute alcohol). After a few minutes, the scientist measures the conductivity of both solutions. What would be the expected outcome, and why?

    <p>The water solution will be conductive, while the ethanol solution will exhibit minimal conductivity because water facilitates the formation of hydronium ions. (D)</p> Signup and view all the answers

    A student dissolves sodium hydroxide (NaOH) in heavy water (D2O) instead of regular water (H2O). How would this change affect the resulting solution's properties, if at all?

    <p>The solution would contain deuteroxide ions (OD-) instead of hydroxide ions (OH-), but its basic properties would remain similar. (B)</p> Signup and view all the answers

    Consider a scenario where gaseous HCl is bubbled into a solution of strong base (e.g., NaOH). Initially, the solution readily absorbs the HCl, but after some time, the absorption rate decreases significantly, and the concentration of chloride ions plateaus. Which explanation best describes this observation?

    <p>The concentration of hydroxide ions in the solution has decreased significantly, slowing down the neutralization reaction. (C)</p> Signup and view all the answers

    A chemist is tasked with preparing a highly concentrated solution of hydronium ions ($H_3O^+$). Which of the following methods would be the MOST effective in achieving this?

    <p>Dissolving a strong acid, such as hydrochloric acid, in a minimal amount of water. (D)</p> Signup and view all the answers

    A researcher isolates a sample of pure hydronium ions ($H_3O^+$) at very low temperatures in the solid-state. Upon slowly warming the sample, what transformation is LEAST likely to occur?

    <p>Sublimation of $H_3O^+$ directly into the gaseous phase as stable $H_3O^+$ molecules. (A)</p> Signup and view all the answers

    Imagine an experiment where a student adds a small amount of hydrochloric acid ($HCl$) to a buffer solution. What would be the primary effect of this addition on the buffer system?

    <p>It would be neutralized by the basic component of the buffer, resulting in a minimal change in pH. (C)</p> Signup and view all the answers

    Consider a scenario where a concentrated solution of a strong monoprotic acid HX is diluted with water. As water is added, which of the following occurs?

    <p>The concentration of $H_3O^+$ ions decreases, and the pH increases. (A)</p> Signup and view all the answers

    Consider an electrochemical cell where the electrolyte consists of a mixture of $H_2SO_4$ and $D_2SO_4$ (deuterated sulfuric acid) in $H_2O$. Over time, electrolysis occurs, and gases are evolved at both electrodes. What differences would be observed in the isotopic composition of the gases evolved at the anode and the cathode, and why?

    <p>The gas evolved at the anode will be enriched in protium due to the faster oxidation kinetics of $OH^-$ compared to $OD^-$. The gas at the cathode will be enriched in deuterium due to the faster reduction kinetics of $D^+$ compared to $H^+$. (D)</p> Signup and view all the answers

    A chemist prepares a solution by dissolving $HCl$ gas in a mixture of $H_2O$ and $D_2O$. Given that the autoionization of water produces both $H_3O^+$ and $D_3O^+$ (as well as mixed isotopologues like $H_2DO^+$), which of the following equilibria is most significantly affected by the presence of differing water isotopologues, and how does this impact the overall acidity?

    <p>$D_2O + H_2O \rightleftharpoons 2HDO$ is the most significantly affected due to the entropic favorability of forming HDO, leading to a slight decrease in the effective concentration of $H_3O^+$ and a decrease in overall acidity. (C)</p> Signup and view all the answers

    A researcher is studying the behavior of $HCl$ in a non-aqueous solvent with a very low dielectric constant. They observe that while the $HCl$ dissolves, the solution remains non-conductive. Further analysis reveals the formation of complex aggregates of $HCl$ molecules. Which of the following best describes the predominant form of $HCl$ in this solution and the reason for the lack of conductivity?

