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Questions and Answers

How does metallic character change as atomic number increases across a period and down a group?

  • Increases in a period and decreases in a group
  • Decreases in a period and the group
  • Increases both in a period and the group
  • Decreases in a period and increases in a group (correct)

Which elements are most likely to form anions?

  • Nitrogen family
  • Alkali metals
  • Halogens (correct)
  • Oxygen family

Which group of elements has the strongest tendency to form anions?

  • V, Cr, Mn
  • Na, Mg, Al
  • N, O, F (correct)
  • Ga, In, Tl

What is the expected smallest ion in size?

<p>Mg2+ (D)</p> Signup and view all the answers

Which of the following does not represent the correct order of ion sizes?

<p>Mn2+ &gt; Ni2+ &lt; Co2+ (C)</p> Signup and view all the answers

What is the correct order of ionic size for Na+, Mg++, Al3+, and Si4+?

<p>Na+&gt; Mg++&lt; Al3+&lt; Si4+ (D)</p> Signup and view all the answers

If the atomic number of an element is 33, which group will it be placed in on the periodic table?

<p>Fifth group (A)</p> Signup and view all the answers

Which statement correctly describes the trend of atomic volume in a period from left to right?

<p>Decreases (A)</p> Signup and view all the answers

Which electronic configuration exhibits an abnormally high difference between second and third ionization energy?

<p>Is2, 2s2, 2p6, 3s1 3p1 (C)</p> Signup and view all the answers

What is one of the characteristic properties of nonmetals?

<p>Tend to gain electrons (D)</p> Signup and view all the answers

Flashcards

Isoelectronic Ions

Ions with the same number of electrons.

Ionic Size Trend

The order in which ionic sizes change among isoelectronic ions.

Periodic Table Position

Location of an element in the periodic table based on atomic number.

Atomic Volume Trend

The change in atomic volume across a period of the periodic table.

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High Ionization Energy Difference

Elements exhibiting a significant difference between second and third ionization energies.

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Metallic Character Trend

Metallic character increases down a group and decreases across a period in the periodic table.

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Anion Formation Tendency

Elements in the oxygen family (group 16) and halogens (group 17) readily form anions.

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Noble Gas Element

Elements in Group 18 of the periodic table, known for their low chemical reactivity due to a full outer electron shell.

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Ion Size Comparison

Cations are smaller than their parent atoms, and anions are larger. The size is determined by effective nuclear charge.

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Paramagnetic Oxide

Substances with unpaired electrons attract magnetic fields and exhibit paramagnetism.

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Study Notes

Classification of Elements and Periodic Properties

  • Pauling's electronegativity values help predict molecular polarity, EMF series position, coordination numbers, and dipole moments.
  • Electronic configurations are used to determine which elements are not in the same family.
  • Metallic character decreases across a period and increases down a group in the periodic table.
  • Anion formation is most easily seen in the halogen group.
  • Elements in the oxygen family have a strong tendency to form anions.
  • Protons have a large charge, ionization potential, and hydration energy, but small radius.
  • Isoelectronic species (Na+, Mg2+, Al3+, Si4+) have decreasing ionic size as the positive charge increases.
  • Element 33 is in group 15.
  • Atomic volume decreases across a period from left to right.
  • High difference in ionization energies is seen in elements with a specific electronic configurations.
  • Nonmetals are typically electronegative reducing agents, forming basic oxides.
  • Element with electronic configuration 1s²2s²2p⁶3s²3p³ has atomic number 15.
  • Element with atomic number 118 will be a noble gas.
  • Smallest ion size is Mg²+.
  • Ionic radii are inversely proportional to effective nuclear charge.
  • Paramagnetic behaviour is seen in oxides with an odd number of electrons.
  • A cation has a smaller ionic radius than its neutral atom. An anion has a larger ionic radius than its neutral atom.
  • The first ionization potential of beryllium is greater than that of boron.
  • Elements with atomic configurations that include a half-filled or filled electronic sublevel/shell have higher ionization energies.
  • The order of first ionization potentials for Be, B, C, N, and O is Be < B < C < N < O.
  • The correct order of acidic strength for hydrides of Group 15 elements is NH₃ < PH₃ < AsH₃.
  • Silicon has a coordination number of 4 in its compounds.
  • Fluorine has a lower bond energy than chlorine.
  • Mn(III) is more stable than Mn(II) in aqueous solution.
  • Elements in group 15 exhibit oxidation states of +3 and +5.
  • Ferrous ions (Fe²⁺) have a higher degree of unpairing than nickel(II) ions (Ni²⁺).

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