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Questions and Answers

What is a characteristic feature of a vacancy defect?

  • It is only found in metallic solids.
  • It creates an overcrowded crystal structure.
  • It increases the density of a substance.
  • It occurs when an atom is absent from its lattice site. (correct)

How does an interstitial defect affect the density of a substance?

  • Density increases due to additional atoms in void spaces. (correct)
  • Density is enhanced only in ionic compounds.
  • Density remains unchanged.
  • Density decreases significantly.

In a Frenkel defect, what happens to the smaller ion in ionic solids?

  • It combines with neighboring atoms.
  • It moves to an interstitial space, creating a vacancy. (correct)
  • It enhances the overall density.
  • It remains in its original position.

Which of the following statements is true regarding Schottky defects?

<p>An equal number of anions and cations are absent. (D)</p> Signup and view all the answers

Which statement describes line defects?

<p>They involve distortion around a specific line. (D)</p> Signup and view all the answers

What is typically a cause for the formation of edge defects in crystals?

<p>Solidification of the crystal. (A)</p> Signup and view all the answers

What is the expected vapor pressure of a substance at 363 K?

<p>1.4 atm (B)</p> Signup and view all the answers

What is the estimated energy required for sublimation of ice based on its vapor pressures at 268 K and 273 K?

<p>52,370 J/mol (C)</p> Signup and view all the answers

What results from vacancy condensation in crystalline structures?

<p>Accumulation of vacancies leading to line defects. (B)</p> Signup and view all the answers

When the vapor pressure of ethanol at 34.9 ˚C is 115 torr, what is its heat of vaporization?

<p>40.5 kJ/mol (C)</p> Signup and view all the answers

Which defect type incorporates both vacancy and interstitial effects?

<p>Frenkel defect. (B)</p> Signup and view all the answers

At what temperature does the vapor pressure of ethanol reach 760 torr based on the heat of vaporization provided?

<p>77 ˚C (D)</p> Signup and view all the answers

What is the octet rule in atomic structure?

<p>Atoms tend to have eight electrons in the outermost shell. (C)</p> Signup and view all the answers

In solids, how do atoms move when they are closely arranged together?

<p>They tend to move into the orbitals of neighboring atoms. (C)</p> Signup and view all the answers

What is the primary effect of doping in semiconductors?

<p>Increases the number of charge carriers (A)</p> Signup and view all the answers

Which of the following correctly describes the behavior of valence electrons?

<p>They are involved in bonding and chemical reactions. (C)</p> Signup and view all the answers

What is the phase diagram commonly used for?

<p>To illustrate the phases of matter at varying pressures and temperatures. (D)</p> Signup and view all the answers

Which type of semiconductor uses higher valence elements as donor atoms?

<p>n-type semiconductor (D)</p> Signup and view all the answers

What does the presence of donor atoms do to the Fermi energy level in semiconductors?

<p>Alters based on temperature and donor concentration (C)</p> Signup and view all the answers

Using the formula $R = \frac{pL}{A}$, which parameter does NOT affect the resistance of a material?

<p>Color of the material (C)</p> Signup and view all the answers

What is the resistivity of tungsten according to the provided resistivity values?

<p>10.6×10−8 ohm-m (B)</p> Signup and view all the answers

In the resistance calculation example provided, what was the calculated resistance of the copper wire?

<p>0.0187 ohm (C)</p> Signup and view all the answers

What electrical property is uniquely characteristic of semiconductors compared to conductors and insulators?

<p>Ability to be manipulated through doping (D)</p> Signup and view all the answers

What is the diameter of a tungsten filament with a length of 4.00 cm and a resistance of 0.350 Ω?

<p>1.00 mm (D)</p> Signup and view all the answers

Flashcards

Burgers Vector

The displacement distance of atoms around a dislocation line. It's perpendicular to the edge dislocation line.

Screw Dislocation

A type of line defect formed by applying shear stress to a perfect crystal, causing a helical path in the crystal lattice.

Point Defects

Imperfections in the crystal structure that occur at a single atomic site.

Line Defects

One-dimensional imperfections that disrupt the crystal lattice, like dislocations. They influence material properties.

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Doping

The deliberate introduction of impurities into a semiconductor to alter its electrical, optical, and structural properties.

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Donor Atoms

Impurity atoms added to a semiconductor during doping, which contribute extra electrons (n-type) or holes (p-type) to the material.

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n-type Semiconductor

A semiconductor material doped with impurities that have a higher valence than the base element, resulting in an excess of free electrons, making it more conductive.

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p-type Semiconductor

A semiconductor material doped with impurities that have a lower valence than the base element, resulting in an excess of 'holes' (electron vacancies), allowing for better conductivity.