    <p>Ion pairs $(H^+Cl^-)$ are formed but do not dissociate due to the low dielectric constant of the solvent, preventing ion mobility. (B)</p> Signup and view all the answers

    Imagine a scenario where $HCl$ gas is carefully introduced into a sealed chamber containing a mixture of finely powdered $Na_2CO_3$ and $CaCO_3$. Assuming the reaction proceeds to completion and that the evolved $CO_2$ is continuously removed to prevent back reactions, what would be the ultimate ratio of $CaCl_2$ to $NaCl$ in the resulting solid mixture?

    <p>The ratio would depend on the initial molar ratio of $Na_2CO_3$ to $CaCO_3$. If they were initially in a 1:1 molar ratio, the final ratio of $CaCl_2$ to $NaCl$ would be 1:2. (D)</p> Signup and view all the answers

    Consider a galvanic cell constructed with two half-cells: one with a platinum electrode immersed in an aqueous solution of $HCl$, and another with a silver electrode immersed in an aqueous solution of $AgCl$. What effect will progressively increasing the concentration of $HCl$ in the first half-cell have on the overall cell potential, and why?

    <p>The cell potential will decrease because increasing $HCl$ concentration will shift the equilibrium to favor the formation of solid $AgCl$, thus reducing the concentration of $Ag^+$ ions. (B)</p> Signup and view all the answers

    A researcher performs an experiment to determine the extent of ionization of $HCl$ in various solvents with different protic and aprotic character. In which of the following solvent categories would you expect $HCl$ to exhibit the lowest degree of ionization, and why?

    <p>Aprotic solvents with low dielectric constants, as they poorly solvate ions and hinder their separation. (A)</p> Signup and view all the answers

    Consider a scenario in which a small amount of $HCl$ gas is introduced into a closed system containing a mixture of $NH_3$ gas and water vapor at equilibrium. How will the equilibrium partial pressures of $NH_3$ and $H_2O$ be affected, and what new species will be formed in the gas phase?

    <p>The partial pressure of $NH_3$ will decrease due to its reaction with $HCl$ to form solid $NH_4Cl$. The partial pressure of $H_2O$ will remain relatively constant, assuming sufficient water vapor is present. (A)</p> Signup and view all the answers

    A graduate student attempts to synthesize a novel compound using $HCl$ as a catalyst in a reaction carried out in anhydrous diethyl ether. Despite rigorous drying of the solvent, the reaction is sluggish and yields are low. Mass spectrometry reveals the presence of protonated ether molecules ($Et_2OH^+$). What explains this observation, and what practical step could improve the reaction?

    <p>Trace amounts of water in the ether react with $HCl$ to form hydronium ions, which then protonate the ether. Adding a drying agent like molecular sieves would improve the reaction. (A)</p> Signup and view all the answers

    A materials scientist is investigating the corrosion resistance of various metals in highly acidic environments. They expose several metal samples to concentrated $HCl$ solutions under varying anodic potentials. Which of the following metals would be expected to exhibit transpassive behavior at a sufficiently high anodic potential in $HCl$, and what characterizes this behavior?

    <p>Chromium (Cr); transpassive behavior involves the formation of soluble chromate species, leading to accelerated corrosion. (C)</p> Signup and view all the answers

    In an experiment involving the electrolysis of a concentrated aqueous solution of $NaCl$, $HCl$ gas is observed to evolve at the anode under specific conditions. Which set of conditions and mechanistic steps BEST explains this phenomenon?

    <p>High current density and low pH; favoring the direct oxidation of $Cl^-$ to $Cl_2$, followed by rapid hydrolysis of $Cl_2$ to form $HOCl$, which disproportionates to $HCl$ and $O_2$. (C)</p> Signup and view all the answers

    Which of the following is NOT a characteristic property of acids in aqueous solution?

    <p>They produce hydroxide ions ($OH^-$). (D)</p> Signup and view all the answers

    What is the role of a guard tube containing calcium chloride in the preparation of HCl gas?

    <p>To dry the gas produced. (C)</p> Signup and view all the answers

    Why is water necessary for HCl to exhibit acidic properties?

    <p>Water facilitates the separation of $H^+$ ions from HCl molecules. (C)</p> Signup and view all the answers

    Which of the following statements is most accurate regarding hydrogen ions in aqueous solution?

    <p>Hydrogen ions exist as hydronium ions ($H_3O^+$). (A)</p> Signup and view all the answers

    What is produced when a base, such as sodium hydroxide (NaOH), is dissolved in water?

    <p>Hydroxide ions ($OH^-$) (B)</p> Signup and view all the answers

    In an experiment, a student prepares a solution of HCl in a nonpolar solvent and finds that it does not conduct electricity. Which of the following best explains this observation?

    <p>The nonpolar solvent prevents the ionization of HCl. (C)</p> Signup and view all the answers

    A student tests a gas produced from the reaction of solid NaCl and concentrated sulfuric acid with both dry and wet blue litmus paper. What would they observe?

    <p>Only wet litmus paper turns red. (D)</p> Signup and view all the answers

    Consider two beakers. Beaker A contains a 1M solution of HCl, and Beaker B contains pure ethanol. Which solution will conduct electricity, and why?

    <p>Beaker A; because ethanol is not an electrolyte (D)</p> Signup and view all the answers

    A chemist dissolves $HCl$ in both $H_2O$ and $D_2O$ (heavy water). Which of the following statements accurately compares the resulting solutions?

    <p>The $D_2O$ solution will be slightly less acidic due to the kinetic isotope effect on the dissociation of $DCl$. (A)</p> Signup and view all the answers

    A researcher dissolves sodium hydroxide ($NaOH$) in heavy water ($D_2O$) instead of regular water ($H_2O$). Consider the following equilibrium: $NaOD(s) \rightleftharpoons Na^+(aq) + OD^-(aq)$. How would you expect this to affect the solution, if at all?

    <p>The basicity of the solution will be virtually unchanged, as $OD^-$ and $OH^-$ have similar base strengths. (A)</p> Signup and view all the answers

    Which of the following solutions is MOST likely to conduct electricity?

    <p>A solution of hydrochloric acid in water (C)</p> Signup and view all the answers

    What is the role of water in the context of acids?

    <p>Water is necessary for the ionization of acids, producing $H^+$ ions (D)</p> Signup and view all the answers

    Why do hydrogen ions in aqueous solutions always exist as $H_3O^+$ or $H^+(aq)$?

    <p>Hydrogen ions are unstable on their own and immediately react with water molecules (D)</p> Signup and view all the answers

    When sodium hydroxide (NaOH) is dissolved in water, which of the following ions are produced?

    <p>$Na^+$ and $OH^-$ (A)</p> Signup and view all the answers

    What is the purpose of using a guard tube containing calcium chloride in the preparation of dry HCl gas?

    <p>To remove moisture from the gas (D)</p> Signup and view all the answers

    A chemist tests dry HCl gas with dry blue litmus paper and observes no color change. What does this indicate?

    <p>Water is required for HCl to exhibit its acidic properties (C)</p> Signup and view all the answers

    Which equation accurately represents the interaction between hydrochloric acid and water?

    <p>HCl + H2O → H3O+ + Cl- (A)</p> Signup and view all the answers

    Consider a scenario where solid NaCl is mixed with concentrated sulfuric acid in a completely sealed, anhydrous environment. What would you expect to observe?

    <p>No immediate reaction due to the absence of water to facilitate protonation. (D)</p> Signup and view all the answers

    A researcher attempts to measure the pH of a solution of $HCl$ dissolved in anhydrous diethyl ether ($Et_2O$) using a standard aqueous pH meter. What reading is most likely, and why?

    <p>No reliable reading, because the pH meter's electrode relies on an aqueous environment for proper function, thus cannot accurately assess the 'acidity' in a non-aqueous solvent. (B)</p> Signup and view all the answers

    A highly specialized electrochemical cell is constructed with two platinum electrodes, one immersed in $DCl$ (deuterated hydrochloric acid) in $D_2O$ (heavy water) and the other in standard $HCl$ in $H_2O$. A salt bridge maintains ionic conductivity between the two half-cells. Under what conditions would you expect the measured cell potential to deviate significantly from zero, assuming both solutions are nominally 1 M and at the same temperature?