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Fermi Energy Level

The energy level at which there is a 50% probability of finding an electron in a material at absolute zero temperature. It shifts upon doping.

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What is resistivity and how does it relate to resistance?

Resistivity (ρ) is a material property that describes how strongly a material opposes the flow of electric current. Resistance (R) is a measure of how much a specific object made of that material opposes the current. Resistance is calculated as R = ρL/A, where L is the length and A is the cross-sectional area.

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Conductor

A material that allows electric current to flow easily through it, with low resistance.

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Insulator

A material that strongly resists the flow of electric current, having very high resistance.

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Valence Electrons

Electrons located in the outermost shell of an atom. They're responsible for bonding with other atoms and determining the electrical properties of a material.

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Octet Rule

A rule stating that atoms tend to gain, lose, or share electrons to achieve a stable configuration with eight electrons in their outermost shell.

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Semiconductors

Materials that can act as both conductors and insulators, depending on conditions like temperature or impurities. Their conductivity falls between conductors and insulators.

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Why do materials behave differently electrically?

The arrangement of atoms and the freedom of electrons within those materials determine their electrical properties. In conductors, electrons move freely, in semiconductors, their movement is more restricted, and in insulators, electrons are tightly bound.

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Vapor Pressure

The pressure exerted by the vapor of a substance in equilibrium with its liquid or solid phase at a given temperature.

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Sublimation

The process where a substance changes directly from the solid state to the gaseous state without passing through the liquid state.

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Temperature coefficient of resistance

A material's property describing how its resistance changes with temperature. It's represented by 'a' and measured in per degree Celsius (°C).

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Resistance at different temperature

The resistance of a material changes with temperature. The formula for calculating resistance at a different temperature is R = Ro(1 + aΔT), where Ro is the initial resistance, a is the temperature coefficient of resistance, and ΔT is the temperature change.

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Linear expansion

The tendency of matter to increase in length when heated. The amount of expansion depends on the material's coefficient of linear expansion and the temperature change.

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Volumetric expansion

The tendency of matter to increase in volume when heated. The amount of expansion depends on the material's coefficient of volumetric expansion and the temperature change.

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Coefficient of Linear Expansion (a)

A material property that indicates how much it expands per degree Celsius change in temperature. Each material has its unique a value.

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Coefficient of Volumetric Expansion (b)

A material property that indicates how much its volume expands per degree Celsius change in temperature. Each material has its unique 'b' value.

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Calculating resistance at a different temperature

The formula R = Ro(1 + aΔT) is used to calculate the resistance of a material at a different temperature, where Ro is the initial resistance, a is the temperature coefficient of resistance, and ΔT is the temperature change.

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Temperature effects on materials

Temperature affects the physical properties of materials, including resistance and expansion. These changes are predictable and can be calculated using specific formulas and material properties.

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Refraction

The bending of light as it passes from one medium to another, caused by a change in its speed.

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Refractive Index

A dimensionless number that describes how much a material slows down light compared to a vacuum.

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What is the formula for refractive index?

N = C/V, where N is the refractive index, C is the speed of light in a vacuum, and V is the speed of light in the material.

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What is the optical property that explains why a straw appears bent in water?

Refraction, because light bends as it passes from air (faster) into water (slower).

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Optical Properties

The characteristics of materials describing how they interact with light.

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Corrosion

The gradual deterioration of a material due to a chemical reaction with its environment.

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Corrosion Constant

A numerical value representing a material's resistance to corrosion.

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What happens to the speed of light in a medium with a higher refractive index?

The speed of light decreases in a medium with a higher refractive index.

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Vacancy Defect

A point defect in a crystal lattice where an atom is missing from its usual position, creating a vacant site. This lowers the density of the material.

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Interstitial Defect

A point defect where an extra atom or molecule occupies a space between the regular lattice sites, increasing the material's density.

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Frenkel Defect

A point defect in ionic solids where a smaller ion (usually a cation) leaves its lattice site and occupies an interstitial space. This creates both a vacancy and an interstitial defect.

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Schottky Defect

A point defect in ionic solids where an equal number of cations and anions are missing from their lattice sites, maintaining electrical neutrality. It's like a balanced pair of missing tiles.

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Edge Defect

A type of line defect where the lattice structure near the defect line is distorted towards or away from the line. It's like the tiles around a crack are pushed or pulled.

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What are the different types of point defects?

Point defects are localized imperfections in a crystal lattice. Common types include vacancy defects (missing atoms), interstitial defects (extra atoms), Frenkel defects (an ion moving to an interstitial space), and Schottky defects (balanced missing ions).