    <p>Due to the kinetic isotope effect affecting the rates of electrode reactions involving deuterium versus protium. (C)</p> Signup and view all the answers

    Flashcards

    Conductivity of Acids

    Acids allow electric current to flow through them, indicating ionic mobility.

    Ions in Acids

    Acids produce H+ ions as cations and various anions in solution.

    H+ Ion

    The hydrogen ion (H+) is responsible for the acidic properties of substances.

    Hydronium Ion (H3O+)

    H+ ions combine with water to form hydronium ions (H3O+) in solutions.

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    Acid-Base Reaction in Water

    Acids release H+ ions when dissolved in water, enabling their acidic behavior.

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    Glucose and Alcohol Solutions

    These solutions do not conduct electricity, indicating no ion presence.

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    NaOH in Water

    Sodium hydroxide (NaOH) dissociates in water to yield Na+ and OH- ions.

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    HCl Gas Production

    When HCl is placed in water, it dissociates to release H+ and Cl- ions.

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    Litmus Paper Test

    Litmus paper changes color based on the presence of acids or bases in a solution.

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    Dissociation of Acids

    Acids dissociate to produce ions only in aqueous solutions, not in dry form.

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    Electric Current in Acids

    Acids conduct electricity due to the presence of free ions.

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    H+ Ion Role

    The presence of H+ ions determines the acidic properties of substances.

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    Action of Acids in Water

    Acids produce H+ ions when dissolved in water, forming hydronium ions.

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    Formation of Hydronium Ion

    H+ ions combine with water to form hydronium ions (H3O+).

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    Dissociation of Sodium Hydroxide

    Sodium hydroxide (NaOH) dissociates in water to produce Na+ and OH- ions.

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    Gas from HCl Reaction

    Adding concentrated sulphuric acid to NaCl produces HCl gas.

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    Testing Gas with Litmus

    The litmus paper test identifies acidity based on color change.

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    Presence of Ions in Solutions

    Electrical conductivity indicates the presence of ions in a solution.

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    Acids vs. Non-conductive Solutions

    In contrast to acids, glucose and alcohol solutions do not conduct electricity.

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    Acidic Character in Dry and Aqueous Forms

    Dry HCl gas cannot produce H+ ions; only in water does it exhibit acidic behavior.

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    Glowing Bulb in Acids

    The bulb glows when electric current flows through acidic solutions due to ions.

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    Effect of Water on Acids

    Acidic behavior is observed only when acids are dissolved in water, producing H3O+.

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    Dry HCl Gas Behavior

    Dry HCl gas does not produce H+ ions; it requires water to dissociate.

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    Testing Acid Gas with Litmus

    Litmus paper changes color when exposed to acidic gases like HCl.

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    NaOH Dissociation in Water

    Sodium hydroxide (NaOH) dissolves to produce Na+ and OH- ions in water.

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    Electric Current Indicator

    The flow of electric current indicates the presence of ions in solutions.

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    Conductivity of Non-Acids

    Glucose and alcohol solutions do not conduct electricity due to lack of ions.

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    Acids in Water Equation

    When acids dissociate in water, they produce H+ ions and anions, leading to acidity.

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    Ions Produced by Acids

    Acids produce H+ ions and anions when dissolved in water.

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    Role of Water in Acids

    Acids produce H+ ions in the presence of water only.

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    Sodium Chloride Reaction

    Mixing NaCl with sulfuric acid produces HCl gas.

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    Hydronium Ion Formation

    H+ ions combine with water to form hydronium (H3O+) in solution.

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    Bases in Water

    Bases like NaOH dissociate into Na+ and OH- ions in water.

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    Gas and Acidic Character

    Dry HCl gas doesn’t produce H+ ions; requires water to show acidity.