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What is the impact of line defects on materials?

Line defects, like edge defects, disrupt the crystal lattice along a line. These defects can influence the material's strength, ductility, and other mechanical properties.

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Study Notes

Course Information

  • Course title: CHEM 004 – Material Science and Engineering
  • Department: Department of Environmental and Sanitary Engineering
  • Institution: Technological Institute of the Philippines – Q.C
  • Presenter: Engr. Andrey Joshua Antiporta

Atomic Structure and Bonding

  • Valence electrons are located at the outermost shell of an atom
  • Electrons tend to form pairs for stability
  • Unpaired electrons tend to gain other electrons from another atom
  • Atoms are composed of a nucleus containing protons and neutrons, with electrons orbiting the nucleus
  • Protons are positively charged
  • Neutrons are neutral
  • Electrons are negatively charged
  • 1 Å = 100 pm

Ionic Bonding

  • Occurs between positive and negative ions (cations and anions)
  • Electron transfer is necessary
  • Large difference in electronegativity is required
  • Example: NaCl (sodium chloride)
  • Nondirectional bonding, meaning the bond does not have a specific direction

Covalent Bonding

  • Covalent bonds involve sharing of electrons
  • Atoms share electrons to gain stability
  • Electronegativities of atoms are similar or comparable
  • Example: H2, CH4

Metallic Bonding

  • Metals tend to form bonds by collective sharing of delocalized electrons
  • Delocalized electrons give metals their conductive properties

Inter-molecular or Secondary Bonds

  • Dipole-Dipole Interactions occur when two molecules have polar charges (dipoles).
  • These charges are weak.
  • Hydrogen bonding is a type of secondary bonding (an example of dipole-dipole)

Bonding Forces and Energy

  • Primary bonding: Ionic, Covalent, Metallic
  • Secondary bonding: Dipole-dipole, H-bonds
  • Bonding energies and melting temperatures vary for different substances
    • Ionic bonds tend to have large bonding energies
    • Covalent bonds vary but are moderate
    • Metallic bonds are variable and moderate
    • Secondary bonds have the lowest bond energy

Mechanical Properties of Solids

  • Elasticity is the tendency of a material to return to its original shape after stress is applied.
  • Stress is force applied to a material.
  • Strain is deformation caused by stress.

Crystalline Structures

  • Solids are characterized by structural rigidity and resistance to applied forces.
  • Crystalline solids have a highly ordered, repeating arrangement of atoms or molecules in a periodic lattice.
  • Polycrystalline structures are comprised of many small crystals in a random arrangement
  • Amorphous solids have no long-range order

Imperfections in Solids

  • Imperfections, or defects, can occur in crystalline structures, leading to unique properties
  • Impurities are often present in a metal
  • Dislocation defects result from the presence of atoms in planes and/or directions of slip
  • Point defects: vacancy, interstitial defects
  • Frenkel defect: smaller ion (cation) moves out of its place and occupies an intermolecular space; a vacancy defect is created on its original position and the interstitial defect is experienced in its new position
  • Schottky defect: equal number of anions and cations are missing from the compound

Semiconductor Doping

  • Doping is introducing impurities into an intrinsic semiconductor.
  • Extrinsic semiconductors are doped with impurities.
  • P-type dopants are used when extra electrons are required
  • N-type impurities are used when extra electron holes are required

Unit Cell

  • Unit cell is the smallest repeating unit of a crystalline structure.
  • Types of unit cell: Simple cubic, Body-centered cubic (BCC), Face-centered cubic (FCC)
  • Density is related to the unit cell

Diffusion

  • Diffusion is the process by which atoms or molecules move from a region of higher concentration to a region of lower concentration.
  • Mechanisms: Substitutional diffusion, Vacancy diffusion, Interstitial diffusion
  • Factors that affect the rate of diffusion: temperature, type of material, type of diffusing atoms

Phase Diagrams

  • Phase diagrams show the phases of a substance at various temperatures and pressures
  • Triple point: the temperature and pressure where all three phases (solid, liquid, gas) coexist in equilibrium
  • Critical point: the point beyond where a liquid cannot exist
  • Fusion/Melting curve: the curve representing solid to liquid
  • Vaporization curve: the curve representing liquid to gas
  • Sublimation curve: the curve representing solid to gas

Electrical Properties

  • A conductor allows the easy flow of electrons
  • An insulator does not allow any flow of electrons
  • A semiconductor is intermediate, and its behavior depends on temperature

Thermal Properties

  • Thermal expansion is the tendency of a substance to increase in size due to temperature increases.
  • Linear and volumetric coefficients determine the amount of expansion.

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