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    Electric Current and Ions

    Flow of electricity in solutions shows presence of ions.

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    Electric Current through Solutions

    The flow of electric current indicates ionic movement in solutions.

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    Acids Produce Ions

    Acids dissociate in water to produce H+ and anions like Cl–.

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    Testing the Gas from HCl

    Dry HCl gas does not change litmus color; it needs water to dissociate.

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    Behavior of Bases in Water

    Bases like NaOH dissociate in water to yield Na+ and OH- ions.

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    Gas from NaCl and H2SO4

    Adding concentrated H2SO4 to NaCl produces HCl gas.

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    Ions in Non-Conductive Solutions

    Glucose and alcohol solutions do not conduct electricity, indicating no ions.

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    Chloride Ion Presence

    The chloride ion (Cl–) is an example of an anion that comes from acids like HCl.

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    Acids in Aqueous Solution

    Acids dissociate to release H+ ions only in water.

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    Ionic Movement

    The flow of electric current shows ions are present.

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    Role of Water

    Water is essential for acids to produce H+ ions.

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    Hydronium Ion Equation

    H+ ions combine with water to form H3O+.

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    Testing for Acidity

    Litmus paper changes color when in contact with acids.

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    Sodium Hydroxide Reaction

    NaOH dissociates in water to yield Na+ and OH- ions.

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    Conductivity of Solutions

    Only ionic solutions can conduct electricity.

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    Non-Conductive Solutions

    Glucose and alcohol do not release ions in water.

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    Colloquial Acid Character

    Acidic behavior is confirmed only when in solution.

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    Study Notes

    Acidic Properties of Solutions

    • Acids produce hydrogen ions (H⁺) in solution.
    • These ions are responsible for the acidic properties of the solutions.
    • Acids such as HCl, HNO₃, and H₂SO₄ contain H⁺ ions.
    • The presence of water is crucial for the separation of H⁺ ions from the acid molecules.
    • Dry HCl gas does not exhibit acidic properties, but an aqueous solution (HCl dissolved in water) shows them.
    • Acids contain anions such as Cl⁻ in HCl, NO₃⁻ in HNO₃, and SO₄²⁻ in H₂SO₄.
    • The bulb glows when acids and alcohols are mixed in a solution indicating an electricity flow.
    • Acids can contain Cl− , NO⁻₃, and SO₄²⁻ anions.
    • Acids produce hydrogen ions in the presence of water, HCl + H₂O → H₃O⁺ + Cl⁻

    Activity 2.9

    • The activity examines if acids only produce ions in solution.
    • A solid (NaCl) and concentrated sulfuric acid are used in a setup to produce HCl gas.
    • The setup involves observing the gas released from the test tube (HCl).
    • The gas is tested by dry and wet litmus paper.
    • Wet litmus changes color, while dry litmus does not, demonstrating the acidity of the aqueous solution.
    • The experiment demonstrates that hydrogen ions (H⁺) in HCl are produced in the presence of water, not in its absence.
    • The separation of H⁺ from HCl molecules cannot occur without water.
    • HCl + H₂O → H₃O⁺ + Cl⁻
    • The experiment uses a drying tube with calcium chloride to dry the gas, preventing interference from water vapor in humid environments. This is to ensure the presence of only the dry HCl gas is being tested.

    Hydronium Ions in Acids

    • Hydrogen ions (H⁺) do not exist on their own in water.
    • They combine with water molecules (H₂O), forming hydronium ions (H₃O⁺) or (H⁺(aq)).
    • The combination with water is necessary for the hydrogen ions to exist as functioning acidic species.
    • Hydronium ions (H3O+) are the active form of acidity in a water solution.
    • This is demonstrated by testing the gas evolved from a reaction successively with dry and wet litmus paper.

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    Description

    This quiz focuses on the acidic properties of solutions, including how acids produce hydrogen ions in water and the role of hydronium ions. It also examines an activity that demonstrates the behavior of acids in solutions. Test your understanding of key concepts related to acids and their properties.

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